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We present results from conducting a theoretical chemical analysis of a sample of benchmark companion brown dwarfs whose primary star is of type F, G, or K. We summarize the entire known sample of these types of companion systems, termed “compositional benchmarks,” that are present in the literature or recently published as key systems of study in order to best understand brown dwarf chemistry and condensate formation. Via mass balance and stoichiometric calculations, we predict a median brown dwarf atmospheric oxygen sink of${17.8}_{-2.3}^{+1.7}\%$by utilizing published stellar abundances in the local solar neighborhood. Additionally, we predict a silicate condensation sequence such that atmospheres with bulk Mg/Si ≲0.9 will form enstatite (MgSiO₃) and quartz (SiO₂) clouds, and atmospheres with bulk Mg/Si ≳0.9 will form enstatite and forsterite (Mg₂SiO₄) clouds. The implications of these results on C/O ratio trends in substellar-mass objects and the utility of these predictions in future modeling work are discussed.

Brown dwarf spectra offer vital testbeds for our understanding of the chemical and physical processes that sculpt substellar atmospheres. Recently, atmospheric retrieval approaches have been successfully applied to low-resolution (R∼ 100) spectra of L, T, and Y dwarfs, yielding constraints on the chemical abundances and temperature structures of these atmospheres. Medium-resolution (R∼ 10³) spectra of brown dwarfs offer additional insight, as molecular features are more easily disentangled and the thermal structure of the upper atmosphere is better probed. We present results from a GPU-based retrieval analysis of a high signal-to-noise, medium-resolution (R∼ 6000) FIRE spectrum from 0.85 to 2.5μm of the T9 dwarf UGPS J072227.51–054031.2. At 60× higher spectral resolution than previous brown dwarf retrievals, a number of novel challenges arise. We examine the effect of different opacity sources, in particular for CH₄. Furthermore, we find that flaws in the data like errors from order stitching can bias our constraints. We compare these retrieval results to those for anR∼ 100 spectrum of the same object, revealing how constraints on atmospheric abundances and temperatures improve by an order of magnitude or more with increased spectral resolution. In particular, we can constrain the abundance of H₂S, which is undetectable at lower spectral resolution. While these medium-resolution retrievals offer the potential of precise, stellar-like constraints on atmospheric abundances (∼0.02 dex), our retrieved radius is unphysically small ($R={0.50}_{-0.01}^{+0.01}$R_Jup), indicating shortcomings with our modeling framework. This work is an initial investigation into brown dwarf retrievals at medium spectral resolution, offering guidance for future ground-based studies and JWST observations.

Using a sample of 361 nearby brown dwarfs, we have searched for 4.6μm variability, indicative of large-scale rotational modulations or large-scale, long-term changes on timescales of over 10 yr. Our findings show no statistically significant variability in Spitzer’s Infrared Array Camera (IRAC) channel 2 (ch2) or Wide-field Infrared Survey Explorer W2 photometry. For Spitzer the ch2 1σlimits are ∼8 mmag for objects at 11.5 mag and ∼22 mmag for objects at 16 mag. This corresponds to no variability above 4.5% at 11.5 mag and 12.5% at 16 mag. We conclude that highly variable brown dwarfs, at least two previously published examples of which have been shown to have 4.6μm variability above 80 mmag, are very rare. While analyzing the data, we also developed a new technique for identifying brown dwarf binary candidates in Spitzer data. We find that known binaries have IRAC ch2 point response function (PRF) flux measurements that are consistently dimmer than aperture flux measurements. We have identified 59 objects that exhibit such PRF versus aperture flux differences and are thus excellent binary brown dwarf candidates.

