Abstract The sensitivity of urban canopy air temperature ( ) to anthropogenic heat flux ( ) is known to vary with space and time, but the key factors controlling such spatiotemporal variabilities remain elusive. To quantify the contributions of different physical processes to the magnitude and variability of (where represents a change), we develop a forcing-feedback framework based on the energy budget of air within the urban canopy layer and apply it to diagnosing simulated by the Community Land Model Urban over the contiguous United States (CONUS). In summer, the median is around 0.01 over the CONUS. Besides the direct effect of on , there are important feedbacks through changes in the surface temperature, the atmosphere–canopy air heat conductance ( ), and the surface–canopy air heat conductance. The positive and negative feedbacks nearly cancel each other out and is mostly controlled by the direct effect in summer. In winter, becomes stronger, with the median value increased by about 20% due to weakened negative feedback associated with . The spatial and temporal (both seasonal and diurnal) variability of as well as the nonlinear response of to are strongly related to the variability of , highlighting the importance of correctly parameterizing convective heat transfer in urban canopy models.
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Nucleation kinetics and virtual melting in shear-induced structural transitions
Abstract Large shear deformations can induce structural changes within crystals, yet the microscopic kinetics underlying these transformations are difficult for experimental observation and theoretical understanding. Here, we drive shear-induced structural transitions from square ( ) lattices to triangular ( ) lattices in thin-film colloidal crystals and directly observe the accompanying kinetics with single-particle resolution inside the bulk crystal. When the oscillatory shear strain amplitude , -lattice nuclei are surrounded by a liquid layer throughout their growth due to localized shear strain at the interface. Such virtual melting at crystalline interface has been predicted in theory and simulation, but have not been observed in experiment. The mean liquid layer thickness is proportional to the shear which can be explained by the Lindemann melting criterion. This provides an alternative explanation on virtual melting.
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- Award ID(s):
- 2003659
- PAR ID:
- 10645283
- Publisher / Repository:
- IOP Publishing
- Date Published:
- Journal Name:
- Reports on Progress in Physics
- Volume:
- 88
- Issue:
- 1
- ISSN:
- 0034-4885
- Page Range / eLocation ID:
- 010501
- Subject(s) / Keyword(s):
- Colloids, Nucleation, Shear, Phase Transformations
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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