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Published Sn isotope data along with 150 new analyses of cassiterite and four granite analyses constrain two major tin isotope fractionation steps associated with (1) separation of tin from the magma/orthomagmatic transitional environment and (2) hydrothermal activity. A distinct Sn isotope difference across deposit type, geological host rocks, and time of ore deposit formation demonstrates that the difference in the mean δ124Sn value represents the operation of a unified process. The lower Sn isotope values present in both residual igneous rocks and pegmatite suggest that heavier Sn isotopes were extracted from the system during orthomagmatic fluid separation, likely by F ligands with Sn. Rayleigh distillation models this first F ligand-induced fractionation. The subsequent development of the hydrothermal system is characterized by heavier Sn isotope composition proximal to the intrusion, which persists in spite of Sn isotope fractionating towards isotopically lighter Sn during hydrothermal evolution. 

Geologic reconstructions of overwash events can extend storm records beyond the brief instrumental record. However, the return periods of storms calculated from geologic records alone may underestimate the frequency of events given the preservation bias of geologic records. Here, we compare a geologic reconstruction of storm activity from a salt marsh in New Jersey to two neighboring instrumental records at the Sandy Hook and Battery tide gauges. Eight overwash deposits were identified within the marsh's stratigraphy by their fan‐shaped morphology and coarser mean grain size (3.6 ± 0.7 φ) compared to autochthonous sediments they were embedded in (5.6 ± 0.8 φ). We used an age–depth model based on modern chronohorizons and three radiocarbon dates to provide age constraints for the overwash deposits. Seven of the overwash deposits were attributed to historical storms, including the youngest overwash deposit from Hurricane Sandy in 2012. The four youngest overwash deposits overlap with instrumental records. In contrast, the Sandy Hook and Battery tide gauges recorded eight and 11 extreme water levels above the 10% annual expected probability (AEP) of exceedance level, respectively, between 1932/1920 and the present. The geologic record in northern New Jersey, therefore, has a 36–50% preservation potential of capturing extreme water levels above the 10% AEP level. 

Ti-isotope fractionation on the most Ti-rich minerals on Earth has not been reported. Therefore, we present a chemical preparation and separation technique for Ti-rich minerals for mineralogic, petrologic, and economic geologic studies. A two-stage ion-exchange column procedure modified from the previous literature is used in the current study to separate Ti from Fe-rich samples, while α-TiO2 does not require chemical separation. Purified solutions in conjunction with solution standards were measured on two different instruments with dry plasma and medium-resolution mode providing mass-dependent results with the lowest errors. 49/47TiOL-Ti for the solution and solids analyzed here demonstrate a range of >5‰ far greater than the whole procedural 1 error of 0.10‰ for a synthetic compound and 0.07‰ for the mineral magnetite; thus, the procedure produces results is resolvable within the current range of measured Ti-isotope fractionation in these minerals. 

turnovers culminating in the so-called End-Triassic Extinction. We attribute onset of this interval of declining diversity to unusually high volcanic activity at the Norian/Rhaetian boundary (NRB) that may have initiated the stepwise extinctions of the Late Triassic [1]. We correlate the initiation of a rapid decline in 87Sr/86Sr and 187Os/188Os seawater values [2, 3] to a negative organic carbon isotope shift, which we attribute to volcanogenic CO2 outgassing to the ocean-atmosphere system by the Angayucham large igneous province (LIP). By studying the geochemical and isotope composition of bulk rocks from different sections located at different latitudes, sides of the Pangea continent and Hemispheres, we documented an accelerated chemical weathering due to global warming by elevated CO2, which enhanced nutrient discharge to the oceans and thus greatly increased biological productivity; higher export production and oxidation of organic matter led to oceanic dysoxia to anoxia at the NRB. Biotic consequences of these climatic and environmental changes include severe extinctions of several fossil groups, such as ammonoids, bivalves and radiolarians, as has been documented worldwide [1]. 

Abstract Numerous geochemical anomalies exist at the K-Pg boundary that indicate the addition of extraterrestrial materials; however, none fingerprint volatilization, a key process that occurs during large bolide impacts. Stable Zn isotopes are an exceptional indicator of volatility-related processes, where partial vaporization of Zn leaves the residuum enriched in its heavy isotopes. Here, we present Zn isotope data for sedimentary rock layers of the K-Pg boundary, which display heavier Zn isotope compositions and lower Zn concentrations relative to surrounding sedimentary rocks, the carbonate platform at the impact site, and most carbonaceous chondrites. Neither volcanic events nor secondary alteration during weathering and diagenesis can explain the Zn concentration and isotope signatures present. The systematically higher Zn isotope values within the boundary layer sediments provide an isotopic fingerprint of partially evaporated material within the K-Pg boundary layer, thus earmarking Zn volatilization during impact and subsequent ejecta transport associated with an impact at the K-Pg. 

Abstract Submarine groundwater discharge is increasingly recognized as an important component of the oceanic geochemical budget, but knowledge of the distribution of this phenomenon is limited. To date, reports of meteoric inputs to marine sediments are typically limited to shallow shelf and coastal environments, whereas contributions of freshwater along deeper sections of tectonically active margins have generally been attributed to silicate diagenesis, mineral dehydration, or methane hydrate dissociation. Here, using geochemical fingerprinting of pore water data from Site J1003 recovered from the Chilean Margin during D/V JOIDES Resolution Expedition 379 T, we show that substantial offshore freshening reflects deep and focused contributions of meteorically modified geothermal groundwater, which is likely sourced from a reservoir ~2.8 km deep in the Aysén region of Patagonia and infiltrated marine sediments during or shortly after the last glacial period. Emplacement of fossil groundwaters reflects an apparently ubiquitous phenomenon in margin sediments globally, but our results now identify an unappreciated locus of deep submarine groundwater discharge along active margins with potential implications for coastal biogeochemical processes and tectonic instability. 

Isotopic analyses of human remains augment the biological profile with geolocation and dietary information, furthering efforts to identify unknown individuals from a forensic context. Here we test the methodological resolution of geolocation (δ18O, 87Sr/86Sr) and dietary (δ13C, δ15N) isotopes of one identified individual who immigrated to New York City from St. Vincent and the Grenadines (SVG), Lesser Antilles. Isotope-based geolocation estimates did not identify the childhood residency on SVG, but did point to New York City as a possible residence during early adulthood. The individual’s C3-based diet did not significantly change from childhood to early adulthood, illustrating the maintenance of food traditions after the immigration event. This study illustrates that further development of tissue-specific isoscapes incorporating bioavailable foods, drinking water, and cultural traditions is warranted to refine methodological resolution of isotopic applications in forensic anthropology.