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1. An Electrodynamic Wireless Power Receiver ‘Chip’ for Wearables and Bio-implants

   https://doi.org/10.1109/WoW47795.2020.9291290  

   Halim, Miah A. ; Rendon-Hernandez, Adrian A. ; Arnold, David P. ( November 2020 , 2020 IEEE PELS Workshop on Emerging Technologies: Wireless Power Transfer (WoW))

   null (Ed.)

   This paper presents the design, fabrication and experimental characterization of a chip-sized wireless power receiver for low-frequency electrodynamic wireless power transmission (EWPT). Utilizing a laser micro-machined meandering suspension, one NdFeB magnet, and two PZT-SA piezoelectric patches, this 0.08 cm 3 micro-receiver operates at its torsion mode mechanical resonance of 724 Hz. The device generates 360 μW average power (4.2 mWcm -3 power density) at 1 cm distance from a transmitter coil operating at 724 Hz and safely within allowable human exposure limits of 2 mTrms field. Compared to a previously reported macro-scale prototype, this volume-efficient micro-receiver is 31x smaller and offers 3.2x higher power density within a low-profile, compact footprint for wirelessly charging wearable and bio-implantable devices. 

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2. Strongly (001) Oriented Bimorph PZT Film on Metal Foils Grown by rf ‐Sputtering for Wrist‐Worn Piezoelectric Energy Harvesters

   https://doi.org/10.1002/adfm.201801327  

   Yeo, Hong Goo ; Xue, Tiancheng ; Roundy, Shad ; Ma, Xiaokun ; Rahn, Christopher ; Trolier‐McKinstry, Susan ( July 2018 , Advanced Functional Materials)

   For piezoelectric energy harvesters, a large volume of piezoelectric material with a high figure of merit is essential to obtain a higher power density. The work describes the growth of highly (001) oriented sputtered lead zirconate titanate (PZT) films (f≈ 0.99) exceeding 4 µm in thickness on both sides of an Ni foil to produce a bimorph structure. These films are incorporated in novel wrist‐worn energy harvesters (<16 cm²) in which piezoelectric beams are plucked magnetically using an eccentric rotor with embedded magnets to implement frequency up‐conversion. The resulting devices successfully convert low‐frequency vibration sources (i.e., from walking, rotating the wrist, and jogging) to higher frequency vibrations of the PZT beams (100–200 Hz). Measured at resonance, six beams producing an output of 1.2 mW is achieved at 0.15 G acceleration. For magnetic plucking of a wrist‐worn nonresonant device, 40–50 µW is produced during mild activity.

    

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3. Lead‐Free Bi 0.5 (Na 0.78 K 0.22 )TiO 3 Nanoparticle Filler–Elastomeric Composite Films for Paper‐Based Flexible Power Generators

   https://doi.org/10.1002/aelm.201900950  

   Won, Sung Sik ; Kawahara, Masami ; Ahn, Chang Won ; Lee, Joonhee ; Lee, Jinkee ; Jeong, Chang Kyu ; Kingon, Angus I. ; Kim, Seung‐Hyun ( December 2019 , Advanced Electronic Materials)

   Key solutions for material selection, processing, and performance of environmentally friendly high‐power generators are addressed. High voltage and high power generation of flexible devices using piezoelectric Bi_0.5(Na_0.78K_0.22)TiO₃nanoparticle filler–polydimethylsiloxane (PDMS) elastomeric matrix for a lead‐free piezoelectric composite film on a cellulose paper substrate is demonstrated. To elucidate the principle of power generation by the piezoelectric composite configuration, the dielectric and piezoelectric characteristics of the composite film are investigated and the results are compared with those of theoretical modeling. The paper‐based composite generator produces a large output voltage of ≈100 V and an average current of ≈20 µA (max. ≈30 µA) through tapping stimulation, which is a record‐high performance compared to previously reported flexible lead‐free piezoelectric composite energy harvesters. Moreover, a triboelectric‐hybridized piezoelectric composite device using a micro‐patterned PDMS shows a much higher output voltage of ≈250 V and output power of ≈0.5 mW, which drives 300 light‐emitting diodes. These results prove that a new class of paper‐based and lead‐free energy harvesting device provides a strong possibility for enlarging the functionality and the capability of high‐power scavengers in flexible and wearable electronics such as sensors and medical devices.

