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Title: Mid-IR spectroscopy of Er 3+ doped low-phonon CsCdCl 3 and CsPbCl 3 crystals
The mid-IR spectroscopic properties of E r 3 + doped low-phonon C s C d C l 3 and C s P b C l 3 crystals grown by the Bridgman technique have been investigated. Using optical excitations at ∼<#comment/> 800 n m and ∼<#comment/> 660 n m , both crystals exhibited IR emissions at ∼<#comment/> 1.55 , ∼<#comment/> 2.75 , ∼<#comment/> 3.5 , and ∼<#comment/> 4.5 µ<#comment/> m at room temperature. The mid-IR emission at 4.5 µm, originating from the 4 I 9 / 2 →<#comment/> 4 I 11 / 2 transition, showed a long emission lifetime of ∼<#comment/> 11.6 m s for E r 3 + doped C s C d C l 3 , whereas E r 3 + doped C s P b C l 3 exhibited a shorter lifetime of ∼<#comment/> 1.8 m s . The measured emission lifetimes of the 4 I 9 / 2 state were nearly independent of the temperature, indicating a negligibly small nonradiative decay rate through multiphonon relaxation, as predicted by the energy-gap law for low-maximum-phonon energy hosts. The room temperature stimulated emission cross sections for the 4 I 9 / 2 →<#comment/> 4 I 11 / 2 transition in E r 3 + doped C s C d C l 3 and C s P b C l 3 were determined to be ∼<#comment/> 0.14 ×<#comment/> 10 −<#comment/> 20 c m 2 and ∼<#comment/> 0.41 ×<#comment/> 10 −<#comment/> 20 c m 2 , respectively. The results of Judd–Ofelt analysis are presented and discussed.  more » « less
Award ID(s):
1827820
PAR ID:
10372091
Author(s) / Creator(s):
; ; ; ; ; ; ;
Publisher / Repository:
Optical Society of America
Date Published:
Journal Name:
Journal of the Optical Society of America B
Volume:
40
Issue:
1
ISSN:
0740-3224; JOBPDE
Format(s):
Medium: X Size: Article No. A1
Size(s):
Article No. A1
Sponsoring Org:
National Science Foundation
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