The mid-IR spectroscopic properties of doped low-phonon and crystals grown by the Bridgman technique have been investigated. Using optical excitations at and , both crystals exhibited IR emissions at , , , and at room temperature. The mid-IR emission at 4.5 µm, originating from the transition, showed a long emission lifetime of for doped , whereas doped exhibited a shorter lifetime of . The measured emission lifetimes of the state were nearly independent of the temperature, indicating a negligibly small nonradiative decay rate through multiphonon relaxation, as predicted by the energy-gap law for low-maximum-phonon energy hosts. The room temperature stimulated emission cross sections for the transition in doped and were determined to be and , respectively. The results of Judd–Ofelt analysis are presented and discussed. 
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                            Phase segregation in inorganic mixed-halide perovskites: from phenomena to mechanisms
                        
                    
    
            Halide perovskites, such as methylammonium lead halide perovskites ( , , Br, and Cl), are emerging as promising candidates for a wide range of optoelectronic applications, including solar cells, light-emitting diodes, and photodetectors, due to their superior optoelectronic properties. All-inorganic lead halide perovskites are attracting a lot of attention because replacing the organic cations with enhances the stability, and its halide-mixing derivatives offer broad bandgap tunability covering nearly the entire visible spectrum. However, there is evidence suggesting that the optical properties of mixed-halide perovskites are influenced by phase segregation under external stimuli, especially illumination, which may negatively impact the performance of optoelectronic devices. It is reported that the mixed-halide perovskites in forms of thin films and nanocrystals are segregated into a low-bandgap I-rich phase and a high-bandgap Br-rich phase. Herein, we present a critical review on the synthesis and basic properties of all-inorganic perovskites, phase-segregation phenomena, plausible mechanisms, and methods to mitigate phase segregation, providing insights on advancing mixed-halide perovskite optoelectronics with reliable performance. 
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                            - Award ID(s):
- 1930809
- PAR ID:
- 10201126
- Publisher / Repository:
- Optical Society of America
- Date Published:
- Journal Name:
- Photonics Research
- Volume:
- 8
- Issue:
- 11
- ISSN:
- 2327-9125
- Page Range / eLocation ID:
- Article No. A56
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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