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Abstract Temperate exoplanets between the sizes of Earth and Neptune, known as “sub-Neptunes,” have emerged as intriguing targets for astrobiology. It is unknown whether these planets resemble Earth-like terrestrial worlds with a habitable surface, Neptune-like giant planets with deep atmospheres and no habitable surface, or something exotic in between. Recent JWST transmission spectroscopy observations of the canonical sub-Neptune, K2-18 b, revealed ~1% CH₄, ~1% CO₂, and a nondetection of CO in the atmosphere. While previous studies proposed that the observed atmospheric composition could help constrain the lower atmosphere's conditions and determine the interior structure of sub-Neptunes like K2-18 b, the possible interactions between the atmosphere and a hot, supercritical water ocean at its base remain unexplored. In this work, we investigate whether a global supercritical water ocean, resembling a planetary-scale hydrothermal system, can explain these observations on K2-18 b–like sub-Neptunes through equilibrium aqueous geochemical calculations. We find that the observed atmospheric CH₄/CO₂ratio implies a minimum ocean temperature of ~710 K, whereas the corresponding CO/CO₂ratio allows ocean temperatures up to ~1070 K. These results indicate that a global supercritical water ocean on K2-18 b is plausible. While life cannot survive in such an ocean, this work represents the first step toward understanding how a global supercritical water ocean may influence observable atmospheric characteristics on volatile-rich sub-Neptunes. Future observations with better-constrained CO and NH₃mixing ratios could further help distinguish between possible interior compositions of K2-18 b. 

Abstract Understanding the surface temperature and interior structure of cold-to-temperate sub-Neptunes is critical for assessing their habitability, yet direct observations are challenging. In this study, we investigate the impact of water condensation on the atmospheric compositions of sub-Neptunes, focusing on the implications for James Webb Space Telescope (JWST) spectroscopic observations. By modeling the atmospheric photochemistry of two canonical sub-Neptunes, K2-18 b and LHS 1140 b, both with and without water condensation and with and without thick atmospheres, we demonstrate that water condensation can significantly affect the predicted atmospheric compositions. This effect is driven by oxygen depletion from the condensation of water vapor and primarily manifests as an increase in the C/O ratio within the photochemically active regions of the atmosphere. This change in composition particularly affects planets with thin H₂-dominated atmospheres, leading to a transition in dominant nitrogen and carbon carriers from N₂and oxygen-rich species like CO/CO₂toward heavier hydrocarbons and nitriles. While our models do not fully account for the loss mechanisms of these higher-order species, such molecules can go on to form more refractory molecules or hazes. Planets with thin H₂-rich atmospheres undergoing significant water condensation are thus likely to exhibit very hazy atmospheres. The relatively flat JWST spectra observed for LHS 1140 b could be consistent with such a scenario, suggesting a shallow surface with extensive water condensation or a high atmospheric C/O ratio. Conversely, the JWST observations of K2-18 b are better aligned with a volatile-rich mini-Neptune with a thick atmosphere. 

Abstract We present a new two-dimensional, bin-scheme microphysical model of cloud formation in the atmospheres of hot Jupiters that includes the effects of longitudinal gas and cloud transport. We predict cloud particle size distributions as a function of planetary longitude and atmospheric height for a grid of hot Jupiters with equilibrium temperatures ranging from 1000 to 2100 K. The predicted 2D cloud distributions vary significantly from models that do not consider horizontal cloud transport and we discuss the microphysical and transport timescales that give rise to the differences in 2D versus 1D models. We find that the horizontal advection of cloud particles increases the cloud formation efficiency for nearly all cloud species and homogenizes cloud distributions across the planets in our model grid. In 2D models, certain cloud species are able to be transported and survive on the daysides of hot Jupiters in cases where 1D models would not predict the existence of clouds. We demonstrate that the depletion of condensible gas species varies as a function of longitude and atmospheric height across the planet, which impacts the resultant gas-phase chemistry. Finally, we discuss various model sensitivities including the sensitivity of cloud properties to microphysical parameters, which we find to be substantially less than the sensitivity to the atmospheric thermal structure and horizontal and vertical transport of condensible material. 

