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The Cenozoic era (66 to 0 million years) is marked by long-term aberrations in carbon cycling and large climatic shifts, some of which challenge the current understanding of carbon cycle dynamics. Here, we investigate possible mechanisms responsible for the observed long-term trends by using a novel approach that features a full-fledged ocean carbonate chemistry model. Using a compilation of pCO 2 , pH, and calcite compensation depth (CCD) observational evidence and a suite of simulations, we reconcile long-term Cenozoic climate and CCD trends. We show that the CCD response was decoupled from changes in silicate and carbonate weathering rates, challenging the continental uplift hypothesis. The two dominant mechanisms for decoupling are shelf-basin carbonate burial fractionation combined with proliferation of pelagic calcifiers. The temperature effect on remineralization rates of marine organic matter also plays a critical role in controlling the carbon cycle dynamics, especially during the warmer periods of the Cenozoic. 

Astronomical calculations reveal the Solar System’s dynamical evolution, including its chaoticity, and represent the backbone of cyclostratigraphy and astrochronology. An absolute, fully calibrated astronomical time scale has hitherto been hampered beyond ~50 million years before the present (Ma) because orbital calculations disagree before that age. Here, we present geologic data and a new astronomical solution (ZB18a) showing exceptional agreement from ~58 to 53 Ma. We provide a new absolute astrochronology up to 58 Ma and a new Paleocene–Eocene boundary age (56.01 ± 0.05 Ma). We show that the Paleocene–Eocene Thermal Maximum (PETM) onset occurred near a 405-thousand-year (kyr) eccentricity maximum, suggesting an orbital trigger. We also provide an independent PETM duration (170 ± 30 kyr) from onset to recovery inflection. Our astronomical solution requires a chaotic resonance transition at ~50 Ma in the Solar System’s fundamental frequencies. 

Abstract. Cenozoic stable carbon (δ13C) and oxygen (δ18O)isotope ratios of deep-sea foraminiferal calcite co-vary with the 405 kyreccentricity cycle, suggesting a link between orbital forcing, the climatesystem, and the carbon cycle. Variations in δ18O are partlyforced by ice-volume changes that have mostly occurred since the Oligocene.The cyclic δ13C–δ18O co-variation is found inboth ice-free and glaciated climate states, however. Consequently, thereshould be a mechanism that forces the δ13C cyclesindependently of ice dynamics. In search of this mechanism, we simulate theresponse of several key components of the carbon cycle to orbital forcing inthe Long-term Ocean-atmosphere-Sediment CArbon cycle Reservoir model(LOSCAR). We force the model by changing the burial of organic carbon in theocean with various astronomical solutions and noise and study the responseof the main carbon cycle tracers. Consistent with previous work, thesimulations reveal that low-frequency oscillations in the forcing arepreferentially amplified relative to higher frequencies. However, whileoceanic δ13C mainly varies with a 405 kyr period in themodel, the dynamics of dissolved inorganic carbon in the oceans and ofatmospheric CO2 are dominated by the 2.4 Myr cycle of eccentricity.This implies that the total ocean and atmosphere carbon inventory is stronglyinfluenced by carbon cycle variability that exceeds the timescale of the405 kyr period (such as silicate weathering). To test the applicability ofthe model results, we assemble a long (∼22 Myr) δ13C andδ18O composite record spanning the Eocene to Miocene(34–12 Ma) and perform spectral analysis to assess the presence of the2.4 Myr cycle. We find that, while the 2.4 Myr cycle appears to beovershadowed by long-term changes in the composite record, it is present asan amplitude modulator of the 405 and 100 kyr eccentricity cycles.