At the lowest masses, the distinction between brown dwarfs and giant exoplanets is often blurred and literature classifications rarely reflect the deuterium burning boundary. Atmospheric characterization may reveal the extent to which planetary formation pathways contribute to the population of very low mass brown dwarfs, by revealing whether their abundance distributions differ from those of the local field population or, in the case of companions, their primary stars. The T8 dwarf Ross 458c is a possible planetary-mass companion to a pair of M dwarfs, and previous work suggests that it is cloudy. We here present the results of the retrieval analysis of Ross 458c, using archival spectroscopic data in the 1.0–2.4 µm range. We test a cloud-free model as well as a variety of cloudy models and find that the atmosphere of Ross 458c is best described by a cloudy model (strongly preferred). The CH4/H2O is higher than expected at $1.97^{+0.13}_{-0.14}$. This value is challenging to understand in terms of equilibrium chemistry and plausible carbon-to-oxygen (C/O) ratios. Comparisons to thermochemical grid models suggest a C/O of ≈1.35, if CH4 and H2O are quenched at 2000 K, requiring vigorous mixing. We find a [C/H] ratio of +0.18, which matches the metallicity of the primary system, suggesting that oxygen is missing from the atmosphere. Even with extreme mixing, the implied C/O is well beyond the typical stellar regime, suggesting either a non-stellar formation pathway or the sequestration of substantial quantities of oxygen via hitherto unmodelled chemistry or condensation processes.

Y dwarfs, the coolest known spectral class of brown dwarfs, overlap in mass and temperature with giant exoplanets, providing unique laboratories for studying low-temperature atmospheres. However, only a fraction of Y dwarf candidates have been spectroscopically confirmed. We present Keck/NIRES near-infrared spectroscopy of the nearby (d≈ 6–8 pc) brown dwarf CWISE J105512.11+544328.3. Although its near-infrared spectrum aligns best with the Y0 standard in theJband, no standard matches well across the fullYJHKwavelength range. The CWISE J105512.11+544328.3 NH₃-H= 0.427 ± 0.0012 and CH₄-J= 0.0385 ± 0.0007 absorption indices and absolute Spitzer [4.5] magnitude of 15.18 ± 0.22 are also indicative of an early-Y dwarf rather than a late-T dwarf. CWISE J105512.11+544328.3 additionally exhibits the bluest Spitzer [3.6]−[4.5] color among all spectroscopically confirmed Y dwarfs. Despite this anomalously blue Spitzer color given its low luminosity, CWISE J105512.11+544328.3 does not show other clear kinematic or spectral indications of low metallicity. Atmospheric model comparisons yield a log(g) ≤ 4.5 andT_eff≈ 500 ± 150 K for this source. We classify CWISE J105512.11+544328.3 as a Y0 (pec) dwarf, adding to the remarkable diversity of the Y-type population. JWST spectroscopy would be crucial to understanding the origin of this Y dwarf’s unusual preference for low-gravity models and blue 3–5μm color.

We present results from an atmospheric retrieval analysis of Gl 229B using the Brewster retrieval code. We find the best fit model to be cloud-free, consistent with the T dwarf retrieval work of Line et al.; Zalesky et al. and Gonzales et al. Fundamental parameters (mass, radius, log(L_Bol/L_Sun), log(g)) determined from our model agree within 1σto SED-derived values, except forT_effwhere our retrievedT_effis approximately 100 K cooler than the evolutionary model-based SED value. We find a retrieved mass of${50}_{-9}^{+12}$M_Jup, however, we also find that the observables of Gl 229B can be explained by a cloud-free model with a prior on mass at the dynamical value, 70M_Jup. We are able to constrain abundances for H₂O, CO, CH₄, NH₃, Na and K and find a supersolar C/O ratio as compared to its primary, Gl 229A. We report an overall subsolar metallicity due to atmospheric oxygen depletion, but find a solar [C/H], which matches that of the primary. We find that this work contributes to a growing trend in retrieval-based studies, particularly for brown dwarfs, toward supersolar C/O ratios and discuss the implications of this result on formation mechanisms and internal physical processes, as well as model biases.

