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ABSTRACT Despite the improvements seen in efficiency of GaAs cells over the years, there remains room for improvement for it to approach the theoretical single junction limit posited by Shockley and Quiesser decades ago. One of the more pursued options is the growth of quantum wells within the structure of GaAs to enhance its photon absorption below its bandgap. Multiple Quantum Wells (MQW) have been an ongoing topic of research and discussion for the scientific community with structures like InGaAs/GaAs and InGaP/GaAs quantum wells producing promising results that could potentially improve overall energy conversion. Here, we used WEIN2K, a commercial density functional theory package, to study the ternary compound Ga 1-x Tl x As and determine its electronic properties. Using these results combined with experimental confirmation we extend these properties to simulate its application to form a MQW GaAs/ Ga 1-x Tl x As solar cell. Ga 1-x Tl x As is a tunable ternary compound, with its bandgap being strongly dependent on the concentration of Tl present. Concentrations of Tl as low as 7% can reduce the bandgap of Ga 1-x Tl x As to roughly 1.30 eV from GaAs’s 1.45 eV at room temperature with as little as a 1.7% increase in lattice constant. The change in bandgap, accompanied by the relatively small change in lattice constant makes Ga 1-x Tl x As a strong candidate for a MQW cell with little to no strain balancing required within the structure to minimize unwanted defects that impede charge collection within the device. Our GaAs photodiode with TlGaAs MQWs shows an expanded absorption band and improved conversion efficiency over the standard GaAs photovoltaic cell with dilute concentrations of Tl incorporated into the compound.
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Intlp compounds for Underwater Solar Energy Harvesting
ABSTRACT With the rising interest in oceanic monitoring, climate awareness and surveillance, the scientific community need for developing autonomous, self-sustaining Unmanned Underwater Vehicles (UUVs) increased as well. Limitations on the size, maneuverability, power consumption, and available on-site maintenance of these UUVs make a number of proposed technologies to power them harder to implement than others; solar energy harvesting stands as one of the more promising candidates to address the need for a long-term energy supply for UUVs due to its relatively small size and ease of deployment. Studies show research groups focusing on the use of Si cells (amorphous and crystalline), InGaP, and more recently Organic Photovoltaics to convert the attenuated solar spectrum under shallow depths (no deeper than 9.1 m) into electrical energy used or stored by the UUV’s power management system (P. P. Jenkins et al. 2014; Walters et al. 2015). In our study, we consider the ternary compound In 1-x Tl x P that allows for varying the quantum efficiency of the cell, and by extension the overall harvesting efficiency of the system by altering the Tl content (x) in the compound. In 1-x Tl x P on InP is a low strain system since the compound exhibits very little change in its lattice constant with changing Tl content due to the comparable atomic size and forces of In and Tl allowing for relatively easy growth on InP substrates. The study focuses on studying the spectral response and comparing the performance of an optimized single junction In 1-x Tl x P cells to In 1-y Ga y P cells while accounting for the optical losses of the solar irradiance underwater for various depths.
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- Award ID(s):
- 1806311
- PAR ID:
- 10152810
- Date Published:
- Journal Name:
- MRS Advances
- Volume:
- 3
- Issue:
- 3
- ISSN:
- 2059-8521
- Page Range / eLocation ID:
- 153 to 158
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1557/adv.2018.22
