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Iron oxide nanomaterials participate in redox processes that give them ideal properties for their use as earth-abundant catalysts. Fabricating nanocatalysts for such applications requires detailed knowledge of the deposition and growth. We report the spontaneous deposition of iron oxide nanoparticles on HOPG in defect areas and on step edges from a metal precursor solution. To study the nucleation and growth of iron oxide nanoparticles, tailored defects were created on the surface of HOPG using various ion sources that serve as the target sites for iron oxide nucleation. After solution deposition and annealing, the iron oxide nanoparticles were found to nucleate and coalesce at 400 °C. AFM revealed that the particles on the sp 3 carbon sites enabled the nanoparticles to aggregate into larger particles. The iron oxide nanoparticles were characterized as having an Fe 3+ oxidation state and two different oxygen species, Fe–O and Fe–OH/Fe–OOH, as determined by XPS. STEM imaging and EDS mapping confirmed that the majority of the nanoparticles grown were converted to hematite after annealing at 400 °C. A mechanism of spontaneous and selective deposition on the HOPG surface and transformation of the iron oxide nanoparticles is proposed. These results suggest a simple method for growing nanoparticles as a model catalyst.
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Gold nanocatalysts supported on carbon for electrocatalytic oxidation of organic molecules including guanines in DNA
Gold (Au) is chemically stable and resistant to oxidation. Although bulk Au is catalytically inert, nanostructured Au exhibits unique size-dependent catalytic activity. When Au nanocatalysts are supported on conductive carbon (denoted as Au@C), Au@C becomes promising for a wide range of electrochemical reactions such as electrooxidation of alcohols and electroreduction of carbon dioxide. In this mini-review, we summarize Au@C nanocatalysts with specific attention on the most recent achievements including the findings in our own laboratories, and show that Au nanoclusters (AuNCs, <2 nm) on nitrided carbon are excellent electrocatalysts for the oxidation of organic molecules including guanines in DNA. The state-of-the-art synthesis and characterization of these nanomaterials are also documented. Synergistic interactions among Au-containing multicomponents on carbon supports and their applications in electrocatalysis are discussed as well. Finally, challenges and future outlook for these emerging and promising nanomaterials are envisaged.
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- Award ID(s):
- 1705566
- PAR ID:
- 10074571
- Date Published:
- Journal Name:
- Dalton Transactions
- ISSN:
- 1477-9226
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/C8DT01966E
