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Title: Phase segregation in inorganic mixed-halide perovskites: from phenomena to mechanisms
Halide perovskites, such as methylammonium lead halide perovskites ( MAPbX 3 , X = I , Br, and Cl), are emerging as promising candidates for a wide range of optoelectronic applications, including solar cells, light-emitting diodes, and photodetectors, due to their superior optoelectronic properties. All-inorganic lead halide perovskites CsPbX 3 are attracting a lot of attention because replacing the organic cations with Cs + enhances the stability, and its halide-mixing derivatives offer broad bandgap tunability covering nearly the entire visible spectrum. However, there is evidence suggesting that the optical properties of mixed-halide perovskites are influenced by phase segregation under external stimuli, especially illumination, which may negatively impact the performance of optoelectronic devices. It is reported that the mixed-halide perovskites in forms of thin films and nanocrystals are segregated into a low-bandgap I-rich phase and a high-bandgap Br-rich phase. Herein, we present a critical review on the synthesis and basic properties of all-inorganic perovskites, phase-segregation phenomena, plausible mechanisms, and methods to mitigate phase segregation, providing insights on advancing mixed-halide perovskite optoelectronics with reliable performance.  more » « less
Award ID(s):
1930809
PAR ID:
10201126
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
Optical Society of America
Date Published:
Journal Name:
Photonics Research
Volume:
8
Issue:
11
ISSN:
2327-9125
Page Range / eLocation ID:
Article No. A56
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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