We present the analysis of two unusually red L dwarfs, CWISE J075554.14−325956.3 (W0755−3259) and CWISE J165909.91−351108.5 (W1659−3511), confirmed by their newly obtained near-infrared spectra collected with the TripleSpec4 spectrograph on the Southern Astrophysical Research Telescope. We classify W0755−3259 as an L7 very low-gravity dwarf, exhibiting extreme redness with a characteristic peakedH-band and spectral indices typical of low-gravity late-type L dwarfs. We classify W1659-3511 as a red L7 field-gravity dwarf, with a more roundedH-band peak and spectral indices that support a normal gravity designation. W1659−3511 is noticeably fainter than W0755−3259, and the roundedH-band of W1659−3511 may be evidence of CH₄absorption.

We present spectroscopic confirmation of a nearby L dwarf pair, CWISE J061741.79+194512.8AB. Keck/NIRES near-infrared spectroscopy shows that the pair is composed of an L2 dwarf primary and an L4 dwarf secondary. High resolution spectroscopy of the combined light system with Keck/NIRSPEC yields a radial velocity of 29.2 ± 0.3 km s⁻¹and a projected rotational velocity$v\sin i$=${41.6}_{-2.6}^{+2.7}$km s⁻¹. Our spectrophotometric distance estimate places the system at 28.2 ± 5.7 pc, significantly more distant than originally estimated in Kirkpatrick et al. The angular separation of the components is 1.″31 ± 0.″14, corresponding to a projected physical separation of 37 ± 8 au.

Comparisons of atmospheric retrievals can reveal powerful insights on the strengths and limitations of our data and modeling tools. In this paper, we examine a sample of five L dwarfs of similar effective temperature (T_eff) or spectral type to compare their pressure–temperature (P-T) profiles. Additionally, we explore the impact of an object’s metallicity and the signal-to-noise ratio (S/N) of the observations on the parameters we can retrieve. We present the first atmospheric retrievals: 2MASS J15261405+2043414, 2MASS J05395200−0059019, 2MASS J15394189−0520428, and GD 165B increasing the small but growing number of L dwarfs retrieved. When compared to the atmospheric retrievals of SDSS J141624.08+134826.7, a low-metallicity d/sdL7 primary in a wide L+T binary, we find that similarT_effsources have similar P-T profiles with metallicity differences impacting the relative offset between their P-T profiles in the photosphere. We also find that for near-infrared spectra, when the S/N is ≳80 we are in a regime where model uncertainties dominate over data measurement uncertainties. As such, S/N does not play a role in the retrieval’s ability to distinguish between a cloud-free and cloudless model, but may impact the confidence of the retrieved parameters. Lastly, we also discuss how to break cloud model degeneracies and the impact of extraneous gases in a retrieval model.

We present an atmospheric retrieval analysis of a pair of highly variable, ∼200 Myr old, early T type planetary-mass exoplanet analogs SIMP J01365662+0933473 and 2MASS J21392676+0220226 using the Brewster retrieval framework. Our analysis, which makes use of archival 1–15μm spectra, finds almost identical atmospheres for both objects. For both targets, we find that the data is best described by a patchy, high-altitude forsterite (Mg₂SiO₄) cloud above a deeper, optically thick iron (Fe) cloud. Our model constrains the cloud properties well, including the cloud locations and cloud particle sizes. We find that the patchy forsterite slab cloud inferred from our retrieval may be responsible for the spectral behavior of the observed variability. Our retrieved cloud structure is consistent with the atmospheric structure previously inferred from spectroscopic variability measurements, but clarifies this picture significantly. We find consistent C/O ratios for both objects, which supports their formation within the same molecular cloud in the Carina-Near moving group. Finally, we note some differences in the constrained abundances of H₂O and CO, which may be caused by data quality and/or astrophysical processes such as auroral activity and their differing rotation rates. The results presented in this work provide a promising preview of the detail with which we will characterize extrasolar atmospheres with JWST, which will yield higher-quality spectra across a wider wavelength range.