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The unstretched laminar flame speed (LFS) plays a key role in engine models and predictions of flame propagation. It is also an essential parameter in the study of turbulent combustion and can be directly used in many turbulent combustion models. Therefore, it is important to predict the laminar flame speed accurately and efficiently. Two improved correlations for the unstretched laminar flame speed, namely improved power law and improved Arrhenius form correlations, are proposed for iso-octane/air mixtures in this study, using simulated results for typical operating conditions for spark-ignition engines: unburned temperatures of 300-950 K, pressures of 1-120 bar, and equivalence ratios of 0.6-1.5. The original data points used to develop the new correlations were obtained using the detailed combustion kinetics for iso-octane from Lawrence Livermore National Laboratory (LLNL). The three coefficients in the improved power law correlation were determined using a methodology different from previous approaches. The improved Arrhenius form correlation employs a function of unburned gas temperature to replace the flame temperature, making the expression briefer and making the coefficients easier to calculate. The improved Arrhenius method is able to predict the trends and the values of laminar flame speed with improved accuracy over a larger range of operating conditions. The improved power law method also works well but for a relatively narrow range of predictions. The improved Arrhenius method is recommended, considering its overall fitting error was only half of that using the improved power law correlation and it was closer to the experimental measurements. Even though ϕm, the equivalence ratio at which the laminar flame speed reaches its maximum, is not monotonic with pressure, this dependence is still included, since it produces least-rich best torque (LBT). The comparisons between the improved correlations in this study and the experimental measurements and the other correlations from various researchers are shown as well.
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Impacts of preferential vaporization on flashback behaviors of multi-component liquid fuels
Liquid transportation fuels are composed of a wide range of molecular structures and weights, therefore exhibiting a relatively large distillation temperature range. When fuel chemical properties change along with the distillation temperature curve, preferential vaporization effects could play a role in near-limit combustion behaviors. The objective of this study is to experimentally evaluate the role of preferential vaporization on flame flashback behaviors. A unique spray burner is developed to control the extent of fuel spray vaporization by adjusting flow rates and/or the spray injection location from the burner exit. Spray characteristics are comprehensively determined using Phase Doppler Particle Analyzer. Two binary component mixtures are formulated (n-octane/iso-cetane and iso-octane/n-hexadecane) to exhibit common combustion behaviors in the fully vaporized condition but have considerably different preferential vaporization characteristics. Identical flashback behaviors of two mixtures are observed for fully pre-vaporized conditions by setting the burner temperature at 700 K, including both propagation- and ignition-driven flashback behaviors. Partially vaporized conditions are investigated at two global equivalence ratios (1.0 and 1.4) by setting the burner temperature at 450 K. The flashback behaviors for both global equivalence ratio conditions are found to be affected by the preferential vaporization characteristics represented by laminar flame speeds of the vaporized fuel mixture composition. The relative significance of local flow perturbation induced by instantaneous fuel droplet evaporation near the flame surface has been also investigated by analyzing planar laser-induced fluorescence images, as well as considering the changes of Markstein length with the extent of fuel vaporization. Finally, the relative contributions of local laminar flame speed representing local fuel vapor deposit, local flow perturbation, and preferential vaporization are evaluated through feature sensitivity analyses.
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- Award ID(s):
- 2028376
- PAR ID:
- 10547931
- Editor(s):
- Egolfopoulos, Fokion; Poinsot, Thierry
- Publisher / Repository:
- Elsevier
- Date Published:
- Journal Name:
- Combustion and Flame
- Volume:
- 245
- Issue:
- C
- ISSN:
- 0010-2180
- Page Range / eLocation ID:
- 112300
- Subject(s) / Keyword(s):
- Preferential vaporization Flame flashback Low-temperature ignition
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1016/j.combustflame.2022.112300
