Search for: All records

Cosmogenic nuclide techniques have advanced the geosciences by providing tools for exposure age dating, burial dating, quantification of denudation rates and more. Advances in geochemistry, accelerator mass spectrometry and atom trap trace analyses are ushering in a new cosmogenic nuclide era, by improving the sensitivity of measurements to ultra- trace levels that now allow new applications of these techniques to numerous Earth surface processes. The advances in cosmogenic nuclide techniques have equipped the next generation of geoscientists with invaluable tools for understanding the planet, but addressing pressing needs requires rising to an even greater challenge: imbuing within the cosmogenic community, and the geosciences as a whole, a commitment to justice, equity, diversity and inclusion that matches our dedication to scientific research. In this Primer, we review the state of the art and recent exciting breakthroughs in the use of cosmogenic nuclide techniques, focusing on erosion factories over space and time, and new perspectives on ice sheet stability. We also highlight promising ways forward in enhancing inclusion in the field, as well as obstacles that remain to be overcome. 

It might be highly effective if students could transition dynamically between individual and collaborative learning activities, but how could teachers manage such complex classroom scenarios? Although recent work in AIED has focused on teacher tools, little is known about how to orchestrate dynamic transitions between individual and collaborative learning. We created a novel technology ecosystem that supports these dynamic transitions. The ecosystem integrates a novel teacher orchestration tool that provides monitoring support and pairing suggestions with two AI-based tutoring systems that support individual and collaborative learning, respectively. We tested the feasibility of this ecosystem in a classroom study with 5 teachers and 199 students over 22 class sessions. We found that the teachers were able to manage the dynamic transitions and valued them. The study contributes a new technology ecosystem for dynamically transitioning between individual and collaborative learning, plus insight into the orchestration functionality that makes these transitions feasible. 

Ionic reactions are the most common reactions used in chemical synthesis. In relatively low dielectric constant solvents (e.g., dichloromethane, toluene), ions usually exist as ion pairs. Despite the importance of counterions, a quantitative description of how the paired ’counterion’ affects the reaction kinetic is still elusive. We introduce a general and quantitative model, namely transition-state expansion (TSE), that describes how the size of a counterion affects the transition- state structure and the kinetics of an ionic reaction. This model could rationalize the counterion effects in nucleophilic substitutions and gold-catalyzed enyne cycloisomerizations. 

How oxygen levels in Earth’s atmosphere and oceans evolved has always been a central question in Earth System Science. Researchers have developed numerous tracers to tackle this question, utilizing geochemical characteristics of different elements. Iodine incorporated in calcium carbonate (including biogenic) minerals, reported as I/Ca, is a proxy for dissolved oxygen in seawater. Here we review the rationale behind this proxy, its recent applications, and some potential future research directions.