skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Digital light processing of liquid crystal elastomers for self-sensing artificial muscles
Artificial muscles based on stimuli-responsive polymers usually exhibit mechanical compliance, versatility, and high power-to-weight ratio, showing great promise to potentially replace conventional rigid motors for next-generation soft robots, wearable electronics, and biomedical devices. In particular, thermomechanical liquid crystal elastomers (LCEs) constitute artificial muscle-like actuators that can be remotely triggered for large stroke, fast response, and highly repeatable actuations. Here, we introduce a digital light processing (DLP)–based additive manufacturing approach that automatically shear aligns mesogenic oligomers, layer-by-layer, to achieve high orientational order in the photocrosslinked structures; this ordering yields high specific work capacity (63 J kg −1 ) and energy density (0.18 MJ m −3 ). We demonstrate actuators composed of these DLP printed LCEs’ applications in soft robotics, such as reversible grasping, untethered crawling, and weightlifting. Furthermore, we present an LCE self-sensing system that exploits thermally induced optical transition as an intrinsic option toward feedback control.  more » « less
Award ID(s):
1825444 1719875
PAR ID:
10291111
Author(s) / Creator(s):
; ; ; ; ; ; ;
Date Published:
Journal Name:
Science Advances
Volume:
7
Issue:
30
ISSN:
2375-2548
Page Range / eLocation ID:
eabg3677
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract Liquid crystalline elastomers (LCEs) are anisotropic soft materials capable of large dimensional changes when subjected to a stimulus. The magnitude and directionality of the stimuli‐induced thermomechanical response is associated with the alignment of the LCE. Recent reports detail the preparation of LCEs by additive manufacturing (AM) techniques, predominately using direct ink write printing. Another AM technique, digital light process (DLP) 3D printing, has generated significant interest as it affords LCE free‐forms with high fidelity and resolution. However, one challenge of printing LCEs using vat polymerization methods such as DLP is enforcing alignment. Here, we document the preparation of aligned, main‐chain LCEs via DLP 3D printing using a 100 mT magnetic field. Systematic examination isolates the contribution of magnetic field strength, alignment time, and build layer thickness on the degree of orientation in 3D printed LCEs. Informed by this fundamental understanding, DLP is used to print complex LCE free‐forms with through‐thickness variation in both spatial orientations. The hierarchical variation in spatial orientation within LCE free‐forms is used to produce objects that exhibit mechanical instabilities upon heating. DLP printing of aligned LCEs opens new opportunities to fabricate stimuli‐responsive materials in form factors optimized for functional use in soft robotics and energy absorption. 
    more » « less
  2. Abstract Liquid crystal elastomers (LCE) are appealing candidates among active materials for 4D printing, due to their reversible, programmable and rapid actuation capabilities. Recent progress has been made on direct ink writing (DIW) or Digital Light Processing (DLP) to print LCEs with certain actuation. However, it remains a challenge to achieve complicated structures, such as spatial lattices with large actuation, due to the limitation of printing LCEs on the build platform or the previous layer. Herein, a novel method to 4D print freestanding LCEs on‐the‐fly by using laser‐assisted DIW with an actuation strain up to −40% is proposed. This process is further hybridized with the DLP method for optional structural or removable supports to create active 3D architectures in a one‐step additive process. Various objects, including hybrid active lattices, active tensegrity, an actuator with tunable stability, and 3D spatial LCE lattices, can be additively fabricated. The combination of DIW‐printed functionally freestanding LCEs with the DLP‐printed supporting structures thus provides new design freedom and fabrication capability for applications including soft robotics, smart structures, active metamaterials, and smart wearable devices. 
    more » « less
  3. Abstract Liquid crystal elastomers (LCEs) have attracted tremendous interest as actuators for soft robotics due to their mechanical and shape memory properties. However, LCE actuators typically respond to thermal stimulation through active Joule heating and passive cooling, which make them difficult to control. In this work, LCEs are combined with soft, stretchable thermoelectrics to create transducers capable of electrically controlled actuation, active cooling, and thermal‐to‐electrical energy conversion. The thermoelectric layers are composed of semiconductors embedded within a 3D printed elastomer matrix and wired together with eutectic gallium–indium (EGaIn) liquid metal interconnects. This layer is covered on both sides with LCE, which alternately heats and cools to achieve cyclical bending actuation in response to voltage‐controlled Peltier activation. Moreover, the thermoelectric layer can harvest energy from thermal gradients between the two LCE layers through the Seebeck effect, allowing for regenerative energy harvesting. As demonstrations, first, closed‐loop control of the transducer is performed to rapidly track a changing actuator position. Second, a soft robotic walker that is capable of walking toward a heat source and harvesting energy is introduced. Lastly, phototropic‐inspired autonomous deflection of the limbs toward a heat source is shown, demonstrating an additional method to increase energy recuperation efficiency for soft systems. 
    more » « less
  4. Liquid crystal elastomers (LCEs) are becoming increasingly popular as a shape memory material for soft robot actuators that operate in a contractile or flexural mode. There have been previously studies on the use of LCEs for reversible changes in surface topography. However, surface protrusions have typically been limited to the order of 1 μm or depend on light, heat, or electrical stimulation that are difficult to locally control or require relatively high voltage. This article presents a novel operation mode of LCE actuators based on the wrinkling behavior of an LCE‐elastomer bilayer architecture. Embedding a liquid‐metal‐based conductive ink within the LCE enables electrical control of surface wrinkling through Joule heating. The actuator cells can generate wrinkles with amplitudes ranging from 17 to 45 μm within 30 s under an input power of 2 W and a voltage on the order of 1 V. As the bilayer is composed entirely of soft materials, it is highly deformable, flexible, and can be integrated into a multi‐cell array capable of bending on curved surfaces. 
    more » « less
  5. Soft robots, constructed from deformable materials, offer significant advantages over rigid robots by mimicking biological tissues and providing enhanced adaptability, safety, and functionality across various applications. Central to these robots are electroactive polymer (EAP) actuators, which allow large deformations in response to external stimuli. This review examines various EAP actuators, including dielectric elastomers, liquid crystal elastomers (LCEs), and ionic polymers, focusing on their potential as artificial muscles. EAPs, particularly ionic and electronic varieties, are noted for their high actuation strain, flexibility, lightweight nature, and energy efficiency, making them ideal for applications in mechatronics, robotics, and biomedical engineering. This review also highlights piezoelectric polymers like polyvinylidene fluoride (PVDF), known for their flexibility, biocompatibility, and ease of fabrication, contributing to tactile and pressure sensing in robotic systems. Additionally, conducting polymers, with their fast actuation speeds and high strain capabilities, are explored, alongside magnetic polymer composites (MPCs) with applications in biomedicine and electronics. The integration of machine learning (ML) and the Internet of Things (IoT) is transforming soft robotics, enhancing actuation, control, and design. Finally, the paper discusses future directions in soft robotics, focusing on self-healing composites, bio-inspired designs, sustainability, and the continued integration of IoT and ML for intelligent, adaptive, and responsive robotic systems. 
    more » « less