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1. Influence of redox conditions on the intensity of Mars crustal magnetic anomalies

   https://doi.org/10.1111/maps.12505  

   Brachfeld, Stefanie; Shah, Deepa; First, Emily; Hammer, Julia; Bowles, Julie (October 2015, Meteoritics & Planetary Science)

   Abstract We evaluate the relationship between the intensity of remanent magnetization andfO₂in natural and synthetic Mars meteorites. The olivine‐phyric shergottite meteorite Yamato 980459 (Y‐980459) and a sulfur‐free synthetic analog (Y‐98*) of identical major element composition were analyzed to explore the rock magnetic and remanence properties of a basalt crystallized from a primitive melt, and to explore the role of magmatic and alteration environmentfO₂on Mars crustal anomalies. The reducing conditions under which Y‐980459 is estimated to have formed (QFM‐2.5; Shearer et al. 2006) were replicated during the synthesis of Y‐98*. Y‐980459 contains pyrrhotite and chromite. Chromite is the only magnetic phase in Y‐98*. The remanence‐carrying capacity of Y‐980459 is comparable to other shergottites that formed in thefO₂range of QFM‐3 to QFM‐1. The remanence‐carrying capacity of these lowfO₂basalts is 1–2 orders of magnitude too weak to account for the intense crustal anomalies observed in Mars's southern cratered highlands. Moderately oxidizing conditions of >QFM‐1, which are more commonly observed in nakhlites and Noachian breccias, are key to generating either a primary igneous assemblage or secondary alteration assemblage capable of acquiring an intense remanent magnetization, regardless of the basalt character or thermal history. This suggests that if igneous rocks are responsible for the intensely magnetized crust, these oxidizing conditions must have existed in the magmatic plumbing systems of early Mars or must have existed in the crust during secondary processes that led to acquisition of a chemical remanent magnetization. 

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2. Distributed crustal shortening followed by transpressional shearing in the Superior Province, northeastern Canada: A Late Archean analogy to modern accretionary plate margins?

   https://doi.org/doi.org/10.1016/j.precamres.2021.106322  

   Jiˇrí ˇZ´ak, Filip Tomek (July 2021, Precambrian research)

   null (Ed.)

   The Canadian Superior Province has become one of the key test pieces to discuss tectonic processes and mechanisms of crustal growth in the Late Archean. The Province consists of a >2.8 Ga proto-cratonic core intruded by voluminous arc-like plutons and surrounded by a series of narrow, elongate ca. 2.8–2.7 Ga juvenile belts, also referred to as terranes or domains. The terranes seem to wrap around the proto-cratonic core and generally young outward, but the kinematics and geodynamic causes of their assembly remain debated. In this paper, we examine the Radisson pluton in northeastern Qu´ebec, which intruded the southern, outer edge of the presumed magmatic arc (Bienville domain) along its ~WNW–ESE-trending tectonic boundary with the protocratonic crust (La Grande domain). The pluton, dominated by porphyritic monzogranite to quartz monzonite, was emplaced at around 2712 Ma and exhibits complex internal structure resulting from superposed magmatic to solid-state deformations. An early margin-parallel ~WNW–ESE magmatic foliation containing a steep lineation, recognized by the anisotropy of magnetic susceptibility (AMS), is interpreted as recording vertical stretching and horizontal flattening of highly crystallized magma, either due to emplacement and/or pure shear dominated transpression. More widespread, however, is a horizontal lineation within the same foliation that is interpreted as recording post-emplacement, but still syn-magmatic, tectonic strain (~NNE–SSW shortening and boundaryparallel stretching). Upon cooling, localized dextral S–C mylonite zones accommodated further shortening within the pluton whereas undeformed late-stage felsic dikes cross-cut the solid-state fabric at an angle to the pluton margins. We suggest that this structural succession, also reproduced by numerical fabric modeling, is a local-scale signal of a two-stage assembly of the northeastern Superior Province: the frontal, NNE-directed terrane convergence and attachment to the cratonic nucleus, operating in a ‘hot’ regime with voluminous arclike plutonism, was followed by more localized dextral shearing parallel to terrane boundaries. The latter phase is recorded at the proto-craton margin but also in the outboard Abitibi greenstone belt virtually at the same time (ca. 2700–2690 Ma). In combination, the two-stage evolution and similar deformation distributed over a broad region resemble modern large hot orogens formed in a plate-tectonic regime. 