    

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4. Machine learning-assisted ultrafast flash sintering of high-performance and flexible silver–selenide thermoelectric devices

   https://doi.org/10.1039/D2EE01844F  

   Saeidi-Javash, Mortaza ; Wang, Ke ; Zeng, Minxiang ; Luo, Tengfei ; Dowling, Alexander W. ; Zhang, Yanliang ( October 2022 , Energy & Environmental Science)

   Flexible thermoelectric generators (TEGs) have shown immense potential for serving as a power source for wearable electronics and the Internet of Things. A key challenge preventing large-scale application of TEGs lies in the lack of a high-throughput processing method, which can sinter thermoelectric (TE) materials rapidly while maintaining their high thermoelectric properties. Herein, we integrate high-throughput experimentation and Bayesian optimization (BO) to accelerate the discovery of the optimum sintering conditions of silver–selenide TE films using an ultrafast intense pulsed light (flash) sintering technique. Due to the nature of the high-dimensional optimization problem of flash sintering processes, a Gaussian process regression (GPR) machine learning model is established to rapidly recommend the optimum flash sintering variables based on Bayesian expected improvement. For the first time, an ultrahigh-power factor flexible TE film (a power factor of 2205 μW m −1 K −2 with a zT of 1.1 at 300 K) is demonstrated with a sintering time less than 1.0 second, which is several orders of magnitude shorter than that of conventional thermal sintering techniques. The films also show excellent flexibility with 92% retention of the power factor (PF) after 10 3 bending cycles with a 5 mm bending radius. In addition, a wearable thermoelectric generator based on the flash-sintered films generates a very competitive power density of 0.5 mW cm −2 at a temperature difference of 10 K. This work not only shows the tremendous potential of high-performance and flexible silver–selenide TEGs but also demonstrates a machine learning-assisted flash sintering strategy that could be used for ultrafast, high-throughput and scalable processing of functional materials for a broad range of energy and electronic applications. 

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5. Enhanced electrochemical biosensor and supercapacitor with 3D porous architectured graphene via salt impregnated inkjet maskless lithography

   https://doi.org/10.1039/C8NH00377G  

   Hondred, John A. ; Medintz, Igor L. ; Claussen, Jonathan C. ( April 2019 , Nanoscale Horizons)

   Advances in solution-phase graphene patterning has provided a facile route for rapid, low-cost and scalable manufacturing of electrochemical devices, even on flexible substrates. While graphene possesses advantageous electrochemical properties of high surface area and fast heterogenous charge transport, these properties are attributed to the edge planes and defect sites, not the basal plane. Herein, we demonstrate enhancement of the electroactive nature of patterned solution-phase graphene by increasing the porosity and edge planes through the construction of a multidimensional architecture via salt impregnated inkjet maskless lithography (SIIML) and CO 2 laser annealing. Various sized macroscale pores (<25 to ∼250 μm) are patterned directly in the graphene surface by incorporating porogens ( i.e. , salt crystals) in the graphene ink which act as hard templates for pore formation and are later dissolved in water. Subsequently, microsized pores (∼100 nm to 2 μm in width) with edge plane defects are etched in the graphene lattice structure by laser annealing with a CO 2 laser, simultaneously improving electrical conductivity by nearly three orders of magnitude (sheet resistance decreases from >10 000 to ∼50 Ω sq −1 ). We demonstrate that this multidimensional porous graphene fabrication method can improve electrochemical device performance through design and manufacture of an electrochemical organophosphate biosensor that uses the enzyme acetylcholinesterase for detection. This pesticide biosensor exhibits enhanced sensitivity to acetylthiocholine compared to graphene without macropores (28.3 μA nM −1 to 13.3 μA nM −1 ) and when inhibited by organophosphate pesticides (paraoxon) has a wide linear range (10 nM to 500 nM), low limit of detection (0.6 nM), and high sensitivity (12.4 nA nM −1 ). Moreover, this fabrication method is capable of patterning complex geometries [ i.e. interdigitated electrodes (IDEs)] even on flexible surfaces as demonstrated by an IDE supercapacitor made of SIIML graphene on a heat sensitive polymer substrate. The supercapacitor demonstrates a high energy density of 0.25 mW h cm −3 at a power density of 0.3 W cm −3 . These electrochemical devices demonstrate the benefit of using SIIML and CO 2 laser annealing for patterning graphene electrodes with a multidimensional porous surface even on flexible substrates and is therefore a platform technology which could be applied to a variety of different biosensors and other electrochemical devices. 

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