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Sensors that use ultraviolet (UV) light absorption to measure nitrate in seawater at in situ temperatures require a correction to the calibration coefficients if the calibration and sample temperatures are not identical. This is mostly due to the bromide molecule, which absorbs more UV light as temperature increases. The current correction applied to in situ ultraviolet spectrophotometer (ISUS) and submersible ultraviolet nitrate analyzer (SUNA) nitrate sensors generally follows Sakamoto et al. (2009, Limnol. Oceanogr. Methods 7, 132–143). For waters warmer than the calibration temperature, this correction model can lead to a 1–2 μmol kg⁻¹positive bias in nitrate concentration. Here we present an updated correction model, which reduces this small but noticeable bias by at least 50%. This improved model is based on additional laboratory data and describes the temperature correction as an exponential function of wavelength and temperature difference from the calibration temperature. It is a better fit to the experimental data than the current model and the improvement is validated using two populations of nitrate profiles from Biogeochemical Argo floats navigating through tropical waters. One population is from floats equipped with ISUS sensors while the other arises from floats with SUNA sensors on board. Although this model can be applied to both ISUS and SUNA nitrate sensors, it should not be used for OPUS UV nitrate sensors at this time. This new approach is similar to that used for OPUS sensors (Nehir et al., 2021, Front. Mar. Sci. 8, 663800) with differing model coefficients. This difference suggests that there is an instrumental component to the temperature correction or that there are slight differences in experimental methodologies.

We analyze 15‐year of observational data and a 5‐year Southern Ocean model simulation to quantify the transformation rates of Circumpolar Deep Water (CDW) and the associated heat loss to the surface. This study finds that over the continental shelves of East Antarctica and the Weddell and Ross Seas, surface buoyancy fluxes transform ∼4.4 Sv of surface waters into CDW, providing a path for CDW to lose heat to the surface. In addition, ∼6.6 Sv of CDW are mixed with surface waters in the Weddell and Ross subpolar gyres. In contrast, enhanced stratification inhibits the outcropping of CDW isopycnals, reducing their transformation rates by a factor of ∼8 over the continental shelf and by a factor of ∼3 over the deeper ocean in the Amundsen and Bellingshausen Seas. The CDW retains its offshore warm properties as it intrudes over the continental shelves, resulting in elevated bottom temperatures there. This analysis demonstrates the importance of processes in subpolar gyres to erode CDW and to facilitate further transformation on the continental shelves, significantly reducing the heat able to access ice shelf fronts. This sheltering effect is strongest in the western Weddell Sea and tends to diminish toward the east, which helps explain the large zonal differences in continental‐shelf bottom temperatures and the melt rates of Antarctic ice shelves.

Forecasting Antarctic atmospheric, oceanic, and sea ice conditions on subseasonal to seasonal scales remains a major challenge. During both the freezing and melting seasons current operational ensemble forecasting systems show a systematic overestimation of the Antarctic sea-ice edge location. The skill of sea ice cover prediction is closely related to the accuracy of cloud representation in models, as the two are strongly coupled by cloud radiative forcing. In particular, surface downward longwave radiation (DLW) deficits appear to be a common shortcoming in atmospheric models over the Southern Ocean. For example, a recent comparison of ECMWF reanalysis 5th generation (ERA5) global reanalysis with the observations from McMurdo Station revealed a year-round deficit in DLW of approximately 50 Wm⁻²in marine air masses due to model shortages in supercooled cloud liquid water. A comparison with the surface DLW radiation observations from the Ocean Observatories Initiative mooring in the South Pacific at 54.08° S, 89.67° W, for the time period January 2016–November 2018, confirms approximately 20 Wm⁻²deficit in DLW in ERA5 well north of the sea-ice edge. Using a regional ocean model, we show that when DLW is artificially increased by 50 Wm⁻²in the simulation driven by ERA5 atmospheric forcing, the predicted sea ice growth agrees much better with the observations. A wide variety of sensitivity tests show that the anomalously large, predicted sea-ice extent is not due to limitations in the ocean model and that by implication the cause resides with the atmospheric forcing.

