The strong spin–orbit coupling (SOC) in lead halide perovskites, when inversion symmetry is lifted, has provided opportunities for investigating the Rashba effect in these systems. Moreover, the strong orbital moment, which, in turn, impacts the spin-pair in singlet and triplet electronic states, plays a significant role in enhancing the optoelectronic properties in the presence of external magnetic fields in lead halide perovskites. Here, we investigate the effect of weak magnetic fields (<1 T) on the photoluminescence (PL) properties of [Formula: see text] nanocrystals with and without Ruddlesden–Popper (RP) faults and single crystals of [Formula: see text]. Along with an enhancement in the PL intensity as a function of an external magnetic field, which is observed in both lead bromide perovskites, the PL emission red-shifts in [Formula: see text] nanocrystals. Density-functional theory calculations of the electronic band-edge in [Formula: see text] show almost no change in the energy gap as a function of the external magnetic field. The experimental results, thus, suggest the role of mixing of the triplet and singlet excitonic states under weak magnetic fields. This is further deduced from an enhancement in PL lifetimes as a function of the field in [Formula: see text]. In [Formula: see text], an increase in PL intensity is observed under weak magnetic fields; however, no changes in the peak energy or PL lifetimes are observed. The internal magnetic fields due to SOC are characterized for all three samples and found to be the highest for [Formula: see text] nanocrystals with RP faults.
- Award ID(s):
- NSF-PAR ID:
- Date Published:
- Journal Name:
- Physical Chemistry Chemical Physics
- Page Range / eLocation ID:
- 2595 to 2600
- Medium: X
- Sponsoring Org:
- National Science Foundation
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