skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Valence, charge transfer, and orbital-dependent correlation in bilayer nickelates Nd3Ni2O7
We examine the bulk electronic structure of Nd 3 Ni 2 O 7 using Ni 2 p core-level hard x-ray photoemission spectroscopy combined with density functional theory + dynamical mean-field theory. Our results reveal a large deviation of the Ni 3 d occupation from the formal Ni 2.5 + valency, highlighting the importance of the charge transfer from oxygen ligands. We find that the dominant d 8 configuration is accompanied by nearly equal contributions from d 7 and d 9 states, exhibiting an unusual valence state among Ni-based oxides. Finally, we discuss the Ni d x 2 y 2 and d z 2 orbital-dependent hybridization, correlation and local spin dynamics. Published by the American Physical Society2025  more » « less
Award ID(s):
2039380
PAR ID:
10597690
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
APS
Date Published:
Journal Name:
Physical Review B
Volume:
111
Issue:
16
ISSN:
2469-9950
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. We used the monochromatic soft-x-ray beamline P04 at the synchrotron-radiation facility PETRA III to resonantly excite the strongest 2 p 3 d transitions in neonlike Ni ions, [ 2 p 6 ] J = 0 [ ( 2 p 5 ) 1 / 2 3 d 3 / 2 ] J = 1 and [ 2 p 6 ] J = 0 [ ( 2 p 5 ) 3 / 2 3 d 5 / 2 ] J = 1 , respectively dubbed 3 C and 3 D , achieving a resolving power of 15 000 and signal-to-background ratio of 30. We obtain their natural linewidths, with an accuracy of better than 10%, as well as the oscillator-strength ratio f ( 3 C ) / f ( 3 D ) = 2.51 ( 11 ) from analysis of the resonant fluorescence spectra. These results agree with those of previous experiments, earlier predictions, and our own advanced calculations. Published by the American Physical Society2024 
    more » « less
  2. Six-dimensional chiral gauged Einstein-Maxwell supergravity admits a two-parameter rotating dyonic string solution whose near horizon limit is the direct product of three-dimensional Anti-De Sitter space and a squashed three-sphere S 3 . For a particular relation between the two parameters, the solution preserves 1 / 2 supersymmetry. We determine the complete Kaluza-Klein spectrum of the theory around these AdS 3 backgrounds. For the supersymmetric backgrounds, the states organize into infinite towers of long and short multiplets of OSp ( 2 | 2 ) . In a certain limit of parameters, both the supersymmetric and the nonsupersymmetric spectra exhibit scale separation. In the latter case there are five topologically massive vectors and five scalars retaining finite masses with integer conformal dimensions, and in the supersymmetric case there are supersymmetric partners with half integer conformal dimensions, while all other masses diverge. Published by the American Physical Society2025 
    more » « less
  3. We demonstrate detection and measurement of electron paramagnetic spin resonances (EPR) of iron defects in β Ga 2 O 3 utilizing generalized ellipsometry at frequencies between 110 and 170 GHz. The experiments are performed on an Fe-doped single crystal in a free-beam configuration in reflection at 45 and magnetic fields between 3 and 7 T. In contrast with low-field, low-frequency EPR measurements, we observe all five transitions of the s = 5 / 2 high-spin state Fe 3 + simultaneously. We confirm that ferric Fe 3 + is predominantly found at octahedrally coordinated Ga sites. We obtain the full set of fourth-order monoclinic zero-field splitting parameters for both octahedrally and tetrahedrally coordinated sites by employing measurements at multiple sample azimuth rotations. The capability of high-field EPR allows us to demonstrate that simplified second-order orthorhombic spin Hamiltonians are insufficient, and fourth-order terms as well as consideration of the monoclinic symmetry are needed. These findings are supported by computational approaches based on density-functional theory for second-order and on ligand-field theory for fourth-order parameters of the spin Hamiltonian. Terahertz ellipsometry is a way to measure spin resonances in a cavity-free setup. Its possibility of varying the probe frequency arbitrarily without otherwise changing the experimental setup offers unique means of truly disentangling different components of highly anisotropic spin Hamiltonians. Published by the American Physical Society2024 
    more » « less
  4. Nuclear medium effects on B + meson production are studied using the binary-collision scaled cross section ratio between events of different charged-particle multiplicities from proton-lead collisions. Data, collected by the CMS experiment in 2016 at a nucleon-nucleon center-of-mass energy of s NN = 8.16 TeV , corresponding to an integrated luminosity of 175 nb 1 , were used. The scaling factors in the ratio are determined using a novel approach based on the Z μ μ + cross sections measured in the same events. The scaled ratio for B + is consistent with unity for all event multiplicities, putting stringent constraints on nuclear modification for heavy flavor. © 2025 CERN, for the CMS Collaboration2025CERN 
    more » « less
  5. Ever since the discovery of the charge density wave (CDW) transition in the kagome metal CsV 3 Sb 5 , the nature of its symmetry breaking has been under intense debate. While evidence suggests that the rotational symmetry is already broken at the CDW transition temperature ( T CDW ), an additional electronic nematic instability well below T CDW has been reported based on the diverging elastoresistivity coefficient in the anisotropic channel ( m E 2 g ). Verifying the existence of a nematic transition below T CDW is not only critical for establishing the correct description of the CDW order parameter, but also important for understanding low-temperature superconductivity. Here, we report elastoresistivity measurements of CsV 3 Sb 5 using three different techniques probing both isotropic and anisotropic symmetry channels. Contrary to previous reports, we find the anisotropic elastoresistivity coefficient m E 2 g is temperature independent, except for a step jump at T CDW . The absence of nematic fluctuations is further substantiated by measurements of the elastocaloric effect, which show no enhancement associated with nematic susceptibility. On the other hand, the symmetric elastoresistivity coefficient m A 1 g increases below T CDW , reaching a peak value of 90 at T * = 20 K . Our results strongly indicate that the phase transition at T * is not nematic in nature and the previously reported diverging elastoresistivity is due to the contamination from the A 1 g channel. Published by the American Physical Society2024 
    more » « less