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Title: Stepwise reduction of a corannulene-based helical molecular nanographene with Na metal
The chemical reduction of a corannulene-based molecular nanographene, C 76 H 64 (1), with Na metal in the presence of 18-crown-6 afforded the doubly-reduced state of 1. This reduction provokes a distortion of the helicene core and has a significant impact on the aromaticity of the system.
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Award ID(s):
2003411 1834750
Publication Date:
Journal Name:
Chemical Communications
Page Range or eLocation-ID:
5574 to 5577
Sponsoring Org:
National Science Foundation
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