An official website of the United States government
Although earthquakes are one of the most notorious natural disasters, a full understanding of the underlying mechanisms is still lacking. Here, nanoscale friction measurements were performed by atomic force microscopy (AFM) on calcite single crystals with an oxidized silicon tip to investigate the influence of roughness, contact aging, and dry vs. aqueous environment. In dry environments, smooth and rough calcite surfaces yielding single- and multiasperity contacts, respectively, exhibit velocity-weakening ( β D ln V ) or neutral friction at slow sliding velocities and velocity-strengthening friction ( α D ln V ) at higher velocities, while the transition shifts to slower velocities with an increase in roughness. The origin of the velocity-weakening friction is determined to be contact aging resulting from atomic attrition of the crystalline surface. Friction measurements in aqueous environment show evidence of pressure solution at sufficiently slow sliding velocities, which not only significantly reduces friction on single-and multiasperity contacts but also, eliminates atomic attrition and thereby, velocity-weakening friction. Importantly, the friction scaling law evolves from logarithmic ( β D ln V ) into linear ( α P S V ), deviating from commonly accepted rate-and-state friction (RSF) laws; this behavior extends over a wider range of velocities with higher roughness. Above a transition velocity, the scaling law remains logarithmic ( α W ln V ). The friction rate parameters α D , β D , α P S , and α W decrease with load and depend on roughness in a nonmonotonic fashion, like the adhesion, suggesting the relevance of the contact area. The results also reveal that parameters and memory distance differ in dry and aqueous environments, with implications for the understanding of mechanisms underlying RSF laws and fault stability.
more »
« less
The Effects of Humidity on the Velocity-Dependence and Frictional Ageing of Nanoscale Silica Contacts
This work examines the effect of environmental humidity on rate-and-state friction behavior of nanoscale silica-silica nanoscale contacts in an atomic force microscope, particularly, its effect on frictional ageing and velocity-weakening vs. strengthening friction from 10 nm/s to 100 μm/s sliding velocities. At extremely low humidities (), ageing is nearly absent for up to 100 s of nominally stationary contact, and friction is strongly velocity-strengthening. This is consistent with dry interfacial friction, where thermal excitations help overcome static friction at low sliding velocities. At higher humidity levels (10–40% RH), ageing becomes pronounced and is accompanied by much higher kinetic friction and velocity-weakening behavior. This is attributed to water-catalyzed interfacial Si–O-Si bond formation. At the highest humidities examined (> 40% RH), ageing subsides, kinetic friction drops to low levels, and friction is velocity-strengthening again. These responses are attributed to intercalated water separating the interfaces, which precludes interfacial bonding. The trends in velocity-dependent friction are reproduced and explained using a computational multi-bond model. Our model explicitly simulates bond formation and bond-breaking, and the passivation and reactivation of reaction sites across the interface during sliding, where the activation energies for interfacial chemical reactions are dependent on humidity. These results provide potential insights into nanoscale mechanisms that may contribute to the humidity dependence observed in prior macroscale rock friction studies. They also provide a possible microphysical foundation to understand the role of water in interfacial systems with water-catalyzed bonding reactions, and demonstrate a profound change in the interfacial physics near and above saturated humidity conditions.
