We used the monochromatic soft-x-ray beamline P04 at the synchrotron-radiation facility PETRA III to resonantly excite the strongest transitions in neonlike ions, and , respectively dubbed and , achieving a resolving power of 15 000 and signal-to-background ratio of 30. We obtain their natural linewidths, with an accuracy of better than 10%, as well as the oscillator-strength ratio from analysis of the resonant fluorescence spectra. These results agree with those of previous experiments, earlier predictions, and our own advanced calculations. Published by the American Physical Society2024
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Valence, charge transfer, and orbital-dependent correlation in bilayer nickelates Nd3Ni2O7
We examine the bulk electronic structure of using Ni core-level hard x-ray photoemission spectroscopy combined with density functional theory dynamical mean-field theory. Our results reveal a large deviation of the Ni occupation from the formal valency, highlighting the importance of the charge transfer from oxygen ligands. We find that the dominant configuration is accompanied by nearly equal contributions from and states, exhibiting an unusual valence state among Ni-based oxides. Finally, we discuss the Ni and orbital-dependent hybridization, correlation and local spin dynamics. Published by the American Physical Society2025
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- Award ID(s):
- 2039380
- PAR ID:
- 10597690
- Publisher / Repository:
- APS
- Date Published:
- Journal Name:
- Physical Review B
- Volume:
- 111
- Issue:
- 16
- ISSN:
- 2469-9950
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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