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Chiral condensed matter systems, such as liquid crystals and magnets, exhibit a host of spatially localized topological structures that emerge from the medium’s tendency to twist and its competition with confinement and field coupling effects. We show that the strength of perpendicular surface boundary conditions can be used to control the structure and topology of solitonic and other localized field configurations. By combining numerical modeling and threedimensional imaging of the director field, we reveal structural stability diagrams and intertransformation of twisted walls and fingers, torons and skyrmions and their crystalline organizations upon changing boundary conditions. Our findings provide a recipe for controllably realizing skyrmions, torons and hybrid solitonic structures possessing features of both of them, which will aid in fundamental explorations and technological uses of such topological solitons. Moreover, with limited examples, we discuss how similar principles can be systematically used to tune stability of twisted walls versus cholesteric fingers and hopfions versus skyrmions, torons and twistions.
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Topological solitons, cholesteric fingers and singular defect lines in Janus liquid crystal shells
Topological solitons are non-singular but topologically nontrivial structures in fields, which have fundamental significance across various areas of physics, similar to singular defects. Production and observation of singular and solitonic topological structures remain a complex undertaking in most branches of science – but in soft matter physics, they can be realized within the director field of a liquid crystal. Additionally, it has been shown that confining liquid crystals to spherical shells using microfluidics resulted in a versatile experimental platform for the dynamical study of topological transformations between director configurations. In this work, we demonstrate the triggered formation of topological solitons, cholesteric fingers, singular defect lines and related structures in liquid crystal shells. We show that to accommodate these objects, shells must possess a Janus nature, featuring both twisted and untwisted domains. We report the formation of linear and axisymmetric objects, which we identify as cholesteric fingers and skyrmions or elementary torons, respectively. We then take advantage of the sensitivity of shells to numerous external stimuli to induce dynamical transitions between various types of structures, allowing for a richer phenomenology than traditional liquid crystal cells with solid flat walls. Using gradually more refined experimental techniques, we induce the targeted transformation of cholesteric twist walls and fingers into skyrmions and elementary torons. We capture the different stages of these director transformations using numerical simulations. Finally, we uncover an experimental mechanism to nucleate arrays of axisymmetric structures on shells, thereby creating a system of potential interest for tackling crystallography studies on curved spaces.
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- Award ID(s):
- 1810513
- PAR ID:
- 10140872
- Date Published:
- Journal Name:
- Soft Matter
- Volume:
- 16
- Issue:
- 11
- ISSN:
- 1744-683X
- Page Range / eLocation ID:
- 2669 to 2682
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/C9SM02033K