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3. Low-Intensity Magnetic Fields Induce Anomalous Disorder-to-Order Transition in Spherical Block Copolymer Micelle Solutions

   https://doi.org/10.1021/acs.macromol.4c02346  

   Kresge, Grace V; Neal, Christopher_A P; Calabrese, Michelle A (January 2025, Macromolecules)

   Magnetic field processing is promising for directing and enhancing self-assembly of diamagnetic block copolymers (BCPs) via domain alignment, but is typically limited to high field strengths and few polymer chemistries. Herein, a novel magnetic field-induced ordering mechanism distinct from domain alignment is demonstrated in aqueous, spherical BCP micelles. Here, low-intensity magnetic fields (B< 0.5 T) induce an anomalous disorder-to-order transition, accompanied by a several order-of-magnitude increase in shear modulus-- effectively transforming a low viscosity liquid into an ordered soft solid. The induced moduli are orders of magnitude larger than those resulting from thermally-induced ordering. Further magnetization induces cubic-to-cylinder order-to-order transitions. Comprehensive characterization via magnetorheology, small- and wide-angle X-ray scattering, differential scanning calorimetry, and vibrational spectroscopy reveals a significant reduction in micelle size and aggregation number relative to zero-field temperature- or concentration-induced ordering, suggesting that B-fields strongly alter polymer-solvent interactions. This extraordinary BCP ordering strategy enables discovery of structures and d-spacings inaccessible via traditional processing routes, thus providing a new platform for developing advanced materials with precisely-controlled features. 

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4. Effect of Ball Milling on the Magnetic Performance of Strontium Ferrite (SrFe12O19) Powders

   https://doi.org/10.33599/nasampe/s.24.0225  

   Asadollahnejad, A; Price, H; Tate, J; Islam, M; Hassan, M; Arigbabowo, O; Geerts, W (January 2024, NA SAMPE)

   The primary advantage of the high energy ball milling (HEBM) process is its ability to synthesize a homogeneous mixture with submicron (up to nanoscale) particle size. This approach is a viable process for particle size reduction and grain refinement of magnetic powders, which affects their domain structure and by extension the resulting magnetic properties. In this research, we designed a 9-ball milling experiment by keeping the rotational speed constant at 300rpm and varying the ball-to-powder ratio of 5:1, 8:1, and 10:1 for 6hrs, lOhrs, and 14hrs milling times. The strontium ferrite magnetic powders subjected to HEBM were analyzed for crystallite size and behavior via XRD, particle size reduction via SEM/ImageJ software/originLabPro, and magnetic performance via powder-based VSM measurement. The magnetic performance of the ball-milled strontium ferrite powders shows a good combination of appreciable increment in the S-values (a ratio of the remanence to saturation magnetization) and a considerable decline in coercivity (<10% decrease) at 6hrs of milling duration. The particle size obtained at 6hr-8:1BPR is 0.59 µm with about 44% reduction from the 1.05 µm particle size of the unmilled strontium ferrites, which is within the reported single-domain particle critical size (0.5 µm - 0.65 µm). The particle size reduction of 0.59 µm at 6hr-8: lBPR would be beneficial in enabling strong interfacial bonding when the ball­milled strontium ferrite powders are used in polymer-bonded magnets. 

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5. Europium anomalies in zircon: A signal of crustal depth?

   https://doi.org/10.1016/j.epsl.2023.118405  

   Yakymchuk, Chris; Holder, Robert M; Kendrick, Jillian; Moyen, Jean-François (November 2023, Earth and Planetary Science Letters)

   Trace element concentrations and ratios in zircon provide important indicators of the petrological processes that operate in igneous and metamorphic systems. In granitoids, the compositions of zircon have been linked to the behaviour of garnet and plagioclase—pressure-sensitive minerals—in the source during partial melting. This has led to the proposal that Europium anomalies in detrital zircon are linked to the depth of crustal melting or magmatic differentiation and are a proxy for average crustal thickness. In addition to the mineral assemblage present during partial melting, Eu anomalies in zircon are also sensitive to redox conditions as well as magma evolution during extraction, ascent, and emplacement. Here we quantitatively model how rock type, mineral assemblages, redox changes, and reaction sequences influence Eu anomalies of zircon in equilibrium with silicate melt. Partial melting of metasedimentary rocks and metabasites yields felsic to intermediate melts with a large range of Eu anomalies, which do not correlate simply with pressure (i.e. depth) of melting. Europium anomalies of zircon associated with partial melting of metasedimentary rocks are most sensitive to temperature whereas Eu anomalies associated with metabasite melting are controlled by plagioclase proportion—a function of pressure, temperature, and rock composition—as well as changes in oxygen fugacity. Furthermore, magmatic crystallization of granitoids can increase or decrease Eu anomalies in zircon from those of the initial (anatectic) melt. Therefore, Eu anomalies in zircon should not be used as a proxy for the crustal thickness or depth of melting but can be used to track the complex processes of metamorphism, partial melting, and magmatic differentiation in modern and ancient systems. Secular changes of Eu/Eu* from the zircon archive may reflect a change in thermal gradients of crustal melting or an increase in the reworking of sedimentary rocks over time. 

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