skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


This content will become publicly available on August 6, 2025

Title: Thermal rock magnetic cycling (TRMC): a method to track thermal alteration details for palaeointensity interpretations
SUMMARY Accurate absolute palaeointensity is essential for understanding dynamo processes on the Earth and other planetary bodies. Although great efforts have been made to propose techniques to obtain magnetic field strength from rock samples, such as Thellier-series methods, the amount of high-fidelity palaeointensities remains limited. One primary reason for this is the thermal alteration of samples that pervasively occurred during palaeointensity experiments. In this study, we developed a comprehensive rock magnetic experiment, termed thermal rock magnetic cycling (TRMC), that can utilize measurements of critical rock magnetic properties at elevated temperatures during multiple heating-cooling cycles to track thermal changes in bulk samples and individual magnetic components with different Curie temperatures in samples for palaeointensity interpretations. We demonstrate this method on a Galapagos lava sample, GA 84.6. The results for this specimen revealed that GA 84.6v underwent thermophysical alteration throughout the TRMC experiment, resulting in changes in its remanence carrying capacity. These findings were then used to interpret the palaeointensity results of specimen GA 84.6c, which revealed that the two-slope Arai plot yielded two linear segments with distinct palaeointensity values that were both biased by thermophysical alteration. To further test the TRMC method, we selected another historical lava sample (HS 2) from Mt Lassen, detecting slight thermal-physical changes after heating the specimen HS 2–8C to a target temperature of 400 °C. We also isolated a stable magnetic component with a Curie temperature below 400 °C using the TRMC method, which may provide a more reliable palaeointensity estimate of 51 μT. By providing a method for tracking thermal alteration independent of palaeointensity experiments, the TRMC method can explore subtle, unrecognizable thermal alteration processes in less detailed palaeointensity measurements, which can help to assess the thermal stability of the measured samples and interpret the changes in the TRM unblocking spectrum and palaeointensity estimates, facilitating the acquisition of more reliable records for constrain the formation of the inner core and the evolution of Earth's magnetic field.  more » « less
Award ID(s):
2153786
PAR ID:
10555664
Author(s) / Creator(s):
;
Publisher / Repository:
Oxford University Press
Date Published:
Journal Name:
Geophysical Journal International
Volume:
239
Issue:
1
ISSN:
0956-540X
Page Range / eLocation ID:
218 to 235
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. SUMMARY Understanding the temporal changes of the Earth’s magnetic field intensity is one of the main goals of modern palaeomagnetism. For most palaeointensity methods to yield reliable results, the magnetic minerals must obey a set of rules. One of these rules is the additivity of partial thermal (TRM) or anhysteretic remanent magnetizations (ARM). Additivity was previously shown for partial TRM in single-domain particles and more generally for ARMs. Additivity between these two low-field remanences, however, has not been investigated, yet. This paper presents a series of rock magnetic experiments on natural low Ti titanomagnetites (Curie temperature between 534 °C and 561 °C) examining the effects of high temperatures on alternating field (AF) demagnetization and acquisition of an ARM. One of our sample sets comes from a borehole drilled through the impact melt sheet of the Manicouagan crater (Canada), the other from the Rocche Rosse lava flow on the island of Lipari (Italy). Hysteresis parameters indicate the magnetic carriers in the pseudo-single-domain range showing no evidence for oxidation. Thermal demagnetization at 300 °C and 500 °C before AF demagnetization shifts the coercivity spectra towards higher fields. AF demagnetization experiments at 500 °C show a significant (by a factor between 1.4 and >7.6) reduction in median destructive field and a shift towards lower coercivities. A linear relationship was found between the peak magnetic field required to demagnetize a fraction of a full TRM of a sample at a specific temperature and the one necessary to demagnetize the same fraction at room temperature after heating to that temperature. The comparison of full ARM and partial TRM at successively higher temperatures with a hybrid hTARM reveals that combined additivity between the two kinds of remanences is fulfilled. These results open the possibility to demagnetize highly coercive minerals, such as hematite and goethite, which is often not achievable at elevated temperatures. Furthermore, the additivity of TRM and ARM remanences may be used to develop novel hybrid TRM/ARM palaeointensity methods for samples, where heating is problematic (e.g. in meteorites). 
    more » « less
  2. Abstract The past ∼200 million years of Earth's geomagnetic field behavior have been recorded within oceanic basalts, many of which are only accessible via scientific ocean drilling. Obtaining the best possible paleomagnetic measurements from such valuable samples requires an a priori understanding of their magnetic mineralogies when choosing the most appropriate protocol for stepwise demagnetization experiments (either alternating field or thermal). Here, we present a quick, and non‐destructive method that utilizes the amplitude‐dependence of magnetic susceptibility to screen submarine basalts prior to choosing a demagnetization protocol, whenever conducting a pilot study or other detailed rock‐magnetic characterization is not possible. We demonstrate this method using samples acquired during International Ocean Discovery Program Expedition 391. Our approach is rooted in the observation that amplitude‐dependent magnetic susceptibility is observed in basalt samples whose dominant magnetic carrier is multidomain titanomagnetite (∼TM60–65, (Ti0.60–0.65Fe0.35–0.40)Fe2O4). Samples with low Ti contents within titanomagnetite or samples that have experienced a high degree of oxidative weathering do not display appreciable amplitude dependence. Due to their low Curie temperatures, basalts that possess amplitude‐dependence should ideally be demagnetized either using alternating fields or via finely‐spaced thermal demagnetization heating steps below 300°C. Our screening method can enhance the success rate of paleomagnetic studies of oceanic basalt samples. 
