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  1. Illumination of aerobic acetonitrile solutions of bipyridine-ligated Co(ii) chlorodiketonate complexes results in O2-dependent aliphatic C–C bond cleavage with high18O incorporation. 
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  2. A pincer iron(iii) catalyst for the oxidation and chlorination of C(sp3)–H bonds was developed. 
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  3. null (Ed.)
    We report synthetic, structural and reactivity investigations of tris-(2-pyridylmethyl)amine (TPA)-ligated Cu( ii ) 1,3-diketonate complexes. These complexes exhibit anaerobic retro-Claisen type C–C bond cleavage reactivity which exceeds that found in analogs supported by chelate ligands with fewer and/or weaker pyridyl interactions. 
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  4. null (Ed.)