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Abstract The closure of the Mozambique Ocean defines the final assembly of the megacontinent Gondwana and is associated with a vast region of crustal growth in the Arabian-Nubian Shield. Despite this central paleogeographic position, there are few constraints on the position of terranes within and bounding the Mozambique Ocean. We report paleomagnetic data from ca. 726 Ma dikes exposed in southern Oman. Well-resolved magnetite magnetization is constrained to be primary by a conglomerate test on mafic clasts within overlying Cryogenian diamictite. The resulting paleomagnetic pole indicates that Oman was at a paleolatitude of 37 ± 2.5°N and was rotated ~80° counterclockwise from its present-day orientation. This position is consistent with Oman forming a contiguous plate with the India and South China cratons on the northern margin of the Mozambique Ocean in a distinct tectonic domain from Arabian-Nubian arcs to the south. This position reveals an ~5500-km-wide oceanic realm prior to subsequent closure that resulted in a major zone of Neoproterozoic crustal growth. 

Abstract Experimental studies have demonstrated that solid solutions of minerals from the alunite group, with chemical compositions intermediate between the Al and Fe end-members, can be readily synthesized in the laboratory. In contrast, up until about a dozen years ago, there were no confirmed reports of alunite group minerals with intermediate Al-Fe compositions in natural settings, leading some to suggest that minerals with such compositions might not exist in nature. In recent years, however, alunite group minerals with intermediate Al-Fe compositions have been documented in a few isolated locations, which were previously limited to basalt-hosted acid-sulfate fumarole deposits and acid mine drainage pit lakes. These occurrences contrast with nearly all other reports of minerals from this group, whose measured chemical compositions are very close to either the Al or Fe end-members. Here, we report jarosite-alunite solid solutions containing approximately equal amounts of Al and Fe, which are found in mineralized fractures of the Aztec Sandstone in southeast Nevada. Analysis of the minerals by X-ray diffraction, Raman spectroscopy, and visible-near infrared spectroscopy confirms that they are bona fide solid solutions and not intimate mixtures of end-member minerals. This study represents the first documented occurrence of alunite group solid solutions with intermediate Al-Fe compositions in sedimentary rocks. The results further demonstrate that alunite group minerals with a wide range of Al-Fe compositions occur naturally and can persist for millions of years or more in natural systems. 

ABSTRACT Microorganisms are important catalysts for the oxidation of reduced inorganic sulfur compounds. One environmentally important source of reduced sulfur is metal sulfide minerals that occur in economic mineral deposits and mine waste. Previous research found thatSulfuriferulaspp. were abundant and active in long-term weathering experiments with simulated waste rock and tailings from the Duluth Complex, Northern Minnesota. We, therefore, isolated several strains ofSulfuriferulaspp. from these long-term experiments and characterized their metabolic and genomic properties to provide insight into microbe-mineral interactions and the microbial biogeochemistry in these and other moderately acidic to circumneutral environments. TheSulfuriferulastrains are all obligate chemolithoautotrophs capable of oxidizing inorganic sulfur compounds and ferrous iron. The strains grew over different pH ranges, but all grew between pH 4.5 and 7, matching the weathering conditions of the Duluth Complex rocks. All strains grew on the iron-sulfide mineral pyrrhotite (Fe_{1 −x}S, 0 <x< 0.125) as the sole energy source, as well as hydrogen sulfide and thiosulfate, which are products of sulfide mineral breakdown. Despite their metabolic similarities, each strain encodes a distinct pathway for the oxidation of reduced inorganic sulfur compounds as well as differences in nitrogen metabolism that reveal diverse genomic capabilities among the group. Our results show thatSulfuriferulaspp. are primary producers that likely play a role in sulfide mineral breakdown in moderately acidic to circumneutral mine waste, and the metabolic diversity within the genus may explain their success in sulfide mineral-rich and other sulfidic environments. IMPORTANCEMetal sulfide minerals, such as pyrite and pyrrhotite, are one of the main sources of reduced sulfur in the global sulfur cycle. The chemolithotrophic microorganisms that break down these minerals in natural and engineered settings are catalysts for biogeochemical sulfur cycling and have important applications in biotechnological processes such as biomining and bioremediation.Sulfuriferulais a recently described genus of sulfur-oxidizing bacteria that are abundant primary producers in diverse terrestrial environments, including waste rock and tailings from metal mining operations. In this study, we explored the genomic and metabolic properties of new isolates from this genus, and the implications for their ecophysiology and biotechnological potential in ore and waste from economic mineral deposits. 