    more » « less
  3. SUMMARY Cyclic loading at elevated temperatures occurs either naturally during tectonic or volcanic-induced earthquakes or can be human-induced due to various geological engineering activities. The aim of this study is to test if mechanical fatigue in rocks can be monitored by magnetic methods. For this purpose, the effect of cyclic-mechanical loading (150 ± 30 MPa) on the magnetic susceptibility and its anisotropy of a magnetite-bearing ore with varying temperatures (400 and 500 °C) and environment (air and vacuum) was investigated. Our study shows that magnetic susceptibility decreases significantly (up to 23 per cent) under air conditions and in vacuum (up to 4 per cent) within the first ca. 1000 cycles. Further loading does not significantly affect the magnetic susceptibility which then remains more or less constant. The decrease of susceptibility parameters is stronger at 500 °C compared to 400 °C under both experimental conditions. Magnetic susceptibility was always measured after decompression of the loaded sample at room temperature so that magnetostriction can be excluded as a reason for these changes. The higher the temperature at which samples were loaded the more pronounced is the oxidation of magnetite to haematite. The transformation of magnetite into haematite under ambient conditions is the most important mechanism influencing bulk magnetic properties. The weak changes in magnetic susceptibility after vacuum loadings are probably caused by intragranular microcracks formed on the surface of magnetite grains. These surface deformation structures are accompanied by the refinement of magnetic domains, which is observed by magnetic force microscopy. Bulk magnetic grain size modifications are also confirmed by hysteresis parameters as well as by the increasing Hopkinson peak ratios determined from magnetic susceptibility measurements over Curie point. The degree of magnetic anisotropy and shape factor only change for the air-treated samples and are therefore related to the haematite formation and not to irreversible ductile deformation in magnetite. Our experimental study shows that cyclic loading can change significantly the magnetic properties of a rock due to mineral transformation below < 1000 cycles and that the first stages of mechanical fatigue, which are a precursor of the failure of rock, are closely associated with these transformations. 
    more » « less
  4. null (Ed.)
    SUMMARY Upon cooling, most rocks acquire a thermoremanent magnetization (TRM); the cooling rate at which this happens not only affects palaeointensity estimates, but also their unblocking temperatures in stepwise thermal demagnetization experiments, which is important, for example, to estimate volcanic emplacement temperatures. Traditional single-domain (SD) theory of magnetic remanence relates relaxation times to blocking temperatures— the blocking temperature is the temperature at which the relaxation time becomes shorter than the experimental timescale—and therefore strictly only applies to remanence acquisition mechanisms at constant temperatures (i.e. viscous remanent magnetizations, VRMs). A theoretical framework to relate (constant) blocking temperatures to (time-varying) cooling rates exists, but this theory has very limited experimental verification—partly due to the difficulty of accurately knowing the cooling rates of geological materials. Here we present an experimental test of this ‘cooling rate effect on blocking temperatures’ through a series of demagnetization experiments of laboratory-induced TRMs with controlled cooling rates. The tested cooling rates span about 1 order of magnitude and are made possible through (1) extremely accurate demagnetization experiments using a low-temperature magnetic properties measurement system (MPMS) and (2) the use of a ‘1-step-only’ stepwise thermal demagnetization protocol where the relaxation process is measured over time. In this way the relaxation time corresponding to the blocking temperature is measured, which can be done to much higher accuracy than measuring the blocking temperature directly as done in traditional stepwise thermal demagnetization experiments. Our experiments confirm that the cooling rate relationship holds to high accuracy for ideal magnetic recorders, as shown for a synthetic weakly interacting SD magnetoferritin sample. A SD-dominated low-Ti titanomagnetite Tiva Canyon Tuff sample, however, showed that natural samples are unlikely to be sufficiently ‘ideal’ to meet the theoretical predictions to high accuracy—the experimental data agrees only approximately with the theoretical predictions, which may potentially affect blocking temperature estimates in stepwise thermal demagnetization experiments. Moreover, we find a strongly enhanced cooling rate effect on palaeointensities for even marginally non-ideal samples (up to 43 per cent increase in pTRM for a halving of the cooling rate). 
    more » « less
  5. SUMMARY The magnetic properties of iron-bearing minerals at above-ambient temperatures control their magnetic expression at depth in the Earth and other planets, as well as the permanent memory they retain as thermoremanence or thermochemical remanence when brought to the surface and cooled. This paper reports magnetic hysteresis parameters measured at temperatures up to the Curie point TC for natural pyrrhotite and hematite and for suites of sized magnetites, both natural and synthesized. Domain structure changes can be inferred from the ratio of saturation remanence Mrs to saturation magnetization Ms. In almost all magnetites and pyrrhotites studied, Mrs decreases more rapidly with increasing measurement temperature T than Ms, indicating thermal unblocking or vortex development in single-domain grains and addition or remobilization of domain walls at high T in multidomain grains. During cooling of a rock, iron minerals might then denucleate domains or vortices. Coercive force Hc, a measure of stability against changing magnetic fields, also decreases with increasing measurement T, usually at a rate similar to that of Mrs, but often retains a finite value near the Curie point. 
    more » « less