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Title: Polymer nanocomposite for protecting photovoltaic cells from solar ultraviolet in space
Abstract Polymer nanocomposite coatings of solar photovoltaic cells that absorb solar ultraviolet (UV) radiation and convert it into visible and near-infrared (NIR) light can increase the operational lifetime and the energy efficiency of the cells. We report a polymer nanocomposite spectrum converting layer (SCL) made of colorless polyimide CORIN impregnated with the nanoparticles (NPs) of fluoride NaYF4doped with three-valent ions of Europium at a molar concentration of 60%. The NPs were the nanocrystals (179 ± 35 nm in size) in thermally stable hexagonal beta-phase. The visible-NIR photoluminescence quantum yield of the nano-powder was ∼69%. The SCLs were applied using the open-air multi-beam multi-target pulsed laser deposition method to silicon heterojunction (SHJ), copper-indium-gallium-selenide (CIGS), and inverted metamorphic multijunction (IMM) solar cells. The cells were exposed to UV radiation from a 365 nm light emitting diode. TheI–Vcharacteristics of the cells were measured with a solar simulator using AM0 filter. The proposed SCLs improved the UV stability of all three types of the cells: the power degradation of SHJs and IMMs cells was stopped or slightly reversed and the degradation rate of CIGSs decreased by ∼25%. The proposed SCLs have great commercial potential, especially for applications to space power.  more » « less
Award ID(s):
2200426
PAR ID:
10592448
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
Nanotechnology Reviews 2024
Date Published:
Journal Name:
Nanotechnology Reviews
Volume:
13
Issue:
1
ISSN:
2191-9097
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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