An official website of the United States government
ABSTRACT Hydrologic connectivity is defined as the connection among stores of water within a watershed and controls the flux of water and solutes from the subsurface to the stream. Hydrologic connectivity is difficult to quantify because it is goverened by heterogeniety in subsurface storage and permeability and responds to seasonal changes in precipitation inputs and subsurface moisture conditions. How interannual climate variability impacts hydrologic connectivity, and thus stream flow generation and chemistry, remains unclear. Using a rare, four‐year synoptic stream chemistry dataset, we evaluated shifts in stream chemistry and stream flow source of Coal Creek, a montane, headwater tributary of the Upper Colorado River. We leveraged compositional principal component analysis and end‐member mixing to evaluate how seasonal and interannual variation in subsurface moisture conditions impacts stream chemistry. Overall, three main findings emerged from this work. First, three geochemically distinct end members were identified that constrained stream flow chemistry: reach inflows, and quick and slow flow groundwater contributions. Reach inflows were impacted by historic base and precious metal mine inputs. Bedrock fractures facilitated much of the transport of quick flow groundwater and higher‐storage subsurface features (e.g., alluvial fans) facilitated the transport of slow flow groundwater. Second, the contributions of different end members to the stream changed over the summer. In early summer, stream flow was composed of all three end members, while in late summer, it was composed predominantly of reach inflows and slow flow groundwater. Finally, we observed minimal differences in proportional composition in stream chemistry across all four years, indicating seasonal variability in subsurface moisture and spatial heterogeneity in landscape and geologic features had a greater influence than interannual climate fluctuation on hydrologic connectivity and stream water chemistry. These findings indicate that mechanisms controlling solute transport (e.g., hydrologic connectivity and flow path activation) may be resilient (i.e., able to rebound after perturbations) to predicted increases in climate variability. By establishing a framework for assessing compositional stream chemistry across variable hydrologic and subsurface moisture conditions, our study offers a method to evaluate watershed biogeochemical resilience to variations in hydrometeorological conditions.
more »
« less
This content will become publicly available on August 1, 2026
Subsurface Storage Drives Hydrologic Connectivity and Spatial Variability in Stream Chemistry
Understanding how subsurface water storage—created and structured by the geology and geomorphology of the critical zone—governs hydrologic connectivity between landscapes and streams is essential for explaining spatial and temporal variation in stream water chemistry. Most headwater studies have focused on high‐resolution stream water chemistry at the catchment outlet, rarely examining the spatial variability among tributaries and the main channel, or how these patterns relate to the underlying geology and geomorphology. Linking upstream spatial and temporal variability with chemical dynamics at the outlet over time is even less common. We conducted weekly synoptic sampling along Lookout Creek, located within the HJ Andrews Experimental Forest Long Term Ecological Research programme. Lookout Creek is in the volcanic terrain of the western Cascades, Oregon. The catchment spans multiple geologic units (e.g., lava flows) and geomorphic features (e.g., earthflows). We measured stream chemistry along the main stem and five tributaries to assess how varying degrees of hydrologic connectivity influence solute concentrations and transport across this geologic and geomorphologic template. To identify the timing and magnitude of hydrologic connectivity between tributaries, the main stem, and the catchment outlet, we analysed spatiotemporal patterns in stream chemistry using concentration‐discharge relationships, principal component analysis, and a metric of subcatchment synchrony. We found that in previously glaciated catchments with active earthflows, solute concentrations and base‐cation‐to‐silica ratios were higher, and more solutes had a chemostatic or mobilising behaviour, indicating high subsurface storage. This variability in subsurface storage, and its influence on hydrologic connectivity, ultimately determined the degree of chemical synchrony with the catchment outlet. Our findings suggest that, under future climate scenarios with shifts in precipitation phase and timing, headwater systems with substantial subsurface storage are likely to be more chemically resilient.
