Abstract Here, we present results of a computational and experimental study of adsorption of various metals on MoS2. In particular, we analyzed the binding mechanism of four metallic elements (Ag, Au, Cu, Ni) on MoS2. Among these elements, Ni exhibits the strongest binding and lowest mobility on the surface of MoS2. On the other hand, Au and Ag bond very weakly to the surface and have very high mobilities. Our calculations for Cu show that its bonding and surface mobility are between these two groups. Experimentally, Ni films exhibit a composition characterized by randomly oriented nanoscale clusters. This is consistent with the larger cohesive energy of Ni atoms as compared with their binding energy with MoS2, which is expected to result in 3D clusters. In contrast, Au and Ag tend to form atomically flat plateaued structures on MoS2, which is contrary to their larger cohesive energy as compared to their weak binding with MoS2. Cu displays a surface morphology somewhat similar to Ni, featuring larger nanoscale clusters. However, unlike Ni, in many cases Cu exhibits small plateaued surfaces on these clusters. This suggests that Cu likely has two competing mechanisms that cause it to span the behaviors seen in the Ni and Au/Ag film morphologies. These results indicate that calculations of the initial binding conditions could be useful for predicting film morphologies. In addition, out calculations show that the adsorption of adatoms with odd electron number like Ag, Au, and Cu results in 100% spin-polarization and integer magnetic moment of the system. Adsorption of Ni adatoms, with even electron number, does not induce a magnetic transition.
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Enhanced joining strength in additive-manufactured polylactic-acid structures fused by embedded heated metallic meshes
Additively manufactured thermoplastic polymers, such as polylactic acid (PLA), hold significant promise for sustainable engineering structures, including wind turbine blades. Upscaling these structures beyond the limitations of 3D printer build volumes is a challenge; fusion joining presents a potential solution. This paper introduces a displacement-controlled resistance welding process for PLA, as an alternative to the typical force controlled methods. We investigated the bonding quality of resistance-welded and adhesive-bonded PLA beams through three-point bending and measured the surface deformations using digital image correlation. Different metal meshes (30 %/0.11 mm Ni–Cu, 34 %/0.07 mm Ni–Cu, and 36 %/0.25 mm Co–Ni) served as heating elements. The process parameters were varied for the 34 %/0.07 mm Ni–Cu mesh to identify an optimum set of parameters. Results showed that this optimized displacement-controlled welding achieved 94 % of the original strength of monolithic samples. This indicates that the new welding process not only ensures high quality bonding and fine surface finishing but also promotes sustainability, recyclability, and economic efficiency in various polymer and composite structural applications.
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- PAR ID:
- 10553078
- Publisher / Repository:
- Elsevier
- Date Published:
- Journal Name:
- Journal of Manufacturing Processes
- Volume:
- 121
- Issue:
- C
- ISSN:
- 1526-6125
- Page Range / eLocation ID:
- 100 to 120
- Subject(s) / Keyword(s):
- Resistance welding, Fusion joining, Additive manufacturing, Thermoplastic polymer, Green manufacturing, Sustainability
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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