Search for: All records

Porphyry ore deposits, Earth’s most important resources of copper, molybdenum, and rhenium, are strongly associated with felsic magmas showing signs of high-pressure differentiation and are usually found in places with thickened crust (>45 kilometers). This pattern is well-known, but unexplained, and remains an outstanding problem in our understanding of porphyry ore deposit formation. We approach this problem by investigating the oxidation state of magmatic sulfur, which controls the behavior of ore-forming metals during magma differentiation and magmatic-hydrothermal transition. We use sulfur in apatite to reconstruct the sulfur oxidation state in the Gangdese batholith, southern Tibet. We find that magma sulfate content increased abruptly after India-Eurasia collision. Apatite sulfur content and the calculated magma S 6+ /ΣS ratio correlate with whole-rock dysprosium/ytterbium ratio, suggesting that residual garnet, favored in thickened crust, exerts a first-order control on sulfur oxidation in magmatic orogens. Our findings link sulfur oxidation to internal petrogenic processes and imply an intrinsic relationship of magma oxidation with synmagmatic crustal thickening. 

Pegmatites are shallow, coarse-grained magmatic intrusions with crystals occasionally approaching meters in length. Compared to their plutonic hosts, pegmatites are thought to have cooled rapidly, suggesting that these large crystals must have grown fast. Growth rates and conditions, however, remain poorly constrained. Here we investigate quartz crystals and their trace element compositions from miarolitic cavities in the Stewart pegmatite in southern California, USA, to quantify crystal growth rates. Trace element concentrations deviate considerably from equilibrium and are best explained by kinetic effects associated with rapid crystal growth. Kinetic crystal growth theory is used to show that crystals accelerated from an initial growth rate of 10−6–10−7 m s−1 to 10−5–10−4 m s−1 (10-100 mm day−1 to 1–10 m day−1), indicating meter sized crystals could have formed within days, if these rates are sustained throughout pegmatite formation. The rapid growth rates require that quartz crystals grew from thin (micron scale) chemical boundary layers at the fluid-crystal interfaces. A strong advective component is required to sustain such thin boundary layers. Turbulent conditions (high Reynolds number) in these miarolitic cavities are shown to exist during crystallization, suggesting that volatile exsolution, crystallization, and cavity generation occur together. 

The surfaces of rocky planets are mostly covered by basaltic crust, but Earth is unique in that it also has extensive regions of felsic crust, manifested in the form of continents. Exactly how felsic crust forms when basaltic magmas are the dominant products of melting the mantles of rocky planets is unclear. A fundamental part of the debate is centered on the low Nb/Ta of Earth’s continental crust (11–13) compared to basalts (15–16). Here, we show that during arc magma differentiation, the extent of Nb/Ta fractionation varies with crustal thickness with the lowest Nb/Ta seen in continental arc magmas. Deep arc cumulates (arclogites) are found to have high Nb/Ta (average ~19) due to the presence of high Nb/Ta magmatic rutiles. We show that the crustal thickness control of Nb/Ta can be explained by rutile saturation being favored at higher pressures. Deep-seated magmatic differentiation, such as in continental arcs and other magmatic orogens, is thus necessary for making continents.