Abstract Atmospheric photochemistry on Titan continuously transforms methane and nitrogen gases into various organic compounds. This study explores the fate of these molecules when they land on Titan's surface. Our analytical exploration reveals that most simple organics found in Titan's atmosphere, including all nitriles, triple‐bonded hydrocarbons, and benzene, land as solids. Only a few compounds are in the liquid phase, while only ethylene remains gaseous. For the simple organics that land as solids, we further examine their interactions with Titan's lake liquids. Utilizing principles of buoyancy, we found that flotation can be achieved via porosity‐induced (25%–60% porosity) or capillary force‐induced buoyancy for hydrogen cyanide ices on ethane‐rich lakes. Otherwise, these ices would sink and become lakebed sediments. By evaluating the timescale of flotation, our findings suggest that porosity‐induced flotation of millimeter‐sized and larger sediments is the only plausible mechanism for floating solids to explain the transient “magic islands” phenomena on Titan's lakes. 

Abstract Storms operated by moist convection and the condensation of CH₄or H₂S have been observed on Uranus and Neptune. However, the mechanism of cloud formation, thermal structure, and mixing efficiency of ice giant weather layers remains unclear. In this paper, we show that moist convection is limited by heat transport on giant planets, especially on ice giants where planetary heat flux is weak. Latent heat associated with condensation and evaporation can efficiently bring heat across the weather layer through precipitations. This effect was usually neglected in previous studies without a complete hydrological cycle. We first derive analytical theories and show that the upper limit of cloud density is determined by the planetary heat flux and microphysics of clouds but is independent of the atmospheric composition. The eddy diffusivity of moisture depends on the planetary heat fluxes, atmospheric composition, and surface gravity but is not directly related to cloud microphysics. We then conduct convection- and cloud-resolving simulations with SNAP to validate our analytical theory. The simulated cloud density and eddy diffusivity are smaller than the results acquired from the equilibrium cloud condensation model and mixing length theory by several orders of magnitude but consistent with our analytical solutions. Meanwhile, the mass-loading effect of CH₄and H₂S leads to superadiabatic and stable weather layers. Our simulations produced three cloud layers that are qualitatively similar to recent observations. This study has important implications for cloud formation and eddy mixing in giant planet atmospheres in general and observations for future space missions and ground-based telescopes. 

With its extreme axial tilt, Uranus' radiant energy budget (REB) and internal heat flux remain among the most intriguing mysteries in our solar system. By combining observations with modeling, we present the global REB over a complete orbital period (1946–2030), revealing significant seasonal variations. Despite these fluctuations, the global average emitted thermal power consistently exceeds absorbed solar power, indicating a net energy loss. Assuming no significant seasonal variation in emitted power, we estimate an internal heat flux of 0.078 ± 0.018 W/m2 by analyzing the energy budget over one orbital period. The combination of internal heat and radiant energies indicates substantial global and hemispheric imbalances, with excesses or deficits exceeding 85% of emitted power at the hemispheric scale. These findings are crucial for understanding Uranus' interior and atmosphere. A future flagship mission to Uranus would provide critical observations to address more unresolved questions of this enigmatic ice giant. 

Aerosols in Jupiter’s stratosphere form intriguing polar hoods, which have been investigated by ultraviolet cameras on Cassini and the Hubble Space Telescope. Transient, concentrated dark ovals of unknown origin have been noted within both the northern and southern polar hoods. However, a systematic comparative study of their properties, which could elucidate the physical processes active at the poles, has not yet been performed due to infrequent observations. Using 26 global maps of Jupiter taken by Hubble between 1994 and 2022, we detected transient ultraviolet-dark ovals with a 48% to 53% frequency of occurrence in the south. We found the southern dark oval to be 4 to 6 times more common than its northern counterpart. The southern feature is an anticyclonic vortex and remains within the auroral oval during most of its lifetime. The oval’s darkness is consistent with a 20 to 50 times increase in haze abundance or an overall upward shift in the stratospheric haze distribution. The anticyclonic vorticity of the dark oval is enhanced relative to its surroundings, which represents a deep extension of the higher-altitude vortices previously reported in the thermosphere and upper stratosphere. The haze enhancement is probably driven by magnetospheric momentum exchange, with enhanced aerosols producing the localized heating detected in previous infrared retrievals.