Abstract We analyze an optical atomic clock using two-photon transitions in rubidium. Four one- and two-color excitation schemes to probe the and fine-structure states are considered in detail. We compare key characteristics of Rb and two-photon clocks. The clock features a high signal-to-noise ratio due to two-photon decay at favorable wavelengths, low dc electric and magnetic susceptibilities, and minimal black-body shifts. Ac Stark shifts from the clock interrogation lasers are compensated by two-color Rabi-frequency matching. We identify a ‘magic’ wavelength near 1060 nm, which allows for in-trap, Doppler-free clock-transition interrogation with lattice-trapped cold atoms. From our analysis of clock statistics and systematics, we project a quantum-noise-limited relative clock stability at the -level, with integration timeτin seconds, and a relative accuracy of . We describe a potential architecture for implementing the proposed clock using a single telecom clock laser at 1550 nm, which is conducive to optical communication and long-distance clock comparisons. Our work could be of interest in efforts to realize small and portable Rb clocks and in high-precision measurements of atomic properties of Rb -states. 
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                    This content will become publicly available on November 18, 2025
                            
                            Low-energy magnetic states of Tb adatom on graphene
                        
                    
    
            Abstract Electronic structure and magnetic interactions of a Tb adatom on graphene are investigated from first principles using combination of density functional theory and multiconfigurational quantum chemistry techniques including spin–orbit coupling (SOC) . We determine that the six-fold symmetry hollow site is the preferred adsorption site and investigate electronic spectrum for different adatom oxidation states including Tb3+, Tb2+, Tb1+, and Tb0. For all charge states, the Tb configuration is retained with other adatom valence electrons being distributed over , , and single-electron orbitals. We find strong intra-site adatom exchange coupling that ensures that the spins are parallel to the4fspin. For Tb3+, the energy levels can be described by theJ = 6 multiplet split by the graphene crystal field (CF). For other oxidation states, the interaction of4felectrons with spin and orbital degrees of freedom of electrons in the presence of SOC results in the low-energy spectrum composed closely lying effective multiplets that are split by the graphene CF. Stable magnetic moment is predicted for Tb3+and Tb2+adatoms due to uniaxial magnetic anisotropy and effective anisotropy barrier around 440 cm−1controlled by the temperature assisted quantum tunneling of magnetization through the third excited doublet. On the other hand, in-plane magnetic anisotropy is found for Tb1+and Tb0adatoms. Our results indicate that the occupation of the orbitals can dramatically affect the magnetic anisotropy and magnetic moment stability of rare earth adatoms. 
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                            - Award ID(s):
- 2044049
- PAR ID:
- 10636329
- Publisher / Repository:
- Journal of Physics - Condensed Matter
- Date Published:
- Journal Name:
- Journal of Physics: Condensed Matter
- Volume:
- 37
- Issue:
- 5
- ISSN:
- 0953-8984
- Page Range / eLocation ID:
- 055803
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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