The mid-IR spectroscopic properties of doped low-phonon and crystals grown by the Bridgman technique have been investigated. Using optical excitations at and , both crystals exhibited IR emissions at , , , and at room temperature. The mid-IR emission at 4.5 µm, originating from the transition, showed a long emission lifetime of for doped , whereas doped exhibited a shorter lifetime of . The measured emission lifetimes of the state were nearly independent of the temperature, indicating a negligibly small nonradiative decay rate through multiphonon relaxation, as predicted by the energy-gap law for low-maximum-phonon energy hosts. The room temperature stimulated emission cross sections for the transition in doped and were determined to be and , respectively. The results of Judd–Ofelt analysis are presented and discussed.
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Rapid acquisition of broadband two-dimensional electronic spectra by continuous scanning with conventional delay lines
A passively phase-stable, broadband ( , ) two-dimensional (2D) electronic spectroscopy apparatus that achieves rapid acquisition rates by continuously—rather than step-wise—scanning the Fourier-transform dimension is demonstrated for the first time, to the best of our knowledge. This is made possible through use of a partially common path interferometer design in which the coherence time is sampled in a “rotating frame.” Rapid, continuous scanning of increases the duty cycle of signal collection, rejects the majority of excitation pulse scatter, and enables the measurement of a complete 2D spectrum in 92 ms, which minimizes the influence of pulse intensity and delay fluctuations on the 2D spectrum. In practice, these improvements make possible the acquisition of hundreds of 2D spectra in tens of minutes, which opens the door to dense sampling of ultrafast relaxation dynamics and to generating extremely broadband 3D Fourier-transform spectra.
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- Award ID(s):
- 1665021
- PAR ID:
- 10150966
- Publisher / Repository:
- Optical Society of America
- Date Published:
- Journal Name:
- Optics Letters
- Volume:
- 45
- Issue:
- 10
- ISSN:
- 0146-9592; OPLEDP
- Format(s):
- Medium: X Size: Article No. 2942
- Size(s):
- Article No. 2942
- Sponsoring Org:
- National Science Foundation
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