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Abstract Antiferromagnetic van der Waals‐typeM2P2X6compounds provide a versatile material platform for studying 2D magnetism and relevant phenomena. Establishing ferromagnetism in 2D materials is technologically valuable. Though magnetism is generally tunable via a chemical way, it is challenging to induce ferromagnetism with isovalent chalcogen and bimetallic substitutions inM2P2X6. Here, we report co‐substitution of Cu1+and Cr3+for Ni2+in Ni2P2S6, creating CuxNi2(1‐x)CrxP2S6medium‐entropy alloys spanning a full substitution range (x= 0 to 1). Such substitution strategy leads to a unique evolution in crystal structure and magnetic phases that are distinct from traditional isovalent bimetallic doping, with Cu and Cr co‐substitution enhancing ferromagnetic correlations and generating a weak ferromagnetic phase in intermediate compositions. This aliovalent substitution strategy offers a universal approach for tuning layered magnetism in antiferromagnetic systems, which along with the potential for light‐matter interaction and high‐temperature ferroelectricity, can enable multifunctional device applications.
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This content will become publicly available on January 29, 2026
Cr 2 TiC 2 T x MXene as an adsorbent material in ultrasonic-assisted d-μ-solid phase extraction for trace detection of heavy metals
Cr2TiC2TxMXene was used as an adsorbent for the trace determination of heavy metals in food samples, with LOD values of 0.09 and 1.9 ng mL−1, and dynamic ranges of 0.3–90 and 6–120 μg L−1for cadmium and lead ions, respectively.
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- PAR ID:
- 10636352
- Publisher / Repository:
- Royal Society of Chemistry
- Date Published:
- Journal Name:
- Nanoscale
- Volume:
- 17
- Issue:
- 5
- ISSN:
- 2040-3364
- Page Range / eLocation ID:
- 2545 to 2553
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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