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Sulfuryl fluoride (SO₂F₂) is a synthetic pesticide and a potent greenhouse gas that is accumulating in the global atmosphere. Rising emissions are a concern since SO₂F₂has a relatively long atmospheric lifetime and a high global warming potential. The U.S. is thought to contribute substantially to global SO₂F₂emissions, but there is a paucity of information on how emissions of SO₂F₂are distributed across the U.S., and there is currently no inventory of SO₂F₂emissions for the U.S. or individual states. Here we provide an atmospheric measurement-based estimate of U.S. SO₂F₂emissions using high-precision SO₂F₂measurements from the NOAA Global Greenhouse Gas Reference Network (GGGRN) and a geostatistical inverse model. We find that California has the largest SO₂F₂emissions among all U.S. states, with the highest emissions from southern coastal California (Los Angeles, Orange, and San Diego counties). Outside of California, only very small and infrequent SO₂F₂emissions are detected by our analysis of GGGRN data. We find that California emits 60-85% of U.S. SO₂F₂emissions, at a rate of 0.26 ( ± 0.10) Gg yr⁻¹. We estimate that emissions of SO₂F₂from California are equal to 5.5–12% of global SO₂F₂emissions.

 

While prior work has explored many proposed datacenter designs, only two designs, Clos-based and expander-based, are generally considered practical because they can scale using commodity switching chips. Prior work has used two diferent metrics, bisection band- width and throughput, for evaluating these topologies at scale. Little is known, theoretically or practically, how these metrics relate to each other. Exploiting characteristics of these topologies, we prove an upper bound on their throughput, then show that this upper bound better estimates worst-case throughput than all previously proposed throughput estimators and scales better than most of them. Using this upper bound, we show that for expander-based topologies, unlike Clos, beyond a certain size of the network, no topology can have full throughput, even if it has full bisection band- width; in fact, even relatively small expander-based topologies fail to achieve full throughput. We conclude by showing that using throughput to evaluate datacenter performance instead of bisection bandwidth can alter conclusions in prior work about datacenter cost, manageability, and reliability. 

Solar‐induced chlorophyll fluorescence (SIF) shows enormous promise as a proxy for photosynthesis and as a tool for modeling variability in gross primary productivity and net biosphere exchange (NBE). In this study, we explore the skill of SIF and other vegetation indicators in predicting variability in global atmospheric CO₂observations, and thus global variability in NBE. We do so using a 4‐year record of CO₂observations from NASA's Orbiting Carbon Observatory 2 satellite and using a geostatistical inverse model. We find that existing SIF products closely correlate with space‐time variability in atmospheric CO₂observations, particularly in the extratropics. In the extratropics, all SIF products exhibit greater skill in explaining variability in atmospheric CO₂observations compared to an ensemble of process‐based CO₂flux models and other vegetation indicators. With that said, other vegetation indicators, when multiplied by photosynthetically active radiation, yield similar results as SIF and may therefore be an effective structural SIF proxy at regional to global spatial scales. Furthermore, we find that using SIF as a predictor variable in the geostatistical inverse model shifts the seasonal cycle of estimated NBE and yields an earlier end to the growing season relative to other vegetation indicators. These results highlight how SIF can help constrain global‐scale variability in NBE.

 

Most recent datacenter topology designs have focused on performance properties such as latency and throughput. In this paper, we explore a new dimension, life cycle management complexity, which attempts to understand the complexity of deploying a topology and expanding it. By analyzing current practice in lifecycle management, we devise complexity metrics for lifecycle management, and show that existing topology classes have low lifecycle management complexity by some measures, but not by others. Motivated by this, we design a new class of topologies, FatClique, that, while being performance-equivalent to existing topologies, is comparable to, or better than them by all our lifecycle management complexity metrics. 

Creating single‐molecule junctions with a long‐lived lifetime at room temperature is an open challenge. Finding simple and efficient approaches to increase the durability of single‐molecule junction is also of practical value in molecular electronics. Here it is shown that a flexible gold‐coated nanopipette electrode can be utilized in scanning tunneling microscope (STM) break‐junction measurements to efficiently enhance the stability of molecular junctions by comparing with the measurements using conventional solid gold probes. The stabilizing effect of the flexible electrode displays anchor group dependence, which increases with the binding energy between the anchor group and gold. An empirical model is proposed and shows that the flexible electrode could promote stable binding geometries at the gold‐molecule interface and slow down the junction breakage caused by the external perturbations, thereby extending the junction lifetime. Finally, it is demonstrated for the first time that the internal conduit of the flexible STM tip can be utilized for the controlled molecule delivery and molecular junction formation.