Abstract Nanometer‐scale titanomagnetite crystals have been detected in nominally aphyric rhyolite pumice, but whether they are numerous enough to impact bubble nucleation in explosive silicic volcanism was unresolved. This study examines sub‐micron crystals using rock magnetic techniques, Rhyolite‐MELTS modeling, and physical characterization. We analyzed pumice from four eruptions spanning wide ranges in intensity, storage depth, and bubble number density (10¹⁶to 10¹³ m⁻³liquid): 1060 CE Glass Mountain, 1912 CE Novarupta, 232 CE Taupo, and 0.45 Ma Pudahuel. Calculations assuming monospecific assemblages of 10 and 1,000 nm cubic particles yield titanomagnetite number densities of 10²¹to 10¹³m⁻³dense rock equivalent, respectively. In all cases, titanomagnetite is thermodynamically stable at pre‐eruptive storage conditions and magnetic susceptibility (χ_LF) is independent of vesicularity and permeability, indicating that crystals likely formed prior to vesiculation. The existence of nm‐scale Fe‐Ti oxides in four diverse cases suggests that heterogeneous bubble nucleation is a general feature of explosive rhyolite volcanism. 

Abstract Lunar paleomagnetic studies have identified multidomain metallic Fe–Ni alloys as the dominant magnetic contributors in mare basalts. Here, we explore the low‐temperature magnetic behavior of standard samples for a suite of opaque minerals that occur within mare basalts (single‐domain and multidomain Fe, wüstite, ulvöspinel, iron chromite, ilmenite, and troilite). We compare the observed low‐temperature behaviors to those of several Apollo mare basalt samples (10003, 10044, 10020, 10069, 10071, 12009, 12022, 15597). Notable magnetic transitions were detected at 30 K (ilmenite), 60–80 K (chromite, troilite), and 100–125 K (ulvöspinel, chromite). We also investigated the effects of low‐temperature cycling on mare basalt remanence and observed that only grains with coercivities 20–40 mT were cleaned. This suggests a minimal impact of diurnal temperature cycling at the lunar surface on the retrieved lunar paleointensity values. Using comprehensive electron microscopy techniques, including scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), wavelength dispersive spectroscopy (WDS), x‐ray diffraction, and transmission electron microscopy (TEM), we further examined magnetic phases within four Apollo 11 mare basalt samples. Our findings revealed the presence of Fe grains (one to 10 μm in diameter) associated with troilite contain sub‐grains ranging in size from tens to hundreds of nanometers in some samples. These grains, which fall within the single‐domain to multi‐domain range as observed in their first‐order reversal curves, might have the potential to retain high coercivity components and thereby effectively record an ancient dynamo field. 

Abstract Megathrust shear zones are the main fluid transport pathways during the seismic cycle and play a key role in controlling physicochemical alteration. Defining fluid‐rock interaction in wall rocks provides evidence for unraveling the hydrogeology of shear zones and their link to active fluid circulation. We analyzed the variation in concentration, grain size and assemblages of magnetic minerals in the wall rocks of a shallow megathrust (the Sestola Vidiciatico shear zone) where no evidence of high‐frictional heating has been recorded. The Sestola Vidiciatico shear zone preserves evidence of active fluid circulation and stress‐switch during the last brittle phases of the Early to Middle Miocene subduction of the Adriatic plate beneath the frontal prism of the European plate. Magnetic properties indicate low bulk heat transfer during the seismic cycle. Changes in magnetic mineral concentrations highlight iron depletion from clay minerals and dissolution of iron‐oxides for interaction with exotic fluids during the coseismic phase. The relative distribution of Fe‐oxides and goethite suggests migration of Fe‐enriched fluids along fractures during the coseismic/postseismic phase, followed by precipitation for interaction with local fluids. Subsequent alteration and weathering of magnetic minerals, accompanied by the formation of hematite and maghemite, are related to partial oxidation during the interseismic phase. Heterogeneity in magnetic mineral distribution supports active fluid circulation during repeated seismic events and/or exhumation. Rock magnetic characterization of wall rocks in exhumed megathrust represents a promising tool to better understand the role of fluid migration and redox conditions during seismic cycles in subduction zones. 

Abstract Late Mesoproterozoic to Neoproterozoic sedimentary sequences within the Lake Superior region preserve critical paleogeographic records of the position of Laurentia spanning from the end of Midcontinent Rift extension through to the end of the Grenvillian Orogeny. Temporally calibrated paleomagnetic poles from these sequences are essential for resolving Laurentia's plate motion during these tectonic events. The 5 km thick ca. 1,080 to 1,045 Ma fluviolacustrine Oronto Group was deposited during thermal subsidence following rifting prior to onset of Grenvillian contractional deformation in the region. Prior paleomagnetic work has focused on the basal Freda Formation (ca. 1,075 Ma) leaving a long temporal gap in poles from that time until the ca. 990 Ma pole of the unconformably overlying Jacobsville Formation. A new U‐Pb detrital zircon maximum depositional age for the upper Freda Formation of 1,051.6 1.1 Ma indicates that Oronto Group deposition was prolonged. We have developed new inclination‐shallowing corrected paleomagnetic data from the Freda Formation that can be temporally calibrated within this improved chronostratigraphic framework. A new pole from the ca. 1,045 Ma upper Freda Formation is similar in position to that from the ca. 1,075 Ma lower Freda Formation. These data indicate that Laurentia's rapid motion of 20 cm/year from ca. 1,110 to 1,080 Ma significantly slowed to 2 cm/year following onset of the continent‐continent collision of the Grenvillian orogeny. These dynamics are what is predicted if the rapid motion was associated with differential plate tectonic motion that closed an ocean basin leading up to collisional orogenesis and the associated assembly of Rodinia. 