The deep ocean releases large amounts of old, pre‐industrial carbon dioxide (CO₂) to the atmosphere through upwelling in the Southern Ocean, which counters the marine carbon uptake occurring elsewhere. This Southern Ocean CO₂release is relevant to the global climate because its changes could alter atmospheric CO₂levels on long time scales, and also affects the present‐day potential of the Southern Ocean to take up anthropogenic CO₂. Here, year‐round profiling float measurements show that this CO₂release arises from a zonal band of upwelling waters between the Subantarctic Front and wintertime sea‐ice edge. This band of high CO₂subsurface water coincides with the outcropping of the 27.8 kg m⁻³isoneutral density surface that characterizes Indo‐Pacific Deep Water (IPDW). It has a potential partial pressure of CO₂exceeding current atmospheric CO₂levels (∆PCO₂) by 175 ± 32 μatm. Ship‐based measurements reveal that IPDW exhibits a distinct ∆PCO₂maximum in the ocean, which is set by remineralization of organic carbon and originates from the northern Pacific and Indian Ocean basins. Below this IPDW layer, the carbon content increases downwards, whereas ∆PCO₂decreases. Most of this vertical ∆PCO₂decline results from decreasing temperatures and increasing alkalinity due to an increased fraction of calcium carbonate dissolution. These two factors limit the CO₂outgassing from the high‐carbon content deep waters on more southerly surface outcrops. Our results imply that the response of Southern Ocean CO₂fluxes to possible future changes in upwelling are sensitive to the subsurface carbon chemistry set by the vertical remineralization and dissolution profiles.

Measurements of pH and nitrate from the Southern Ocean Carbon and Climate Observations and Modeling array of profiling floats were used to assess the ratios of dissolved inorganic carbon (DIC) and nitrate (NO₃) uptake during the spring to summer bloom period throughout the Southern Ocean. Two hundred and forty‐three bloom periods were observed by 115 floats from 30°S to 70°S. Similar calculations were made using the Takahashi surface DIC and nitrate climatology. To separate the effects of atmospheric CO₂exchange and mixing from phytoplankton uptake, the ratios of changes in DIC to nitrate of surface waters (ΔDIC/ΔNO₃) were computed in the Biogeochemical Southern Ocean State Estimate (B‐SOSE) model. Phytoplankton uptake of DIC and nitrate are fixed in B‐SOSE at the Redfield Ratio (RR; 6.6 mol C/mol N). Deviations in the B‐SOSE ΔDIC/ΔNO₃must be due to non‐biological effects of CO₂gas exchange and mixing. ΔDIC/ΔNO₃values observed by floats and in the Takahashi climatology were corrected for the non‐biological effects using B‐SOSE. The corrected, in situ biological uptake ratio (C:N) occurs at values similar to the RR, with two major exceptions. North of 40°S biological DIC uptake is observed with little or no change in nitrate giving high C:N. In the latitude band at 55°S, the Takahashi data give a low C:N value, while floats are high. This may be due to a change in CO₂air‐sea exchange in this region from uptake during the Takahashi reference year of 2005 to outgassing of CO₂during the years sampled by floats.

Climate models of varying complexity have been used for decades to investigate the impact of mountains on the atmosphere and surface climate. Here, the impact of removing the continental topography on the present-day ocean climate is investigated using three different climate models spanning multiple generations. An idealized study is performed where all present-day land surface topography is removed and the equilibrium change in the oceanic mean state with and without the mountains is studied. When the mountains are removed, changes found in all three models include a weakening of the Atlantic meridional overturning circulation and associated SST cooling in the subpolar North Atlantic. The SSTs also warm in all the models in the western North Pacific Ocean associated with a northward shift of the atmospheric jet and the Kuroshio. In the ocean interior, the magnitude of the temperature and salinity response to removing the mountains is relatively small and the sign and magnitude of the changes generally vary among the models. These different interior ocean responses are likely related to differences in the mean state of the control integrations due to differences in resolution and associated subgrid-scale mixing parameterizations. Compared to the results from 4xCO₂simulations, the interior ocean temperature changes caused by mountain removal are relatively small; however, the oceanic circulation response and Northern Hemisphere near-surface temperature changes are of a similar magnitude to the response to such radiative forcing changes.

