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This content will become publicly available on April 1, 2026

Title: Valence, charge transfer, and orbital-dependent correlation in bilayer nickelates Nd3Ni2O7
We examine the bulk electronic structure of Nd 3 Ni 2 O 7 using Ni 2 p core-level hard x-ray photoemission spectroscopy combined with density functional theory + dynamical mean-field theory. Our results reveal a large deviation of the Ni 3 d occupation from the formal Ni 2.5 + valency, highlighting the importance of the charge transfer from oxygen ligands. We find that the dominant d 8 configuration is accompanied by nearly equal contributions from d 7 and d 9 states, exhibiting an unusual valence state among Ni-based oxides. Finally, we discuss the Ni d x 2 y 2 and d z 2 orbital-dependent hybridization, correlation and local spin dynamics. Published by the American Physical Society2025  more » « less
Award ID(s):
2039380
PAR ID:
10597690
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
APS
Date Published:
Journal Name:
Physical Review B
Volume:
111
Issue:
16
ISSN:
2469-9950
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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