more »
« less
- Award ID(s):
- 1951314
- PAR ID:
- 10547709
- Publisher / Repository:
- Springer.com
- Date Published:
- Journal Name:
- Tribology Letters
- Volume:
- 72
- Issue:
- 4
- ISSN:
- 1023-8883
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Supersonic impact of metallic microparticles onto metallic substrates generates extreme interfacial deformation and high contact pressures, enabling solid-state metallic bonding. Although higher impact velocities are generally believed to improve bond quality and mechanical properties in materials formed by supersonic impact deposition, here we report a peak in bond strength for single microparticle impact bonding, followed by a decline at higher impact velocities. Our in situ micromechanical measurements of interfacial strength for Al microparticles bonded to Al substrates reveal a three-fold increase from the critical bonding velocity (800 m/s) to a peak strength around 1,060 m/s. Interestingly, further increase in impact velocity results in a rapid decline in local interfacial strength. The decline continues up to the highest velocity studied, 1,337 m/s, which is well below the threshold required to induce melting or erosion. We show that a mechanistic transition from material strengthening to intensified elastic recovery is responsible for the peak strength in impact-induced bonding, with evidence linking the intensified elastic recovery to adiabatic softening at high impact velocities. Beyond 1,000 m/s for Al, interfacial damage induced by the intensified elastic recovery offsets the strength gain from higher impact velocities, resulting in a net decline in interfacial strength. This mechanistic understanding shall offer insights into the optimal design of processes that rely on impact bonding.more » « less
-
Abstract Establishing a constitutive law for fault friction is a crucial objective of earthquake science. However, the complex frictional behavior of natural and synthetic gouges in laboratory experiments eludes explanations. Here, we present a constitutive framework that elucidates the rate, state, and temperature dependence of fault friction under the relevant sliding velocities and temperatures of the brittle lithosphere during seismic cycles. The competition between healing mechanisms, such as viscoelastic collapse, pressure‐solution creep, and crack sealing, explains the low‐temperature stability transition from steady‐state velocity‐strengthening to velocity‐weakening as a function of slip‐rate and temperature. In addition, capturing the transition from cataclastic flow to semi‐brittle creep accounts for the stabilization of fault slip at elevated temperatures. We calibrate the model using extensive laboratory data on synthetic albite and granite gouge, and on natural samples from the Alpine Fault and the Mugi Mélange in the Shimanto accretionary complex in Japan. The constitutive model consistently explains the evolving frictional response of fault gouge from room temperature to 600°C for sliding velocities ranging from nanometers to millimeters per second. The frictional response of faults can be uniquely determined by the in situ lithology and the prevailing hydrothermal conditions.more » « less
-
Nearly all frictional interfaces strengthen as the logarithm of time when sliding at ultra-low speeds. Observations of also logarithmic-in-time growth of interfacial contact area under such conditions have led to constitutive models that assume that this frictional strengthening results from purely time-dependent, and slip-insensitive, contact-area growth. The main laboratory support for such strengthening has traditionally been derived from increases in friction during “load-point hold” experiments, wherein a sliding interface is allowed to gradually self-relax down to subnanometric slip rates. In contrast, following step decreases in the shear loading rate, friction is widely reported to increase over a characteristic slip scale, independent of the magnitude of the slip-rate decrease—a signature of slip-dependent strengthening. To investigate this apparent contradiction, we subjected granite samples to a series of step decreases in shear rate of up to 3.5 orders of magnitude and load-point holds of up to 10,000 s, such that both protocols accessed the phenomenological regime traditionally inferred to demonstrate time-dependent frictional strengthening. When modeling the resultant data, which probe interfacial slip rates ranging from 3 . μ m · s − 1 . to less than 10 − 5 μ m · s − 1 , we found that constitutive models where low slip-rate friction evolution mimics log-time contact-area growth require parameters that differ by orders of magnitude across the different experiments. In contrast, an alternative constitutive model, in which friction evolves only with interfacial slip, fits most of the data well with nearly identical parameters. This leads to the surprising conclusion that frictional strengthening is dominantly slip-dependent, even at subnanometric slip rates.more » « less
-
Several key features of nanoscale friction phenomena observed in experiments, including the stick-slip to smooth sliding transition and the velocity and temperature dependence of friction, are often described by reduced-order models. The most notable of these are the thermal Prandtl–Tomlinson model and the multibond model. Here we present a modified multibond (mMB) model whereby a physically-based criterion—a critical bond stretch length—is used to describe interfacial bond breaking. The model explicitly incorporates damping in both the cantilever and the contacting materials. Comparison to the Fokker–Planck formalism supports the results of this new model, confirming its ability to capture the relevant physics. Furthermore, the mMB model replicates the near-logarithmic trend of increasing friction with lateral scanning speed seen in many experiments. The model can also be used to probe both correlated and uncorrelated stick slip. Through greater understanding of the effects of damping and noise in the system and the ability to more accurately simulate a system with multiple interaction sites, this model extends the range of frictional systems and phenomena that can be investigated. This article is part of the theme issue ‘Nanocracks in nature and industry’.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript
- Journal Article:
- https://doi.org/10.1007/s11249-024-01904-x
