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   https://doi.org/10.1039/D3CC05350D  

   Kunkel, Grace E; Treacy, Joseph W; Montgomery, Hayden R; Puente, Ellie G; Doud, Evan A; Spokoyny, Alexander M; Maynard, Heather D (December 2023, Chemical Communications)

   Au(iii) polymer reagents provide facile access to semi-telechelic and diblock copolymers. 

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2. In silico screening of P , N -ligands facilitates optimization of Au( iii )-mediated S -arylation

   https://doi.org/10.1039/D4SC05920D  

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   In silicoexamination of 13P,N-ligated Au(iii) OACs determined the key mechanistic factors governing Au(iii)-mediatedS-arylation. Three complexes were synthesized which exhibited bimolecular coordination rate constants as high as 20 200 M⁻¹s⁻¹. 

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3. Identifying charge-transfer and trip–multiplet states in Co( i ), Co( ii ), and Co( iii ) phthalocyanines using (magneto)optical spectroscopy and (TD)DFT calculations

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   Muldowney, Breanna E; Nevonen, Dustin E; Jeaydi, Towhidi Illius; Ziegler, Christopher J; McNicholas, Brendon J; Nemykin, Victor N (January 2025, Dalton Transactions)

   The electronic structures, charge-transfer, and triplet–multiplet transitions in cobalt(i), cobalt(ii), and cobalt(iii) phthalocyanines were investigated in detail by UV-vis-NIR, MCD, DFT, and TDDFT methods. 

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4. Mononuclear Fe( iii ) Schiff base antipyrine complexes for catalytic hydrogen generation

   https://doi.org/10.1039/D4DT01876A  

   Cropley, Jessica D; Mitchell, Amanda C; Fritsch, Nicole A; Ho, Marissa; Wells, Timothy D; Reynolds, Todd M; Brennessel, William W; McNamara, William R (September 2024, Dalton Transactions)

   Mononuclear Fe(iii) complexes containing an antipyrine Schiff base ligand were prepared and fully characterized, demonstrating a planar tetradentate coordination geometry. The resulting complexes are active for HER with possible ligand cooperativity. 

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5. Solution and solid-state characterization of rare silyluranium( iii ) complexes

   https://doi.org/10.1039/d4cc00655k  

   Lin, Nathan J.; Zeller, Matthias; Bart, Suzanne C. (April 2024, Chemical Communications)

   A uranium(iii) silylate complex [K(DME)₄]-[UI₂{(Si(SiMe₃)₂SiMe₂)₂O}] (1) was stabilized by the addition of 18-crown-6 to form [K(18-crown-6)][UI₂{(Si(SiMe₃)₂SiMe₂)₂O}]. This species was fully characterized using multinuclear NMR spectroscopy, electronic absorption spectroscopy and X-ray crystallography. 

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