Abstract Mafic rocks are volumetrically and rheologically significant components of the mid‐to lower continental crust, yet tools to study their fabrics have not been well developed. We examine amphibolites exhumed from mid‐to lower crustal levels in a gneiss dome (Entia dome, central Australia) that display various strengths of mineral lineation and foliation associated with different deformation geometries. Combining petrofabric analysis (electron backscatter diffraction, EBSD) with magnetic fabric analysis (Anisotropy of magnetic susceptibility (AMS), we quantify relationships between AMS‐derived fabrics and crystallographic‐preferred alignment of fabric‐defining amphiboles. We combine single‐crystal AMS data with EBSD data to model amphibole textures and their expected magnetic anisotropy. We formulate a new EBSD‐derived petrofabric index,CA_index, and correlate it with the calculated AMS shape parameterU.CA_indexvalues can then be estimated for natural samples using measuredUvalues, leveraging both rapid but texturally low‐resolution AMS and texturally‐resolved but time‐ and analytically‐onerous petrofabric analyses to interpret petrofabrics from magnetic fabric data. In the Entia dome, we identify amphibole c‐fibers (L‐tectonite) in the high‐strain core of the dome, which reflect constrictional strains. In contrast, a‐fibers (S‐tectonites) are dominant near the dome margins and indicate flattening strains. Fabrics measured in different structural subdomains agree well with 2D and 3D numerical models of finite strain distribution in domal structures. Combining textural modeling, AMS measurements, and EBSD analyses allows investigation of previously unexploited records of ductile deformation and flow in amphibole‐bearing rocks. These results can be applied to a wide range of field‐based studies of tectonic and magnetic processes. 

Abstract The study of sedimentary magnetism in the intermontane Tarom Basin (northern Iran) offers insights into local paleoenvironmental conditions during global middle‐late Miocene climate changes and the topographic growth triggered by the Arabia‐Eurasia continental collision. Rock magnetic results reveal that the ∼16.2 to ∼10–9 Ma coarse‐grained deposits at the basin's southern margin present a homogenous magnetic mineral assemblage, reflecting sediment provenance. Conversely, the ∼13.2 to ∼7.6 Ma, fine‐grained deposits in the basin's depocenter include alternating playa‐lake and lacustrine deposits, recording dry, evaporative conditions, leading to hematite formation in a low‐temperature oxidizing environment, and wetter conditions that preserve the original detrital signal, respectively. Time series analyses show cyclicity in different period bands for magnetic susceptibility, but precession and obliquity cycles can hardly be resolved in the record. Comparison with deep‐sea oxygen isotope data suggests that from ∼13.2 to ∼10.8 Ma environmental conditions likely mirrored global climatic forcing, with lacustrine and playa‐lake deposits associated with increased and decreased global temperature, respectively. At ∼10.8 Ma, the basin likely recorded the Tortonian Thermal Maximum with the establishment of a lacustrine system. From ∼10.4 Ma, the magnetic susceptibility signal departed from the global climate record, possibly due to basin margin (western Alborz and Tarom mountains) and regional (Anatolian‐Iranian plateau) topographic growth, accompanied by increased precipitation seasonality, focused rainfall and augmented erosion rates. Finally, we suggest that before ∼10.8 Ma, the Hadley cells expanded northward, leading to a trade‐dominated system with moist air masses sourced from the Caspian, while from ∼10.8 Ma, westerlies dominance progressively prevailed. 

Abstract The late Ediacaran to early Cambrian witnessed significant Earth system changes, including animal life diversification and an enigmatic paleomagnetic record. This study focuses on the Nama Group, a key geological unit for understanding the Ediacaran‐Cambrian transition. Previous paleomagnetic studies in the Nama Group identified complex remagnetization patterns but lacked a detailed examination of remanence carriers. To address this, we conducted a series of rock magnetic experiments on unweathered borehole core samples to better constrain the remagnetization mechanisms. Thermal demagnetization identified two magnetic components.C₁, a recent viscous remanent magnetization, used for borehole core orientation, andC₂, a stable remagnetization component carried by single‐domain (SD) pyrrhotite and magnetite. Magnetic mineralogy and paleomagnetic data suggest that the remanence acquisition mechanism ofC₂is best explained by thermoviscous remanent magnetization (TVRM) and thermal remanent magnetization (TRM), rather than chemical remanent magnetization (CRM). The presence of low unblocking temperatures, coupled with thermochronological evidence of prolonged heating during tectonic collisions and subsequent cooling, supports this interpretation. The remagnetization event is linked to the final consolidation of West Gondwanaland during the late stages of megacontinent assembly (∼490–480 Ma), coinciding with regional uplift and a stable geomagnetic field during the Moyero reverse superchron. These findings challenge the CRM hypothesis, as the quasi‐synchronous remagnetization across cratonic blocks and the predominance of single reverse polarity are better explained by thermal processes. This study highlights the critical role of thermoviscous relaxation in large‐scale remagnetization and provides new insights into the tectonic evolution of West Gondwanaland.