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The Kirchhoff’s law of thermal radiation stating the equivalence of emissivity and absorptivity at the same wavelength, angle, and polarization, has completely constrained emission and absorption processes. Achieving strong nonreciprocal emission points to fundamental advances for applications such as energy harvesting, heat transfer, and sensing, but strong nonreciprocal thermal emission has not been experimentally realized. Here, we observe strong nonreciprocal thermal emission using a custom-designed angle-resolved magnetic thermal emission spectroscopy and an epitaxially-transferred gradient-doped metamaterial. We show that under magnetic field, the metamaterial strongly breaks the Kirchhoff’s law, with a difference between emissivity and absorptivity at the same wavelength and angle reaching as high as 0.43. Significant nonreciprocal emission persists over broad spectral and angular ranges. The demonstration of strong nonreciprocal thermal emission and the approach can be useful for systematic exploration of nonreciprocal thermal photonics for thermal management, infrared camouflage, and energy conversion.
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Broadband nonreciprocal thermal emissivity and absorptivity
A body that violates Kirchhoff’s law of thermal radiation exhibits an inequality in its spectral directional absorptivity and emissivity. Achieving such an inequality is of fundamental interest as well as a prerequisite for achieving thermodynamic limits in photonic energy conversion1and radiative cooling2. Thus far, inequalities in the spectral directional emissivity and absorptivity have been limited to narrow spectral resonances3, or wavelengths well beyond the infrared regime4. Bridging the gap from basic demonstrations to practical applications requires control over a broad spectral range of the unequal spectral directional absorptivity and emissivity. In this work, we demonstrate broadband nonreciprocal thermal emissivity and absorptivity by measuring the thermal emissivity and absorptivity of gradient epsilon-near-zero InAs layers of subwavelength thicknesses (50 nm and 150 nm) with an external magnetic field. The effect occurs in a spectral range (12.5–16 μm) that overlaps with the infrared transparency window and is observed at moderate (1 T) magnetic fields.
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- Award ID(s):
- 2146577
- PAR ID:
- 10574647
- Publisher / Repository:
- Springer Nature
- Date Published:
- Journal Name:
- Light: Science & Applications
- Volume:
- 13
- Issue:
- 1
- ISSN:
- 2047-7538
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
-
Accepted Manuscript
- Journal Article:
- https://doi.org/10.1038/s41377-024-01520-3