more »
« less
- Award ID(s):
- 2025755
- PAR ID:
- 10644590
- Publisher / Repository:
- Wiley
- Date Published:
- Journal Name:
- Hydrological Processes
- Volume:
- 39
- Issue:
- 8
- ISSN:
- 0885-6087
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Understanding how diverse headwater streams contribute water downstream is critical for accurate modelling of seasonal flow dynamics in larger systems. This study investigated how headwater catchments, with diverse subsurface storage, influence downstream flows within Lookout Creek—a 62 km2, 5th‐order catchment in the rain‐snow transition zone in western Oregon, USA. We analysed one year of hydrometric and water stable isotope data collected at 10 stream locations, complemented by a decade of precipitation isotopic data. As expected, isotopic data revealed that most of the streamflow was sourced from large fall and winter storms. Generally, stream isotope ratios decrease with elevation. However, some streams had higher isotopic values than expected, reflecting the influence of isotopically heavy storms and relatively low storage. Other streams that tended to have low flow variability in response to precipitation inputs had lower isotopic values, indicating higher elevation water sources than their topographic watershed boundaries. Both hydrometric data and water isotope‐based end‐member mixing models suggest storage differences among headwater catchments influenced the seasonal water contributions from tributaries. Most notably, the contributions of Cold and Longer Creeks, which occupy less than 10% of the Lookout Creek drainage area, sustain up to 50% of the streamflow in the summer. These catchments have high storage and high groundwater contributions, as evidenced by flat flow duration curves. Finally, our data suggest that geologic variability and geomorphic complexity (presence of earthflows and landslides) can be indicators of storage that dramatically influence water movement through the critical zone, the variation in streamflow, and the response of streams to precipitation events. Heterogeneity in headwater catchment storage is key to understanding flow dynamics in mountainous regions and the response of streams to changes in climate and other disturbances.more » « less
-
Abstract Evaluating stream water chemistry patterns provides insight into catchment ecosystem and hydrologic processes. Spatially distributed patterns and controls of stream solutes are well‐established for high‐relief catchments where solute flow paths align with surface topography. However, the controls on solute patterns are poorly constrained for low‐relief catchments where hydrogeologic heterogeneities and river corridor features, like wetlands, may influence water and solute transport. Here, we provide a data set of solute patterns from 58 synoptic surveys across 28 sites and over 32 months in a low‐relief wetland‐rich catchment to determine the major surface and subsurface controls along with wetland influence across the catchment. In this low‐relief catchment, the expected wetland storage, processing, and transport of solutes is only apparent in solute patterns of the smallest subcatchments. Meanwhile, downstream seasonal and wetland influence on observed chemistry can be masked by large groundwater contributions to the main stream channel. These findings highlight the importance of incorporating variable groundwater contributions into catchment‐scale studies for low‐relief catchments, and that understanding the overall influence of wetlands on stream chemistry requires sampling across various spatial and temporal scales. Therefore, in low‐relief wetland‐rich catchments, given the mosaic of above and below ground controls on stream solutes, modeling efforts may need to include both surface and subsurface hydrological data and processes.more » « less
-
Geologic features (e.g., fractures and alluvial fans) can play an important role in the locations and volumes of groundwater discharge and degree of groundwater-surface water (GW-SW) interactions. However, the role of these features in controlling GW-SW dynamics and streamflow generation processes are not well constrained. GW-SW interactions and streamflow generation processes are further complicated by variability in precipitation inputs from summer and fall monsoon rains, as well as declines in snowpack and changing melt dynamics driven by warming temperatures. Using high spatial and temporal resolution radon and water stable isotope sampling and a 1D groundwater flux model, we evaluated how groundwater contributions and GW-SW interactions varied along a stream reach impacted by fractures (fractured-zone) and downstream of the fractured hillslope (non- fractured zone) in Coal Creek, a Colorado River headwater stream affected by summer monsoons. During early summer, groundwater contributions from the fractured zone were high, but declined throughout the summer. Groundwater contributions from the non-fractured zone were constant throughout the summer and became proportionally more important later in the summer. We hypothesize that groundwater in the non-fractured zone is dominantly sourced from a high-storage alluvial fan at the base of a tributary that is connected to Coal Creek throughout the summer and provides consistent groundwater influx. Water isotope data revealed that Coal Creek responds quickly to incoming precipitation early in the summer, and summer precipitation becomes more important for streamflow generation later in the summer. We quantified the change in catchment dynamic storage and found it negatively related to stream water isotope values, and positively related to modeled groundwater discharge and the ratio of fractured zone to non-fractured zone groundwater. We interpret these relationships as declining hydrologic connectivity throughout the summer leading to late summer streamflow supported predominantly by shallow flow paths, with variable response to drying from geologic features based on their storage. As groundwater becomes more important for sustaining summer flows, quantifying local geologic controls on groundwater inputs and their response to variable moisture conditions may become critical for accurate predictions of streamflow.more » « less
-
Abstract Intermittent streams currently constitute >50% of the global river network, and the number of intermittent streams is expected to increase due to changes in land use and climate. Surface flows are known to expand and contract within the headwater channel network due to changes in the water table driven by climate, often changing seasonally. However, the underlying causes of disconnections and reconnections throughout the stream network remain poorly understood and may reflect subsurface flow capacity. We assess how 3D subsurface flowpaths control local surface flows at Gibson Jack Creek in the Rocky Mountains, Idaho, USA. Water table dynamics, hydraulic gradients, and hyporheic exchange were monitored along a 200‐m section of the stream throughout the seasonal recession in WY2018. Shallow lateral hillslope‐riparian‐stream connectivity was more frequent in transects spanning perennially flowing stream reaches than intermittent reaches. During low‐flow periods, larger losing vertical hydraulic gradients were observed in paired piezometers in intermittent reaches than in adjacent perennial reaches. Contrary to dominant conceptual models, longitudinal measurements of hydrologic exchange in both intermittent and perennial reaches were seasonally variable except for one perennial reach that showed consistent significant gains. Observed drying dynamics, as well as subsurface pathways, were highly variable even over short distances (30 m). Flow probability and subsurface flow capacity at upstream locations can be assessed with an outlet hydrograph and upstream flow measurements. Accurate characterization of subsurface storage, discharge, and connection is critical to understanding the drivers of drying cycles in intermittent streams and their likely responses to future change.more » « less
