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1. Phase transitions in colloids under microgravity, Abstract: B07.00004,

   Lei, Qian; Khusid, Boris; Kondic, Lou; Hollingsworth, Andrew D.; Chaikin, Paul M.; Meyer, William V.; Reich, Alton J. (March 2021, Abstract: B07.00004, American Physical Society March Meeting 2021, March 15-19, 2021, Virtual)

   null (Ed.)

   Research on colloids is motivated by several factors. They can be used to answer fundamental questions related to the assembly of materials, and they have many potential applications in electronics, photonics, and life sciences. However, the rich variety of colloidal structures observed on the Earth can be influenced by the effects of gravity, which leads to particles settling and the motion of the surrounding fluid. To suppress the gravity effects, experiments on concentrated colloids of spherical and ellipsoidal fluorescent particles were carried out aboard the International Space Station. The particles were suspended in a decalin/tetralin mixture to match the particle refractive index. Confocal microscopy was used to visualize the particle behavior. The work was supported by the NSF CBET grants 1832260 and 1832291 and the NASA grant 80NSSC19K1655. 

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2. Electric field driven aggregation of negatively and positively polarized particles in dilute suspensions.

   Khusid B., Lei Q. (March 2020, Bulletin of the American Physical Society)

   A variety of colloidal structures observed in terrestrial experiments could also have been influenced by gravity effects (particle sedimentation, convection, etc.) It is often assumed that weightlessness simulated in a time-averaged sense by slowly rotating a specimen in a clinostat about an axis perpendicular to the gravity direction that is widely used in biological tests would reduce the effect of gravity on suspensions. Experiments on a non-buoyancy-matched suspension in flights in NASA Zero-gravity aircraft revealed that particle patterns formed in a clinostat and under normal gravity are actually similar. A requirement for matching densities between particles and a solvent severely limits possibilities to study the field-induced structuring in colloids in terrestrial experiments. Long-term microgravity in ISS offers unique opportunity to employ not density matched suspensions to explore a wide range of the mismatch of electric characteristics between particles and a solvent. We will report experimental data on the field driven structure formation in suspensions and present our approach to the development of ISS experiments. The aim is to understand mechanisms of structure formation and suggest novel routes for creating functional materials. *NASA NNX13AQ53G, NSF1832260. 

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3. Writing in the granular gel medium

   https://doi.org/10.1126/sciadv.1500655  

   Bhattacharjee, Tapomoy; Zehnder, Steven M.; Rowe, Kyle G.; Jain, Suhani; Nixon, Ryan M.; Sawyer, W. Gregory; Angelini, Thomas E. (September 2015, Science Advances)

   Gels made from soft microscale particles smoothly transition between the fluid and solid states, making them an ideal medium in which to create macroscopic structures with microscopic precision. While tracing out spatial paths with an injection tip, the granular gel fluidizes at the point of injection and then rapidly solidifies, trapping injected material in place. This physical approach to creating three-dimensional (3D) structures negates the effects of surface tension, gravity, and particle diffusion, allowing a limitless breadth of materials to be written. With this method, we used silicones, hydrogels, colloids, and living cells to create complex large aspect ratio 3D objects, thin closed shells, and hierarchically branched tubular networks. We crosslinked polymeric materials and removed them from the granular gel, whereas uncrosslinked particulate systems were left supported within the medium for long times. This approach can be immediately used in diverse areas, contributing to tissue engineering, flexible electronics, particle engineering, smart materials, and encapsulation technologies. 

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4. Pairwise hydrodynamic interactions of spherical colloids at a gas-liquid interface

   https://doi.org/10.1017/jfm.2021.170  

   Das, Subhabrata; Koplik, Joel; Somasundaran, Ponisseril; Maldarelli, Charles (May 2021, Journal of Fluid Mechanics)

   Colloids which adsorb to and straddle a fluid interface form monolayers that are paradigms of particle dynamics on a two dimensional fluid landscape. The dynamics is typically inertialess (Stokes flows) and dominated by interfacial tension so the interface is undeformed by the flow, and pairwise drag coefficients can be calculated. Here the hydrodynamic interaction between identical spherical colloids on a planar gas/liquid interface is calculated as a function of separation distance and immersion depth. Drag coefficients (normalized by the coefficient for an isolated particle on the surface) are computed numerically for the four canonical interactions. The first two are motions along the line of centres, either with the particles mutually approaching each other or moving in the same direction (in tandem). The second two are motions perpendicular to the line of centres, either oppositely directed (shear) or in the same direction (tandem). For mutual approach and shear, the normalized coefficients increase with a decrease in separation due to lubrication forces, and become infinite on contact when the particle is more than half immersed. However, they remain bounded at contact when the particles are less than half immersed because they do not contact underneath the liquid. For in-tandem motion, the normalized coefficients decrease with a decrease in separation; they collapse, for all immersion depths, to the dependence of the drag coefficient on separation for two particles moving in tandem in an infinite medium. The coefficients are used to compute separation against time for colloids driven together by capillary attraction. 

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5. High-Density and Well-Aligned Hierarchical Structures of Colloids Assembled under Orthogonal Magnetic and Electric Fields

   https://doi.org/10.1021/acsnano.4c11957  

   Haque, Md Ashraful; Maestas, Joseph R; Zhu, Xingrui; Hanson, Benjamin L; Wu, David T; Wu, Ning (January 2025, ACS Nano)

   Colloids can be used either as model systems for directed assembly or as the necessary building blocks for making functional materials. Previous work primarily focused on assembling colloids under a single external field, where controlling particle−particle interactions is limited. This work presents results under a combination of electric and magnetic fields. When these two fields are orthogonally applied, we can independently tune the magnitude and direction of the dipolar attraction and repulsion between the particles. As a result, we obtain well-aligned, highly dense, but individually separated linear chains at intermediate particle concentrations. Both the inter- and intrachain spacings can be tuned by adjusting the particle concentration and relative strengths of both fields. At high particle concentrations and by tuning the electric field frequency, the individual microspheres can assemble into colloidal oligomers such as trimers, tetramers, heptamers, and nonamers in response to the electric field due to the synergy between dipolar and electrohydrodynamic interactions. These oligomers, in turn, serve as building blocks for making hierarchical structures with finer architectures upon superimposing a one-dimensional (1D) magnetic field. In addition to experiments, Monte Carlo (MC) simulations have been performed on colloids confined near the electrode, interacting through a Stockmayer-like potential. They faithfully reproduce key observations in the experiments. Our work demonstrates the potential of using orthogonal electric and magnetic fields to assemble diversified types of highly aligned structures for applications in high-strength composites, optical materials, or structured battery electrodes. 

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