We use one-photon excitation to promote -shell electrons of formic acid (which has a planar equilibrium structure) to an antibonding orbital. The excited molecule is known to have a (chiral) pyramidal equilibrium structure. In our experiment, we determine the handedness of the excited molecule by imaging the momenta of charged fragments, which occur after its Coulomb explosion triggered by Auger-Meitner decay cascades succeeding the excitation. We find that the handedness of the excited molecule depends on its spatial orientation with respect to the propagation (or polarization) direction of the exciting photon. The effect is largely independent of the exact polarization properties of the light driving the excitation. Published by the American Physical Society2024 
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                    This content will become publicly available on December 1, 2025
                            
                            Influence of final state interactions in attosecond photoelectron interferometry
                        
                    
    
            Fano resonances are ubiquitous phenomena appearing in many fields of physics, e.g., atomic or molecular photoionization, or electron transport in quantum dots. Recently, attosecond interferometric techniques have been used to measure the amplitude and phase of photoelectron wave packets close to Fano resonances in argon and helium, allowing for the retrieval of the temporal dynamics of the photoionization process. In this work, we study the photoionization of argon atoms close to the autoionizing state using an interferometric technique with high spectral resolution. The phase shows a monotonic variation across the resonance or a nonmonotonic less than variation depending on experimental conditions, e.g., the probe laser bandwidth. Using three different, state-of-the-art calculations, we show that the measured phase is influenced by the interaction between final states reached by two-photon transitions. Published by the American Physical Society2024 
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                            - Award ID(s):
- 2309133
- PAR ID:
- 10577835
- Publisher / Repository:
- APS
- Date Published:
- Journal Name:
- Physical Review Research
- Volume:
- 6
- Issue:
- 4
- ISSN:
- 2643-1564
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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