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2. Ring-opening metathesis polymerization of norbornene–benzoladderene (macro)monomers

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   Scannelli, Samantha J.; Alaboalirat, Mohammed; Troya, Diego; Matson, John B. (October 2023, Polymer Chemistry)

   We report highk_p(macro)monomer structures for use in grafting-through ring-opening metathesis polymerization to make linear and bottlebrush polymers. 

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3. Novel bioinks from UV-responsive norbornene-functionalized carboxymethyl cellulose macromers

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4. Near-Infrared Fluorescent Micelles from Poly(norbornene) Brush Triblock Copolymers for Nanotheranostics

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5. Supersoft Norbornene‐Based Thermoplastic Elastomers with High Strength and Upper Service Temperature

   https://doi.org/10.1002/adma.202402431  

   Cater, Henry_L; Allen, Marshall_J; Linnell, Mark_I; Rylski, Adrian_K; Wu, Yudian; Lien, Hsu‐Ming; Mangolini, Filippo; Freeman, Benny_D; Page, Zachariah_A (May 2024, Advanced Materials)

   Abstract With over 6 million tons produced annually, thermoplastic elastomers (TPEs) have become ubiquitous in modern society, due to their unique combination of elasticity, toughness, and reprocessability. Nevertheless, industrial TPEs display a tradeoff between softness and strength, along with low upper service temperatures, typically ≤100 °C. This limits their utility, such as in bio‐interfacial applications where supersoft deformation is required in tandem with strength, in addition to applications that require thermal stability (e.g., encapsulation of electronics, seals/joints for aeronautics, protective clothing for firefighting, and biomedical devices that can be subjected to steam sterilization). Thus, combining softness, strength, and high thermal resistance into a single versatile TPE has remained an unmet opportunity. Through de novo design and synthesis of novel norbornene‐basedABAtriblock copolymers, this gap is filled. Ring‐opening metathesis polymerization is employed to prepare TPEs with an unprecedented combination of properties, including skin‐like moduli (<100 kPa), strength competitive with commercial TPEs (>5 MPa), and upper service temperatures akin to high‐performance plastics (≈260 °C). Furthermore, the materials are elastic, tough, reprocessable, and shelf stable (≥2 months) without incorporation of plasticizer. Structure–property relationships identified herein inform development of next‐generation TPEs that are both biologically soft yet thermomechanically durable. 

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