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Stepwise reduction of a corannulene-based helical molecular nanographene with Na metal
The chemical reduction of a corannulene-based molecular nanographene, C 76 H 64 (1), with Na metal in the presence of 18-crown-6 afforded the doubly-reduced state of 1. This reduction provokes a distortion of the helicene core and has a significant impact on the aromaticity of the system.
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Award ID(s):
Publication Date:
NSF-PAR ID:
10325302
Journal Name:
Chemical Communications
Volume:
58
Issue:
37
Page Range or eLocation-ID:
5574 to 5577
ISSN:
1359-7345
1. In this paper, we make partial progress on a function field version of the dynamical uniform boundedness conjecture for certain one-dimensional families ${\mathcal{F}}$ of polynomial maps, such as the family $f_{c}(x)=x^{m}+c$ , where $m\geq 2$ . We do this by making use of the dynatomic modular curves $Y_{1}(n)$ (respectively $Y_{0}(n)$ ) which parametrize maps $f$ in ${\mathcal{F}}$ together with a point (respectively orbit) of period $n$ for $f$ . The key point in our strategy is to study the set of primes $p$ for which the reduction of $Y_{1}(n)$ modulo $p$ fails to be smooth or irreducible. Morton gave an algorithm to construct, for each $n$ , a discriminant $D_{n}$ whose list of prime factors contains all the primes of bad reduction for $Y_{1}(n)$ . In this paper, we refine and strengthen Morton’s results. Specifically, we exhibit two criteria on a prime $p$ dividing $D_{n}$ : one guarantees that $p$ is in fact a prime of bad reduction for $Y_{1}(n)$ , yet this same criterion implies that $Y_{0}(n)$ is geometrically irreducible. The other guarantees that the reduction of $Y_{1}(n)$ modulo $p$ is actually smooth. As an application of the second criterion, we extend results of Morton, Flynn, Poonen, Schaefer, andmore »