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Abstract Germanates are often used as structural analogs of planetary silicates. We have explored the high-pressure phase relations in Mg2GeO4 using diamond-anvil cell experiments combined with synchrotron X-ray diffraction and computations based on density functional theory. Upon room temperature compression, forsterite-type Mg2GeO4 remains stable up to 30 GPa. At higher pressures, a phase transition to a forsterite-III type (Cmc21) structure was observed, which remained stable to the peak pressure of 105 GPa. Using a third-order Birch Murnaghan fit to the experimental data, we obtained V0 = 305.1(3) Å3, K0 = 124.6(14) GPa, and K0′ = 3.86 (fixed) for forsterite-type Mg2GeO4 and V0 = 263.5(15) Å3, K0 = 175(7) GPa, and K0′ = 4.2 (fixed) for the forsterite-III type phase. The forsterite-III type structure was found to be metastable when compared to the stable assemblage of perovskite/post-perovskite + MgO, as observed during laser-heating experiments. Understanding the phase relations and physical properties of metastable phases is crucial for studying the mineralogy of impact sites, understanding metastable wedges in subducting slabs, and interpreting the results of shock compression experiments. 

Abstract On the Greenland Ice Sheet, hydrofracture connects the supraglacial and subglacial hydrologic systems, coupling surface runoff dynamics and ice velocity. In recent decades, the growth of low-permeability ice slabs in the wet snow zone has expanded Greenland's runoff zone, but observations suggest that surface-to-bed connections are rare, because meltwater drains through crevasses into the porous firn beneath ice slabs. However, there is little quantitative evidence confirming the absence of surface-to-bed fracture propagation. Here, we use poromechanics to investigate whether water-filled crevasses in ice slabs can propagate vertically through an underlying porous firn layer. Based on numerical simulations, we develop an analytical estimate of the water injection-induced effective stress in the firn given the water level in the crevasse, ice slab thickness, and firn properties. We find that the firn layer substantially reduces the system's vulnerability to hydrofracture because much of the hydrostatic stress is accommodated by a change in pore pressure, rather than being transmitted to the solid skeleton. This result suggests that surface-to-bed hydrofracture will not occur in ice slab regions until all pore space proximal to the initial flaw has been filled with solid ice. 

Abstract Iceberg calving is a major contributor to Greenland’s ice mass loss. Ice mélange, tightly packed sea ice and icebergs, has been hypothesized to buttress the calving fronts. However, quantifying the mélange buttressing force from field observations remains a challenge. Here we show that such quantification can be achieved with a single field measurement: thickness of mélange at the glacier terminus. We develop the first three-dimensional discrete element model of m´elange along with a simple analytical model to quantify the mélange buttressing using mélange thickness data from ArcticDEM over 32 Greenland glacier termini. We observed a strong seasonality in mélange thickness: thin mélange (averaged thickness 34⁺¹⁷₋₁₅m) in summertime when terminus retreats, and thick mélange (averaged thickness 119⁺³¹₋₃₇m) in wintertime when terminus advances. The observed seasonal changes of mélange thickness strongly coincide with observed Greenland calving dynamics and the modeled buttressing effects. 

Pressure is a unique tuning parameter for probing the properties of materials, and it has been particularly useful for studies of electronic materials such as high-temperature cuprate superconductors. Here we report the effects of quasihydrostatic compression produced by a neon pressure medium on the structures of bismuth-based high-Tc cuprate superconductors with the nominal composition Bi2Sr2Can−1CunO2n+4+δ (n = 1, 2, 3) up to 155 GPa. The structures of all three compositions obtained by synchrotron x-ray diffraction can be described as pseudotetragonal over the entire pressure range studied. We show that previously reported pressure-induced distortions and structural changes arise from the large strains that can be induced in these layered materials by nonhydrostatic stresses. The pressure-volume equations of state (EOS) measured under these quasihydrostatic conditions cannot be fit to single phenomenological formulation over the pressure ranges studied, starting below 20 GPa. This intrinsic anomalous compression as well as the sensitivity of Bi2Sr2Can−1CunO2n+4+δ to deviatoric stresses provide explanations for the numerous inconsistencies in reported EOS parameters for these materials. We conclude that the anomalous compressional behavior of all three compositions is a manifestation of the changes in electronic properties that are also responsible for the remarkable nonmonotonic dependence of Tc with pressure, including the increase in Tc at the highest pressures studied so far for each. Transport and spectroscopic measurements up to megabar pressures are needed to fully characterize these cuprates and explore higher possible critical temperatures in these materials.