The Arctic seasonal halocline impacts the exchange of heat, energy, and nutrients between the surface and the deeper ocean, and it is changing in response to Arctic sea ice melt over the past several decades. Here, we assess seasonal halocline formation in 1975 and 2006–12 by comparing daily, May–September, salinity profiles collected in the Canada Basin under sea ice. We evaluate differences between the two time periods using a one-dimensional (1D) bulk model to quantify differences in freshwater input and vertical mixing. The 1D metrics indicate that two separate factors contribute similarly to stronger stratification in 2006–12 relative to 1975: 1) larger surface freshwater input and 2) less vertical mixing of that freshwater. The larger freshwater input is mainly important in August–September, consistent with a longer melt season in recent years. The reduced vertical mixing is mainly important from June until mid-August, when similar levels of freshwater input in 1975 and 2006–12 are mixed over a different depth range, resulting in different stratification. These results imply that decadal changes to ice–ocean dynamics, in addition to freshwater input, significantly contribute to the stronger seasonal stratification in 2006–12 relative to 1975. These findings highlight the need for near-surface process studies to elucidate the impact of lateral processes and ice–ocean momentum exchange on vertical mixing. Moreover, the results may provide insight for improving the representation of decadal changes to Arctic upper-ocean stratification in climate models that do not capture decadal changes to vertical mixing.

We use two coupled climate models, GFDL‐CM4 and GFDL‐ESM4, to investigate the physical response of the Southern Ocean to changes in surface wind stress, Antarctic meltwater, and the combined forcing of the two in a pre‐industrial control simulation. The meltwater cools the ocean surface in all regions except the Weddell Sea, where the wind stress warms the near‐surface layer. The limited sensitivity of the Weddell Sea surface layer to the meltwater is due to the spatial distribution of the meltwater fluxes, regional bathymetry, and large‐scale circulation patterns. The meltwater forcing dominates the Antarctic shelf response and the models yield strikingly different responses along West Antarctica. The disagreement is attributable to the mean‐state representation and meltwater‐driven acceleration of the Antarctic Slope Current (ASC). In CM4, the meltwater is efficiently trapped on the shelf by a well resolved, strong, and accelerating ASC which isolates the West Antarctic shelf from warm offshore waters, leading to strong subsurface cooling. In ESM4, a weaker and diffuse ASC allows more meltwater to escape to the open ocean, the West Antarctic shelf does not become isolated, and instead strong subsurface warming occurs. The CM4 results suggest a possible negative feedback mechanism that acts to limit future melting, while the ESM4 results suggest a possible positive feedback mechanism that acts to accelerate melt. Our results demonstrate the strong influence the ASC has on governing changes along the shelf, highlighting the importance of coupling interactive ice sheet models to ocean models that can resolve these dynamical processes.

The Canada Basin has exhibited a significant trend toward a fresher surface layer and thus a more stratified upper‐ocean over the past three decades. State‐of‐the‐art ice‐ocean models, by contrast, tend to simulate a surface layer that is saltier and less stratified than observed. Here, we examine decadal changes to seasonal processes that may contribute to this wide‐reaching model bias using climate model simulations from the Community Earth System Model and below‐ice observations from the Arctic Ice Dynamics Joint Experiment in 1975 and Ice Tethered Profilers in 2006–2012. In contrast to the observations, the models simulate salinity profiles that show relatively little variation between 1975 and 2012. We demonstrate that this bias can be mainly attributed to unrealistically deep vertical mixing in the model, creating a surface layer that is saltier than observed. The results provide insight for climate model improvement with broad implications for Arctic sea ice and ecosystem dynamics.

Translation of atmospheric forcing variability into the ocean interior via ocean ventilation is an important aspect of transient climate change. On a seasonal timescale in the subtropics, this translation is mediated by a so‐called “Demon” that prevents access to all except late‐winter mixed‐layer water. Here, we use an eddy‐permitting numerical circulation model to investigate a similar process operating on longer (interannual) timescales in the subpolar North Atlantic. We find that variations in atmospheric forcing are mediated in their translation to the ocean interior, with year‐to‐year changes in the late‐winter mixed layer depth being the critical factor. The signature of persistent strong atmospheric forcing driving deep mixed layers is preferentially ventilated to the interior when the forcing is ceased. Susceptibility to this effect depends on the location and density of subduction—with the rate at which newly ventilated water escapes its region of subduction being the crucial factor.