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1. Soft and Hard Piezoelectric Ceramics and Single Crystals for Random Vibration Energy Harvesting

   https://doi.org/10.1002/ente.201700873  

   Shahab, Shima ; Zhao, Sihong ; Erturk, Alper ( March 2018 , Energy Technology)

   Vibration‐based energy harvesting for enabling next‐generation self‐powered devices is a rapidly growing research area. In real‐world applications, the ambient vibrational energy is often available in non‐deterministic forms rather than the extensively studied deterministic scenarios, such as simple harmonic excitation. It is of interest to choose the best piezoelectric material for a given random excitation. Here, performance comparisons of various soft and hard piezoelectric ceramics and single crystals are presented for electrical power generation under band‐limited off‐resonance and wideband random vibration energy‐harvesting scenarios. For low‐frequency off‐resonance excitation, it is found that soft piezoelectric ceramics based upon lead zirconate titanate (e.g., PZT‐5H and PZT‐5A) outperform their hard counterparts (e.g., PZT‐4 and PZT‐8), and likewise soft single crystals based upon lead magnesium niobate and lead titanate as well as PZT (e.g., PMN‐PT and PMN‐PZT) outperform the relatively hard ones (e.g., manganese‐doped PMN‐PZT‐Mn). Overall, for such off‐resonance random vibrations, PMN‐PT is the most suitable choice among the materials studied. For wideband random excitation with a bandwidth covering the fundamental resonance of the harvester, hard piezoelectric ceramics offer larger power output compared to soft ceramics, and likewise hard single crystals produce larger power compared to their soft counterparts. Remarkably, a hard piezoelectric ceramic (e.g., PZT‐8) can outperform a soft single crystal (e.g., PMN‐PT) for wideband random vibration energy harvesting.

    

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2. Enhanced Piezoelectric, Ferroelectric, and Electrostrictive Properties of Lead‐Free (1‐ x )BCZT‐( x )BCST Electroceramics with Energy Harvesting Capability

   https://doi.org/10.1002/smll.202300549  

   Baraskar, Bharat G. ; Kolekar, Yesappa D. ; Thombare, Balu. R. ; James, Ajit. R. ; Kambale, Rahul C. ; Ramana, C. V. ( May 2023 , Small)

   Next‐generation electronics and energy technologies can now be developed as a result of the design, discovery, and development of novel, environmental friendly lead (Pb)‐free ferroelectric materials with improved characteristics and performance. However, there have only been a few reports of such complex materials’ design with multi‐phase interfacial chemistry, which can facilitate enhanced properties and performance. In this context, herein, novel lead‐free piezoelectric materials (1‐x)Ba_0.95Ca_0.05Ti_0.95Zr_0.05O₃‐(x)Ba_0.95Ca_0.05Ti_0.95Sn_0.05O₃, are reported, which are represented as (1‐x)BCZT‐(x)BCST, with demonstrated excellent properties and energy harvesting performance. The (1‐x)BCZT‐(x)BCST materials are synthesized by high‐temperature solid‐state ceramic reaction method by varyingxin the full range (x= 0.00–1.00). In‐depth exploration research is performed on the structural, dielectric, ferroelectric, and electro‐mechanical properties of (1‐x)BCZT‐(x)BCST ceramics. The formation of perovskite structure for all ceramics without the presence of any impurity phases is confirmed by X‐ray diffraction (XRD) analyses, which also reveals that the Ca²⁺, Zr⁴⁺, and Sn⁴⁺are well dispersed within the BaTiO₃lattice. For all (1‐x)BCZT‐(x)BCST ceramics, thorough investigation of phase formation and phase‐stability using XRD, Rietveld refinement, Raman spectroscopy, high‐resolution transmission electron microscopy (HRTEM), and temperature‐dependent dielectric measurements provide conclusive evidence for the coexistence of orthorhombic + tetragonal (Amm2+P4mm) phases at room temperature. The steady transition ofAmm2crystal symmetry toP4mmcrystal symmetry with increasingxcontent is also demonstrated by Rietveld refinement data and related analyses. The phase transition temperatures, rhombohedral‐orthorhombic (T_R‐O), orthorhombic‐ tetragonal (T_O‐T), and tetragonal‐cubic (T_C), gradually shift toward lower temperature with increasingxcontent. For (1‐x)BCZT‐(x)BCST ceramics, significantly improved dielectric and ferroelectric properties are observed, including relatively high dielectric constantε_r≈ 1900–3300 (near room temperature),ε_r≈ 8800–12 900 (near Curie temperature), dielectric loss, tanδ≈ 0.01–0.02, remanent polarizationP_r≈ 9.4–14 µC cm⁻², coercive electric fieldE_c≈ 2.5–3.6 kV cm⁻¹. Further, high electric field‐induced strainS≈ 0.12–0.175%, piezoelectric charge coefficientd₃₃≈ 296–360 pC N⁻¹, converse piezoelectric coefficient ≈ 240–340 pm V⁻¹, planar electromechanical coupling coefficientk_p≈ 0.34–0.45, and electrostrictive coefficient (Q₃₃)_avg≈ 0.026–0.038 m⁴C⁻²are attained. Output performance with respect to mechanical energy demonstrates that the (0.6)BCZT‐(0.4)BCST composition (x= 0.4) displays better efficiency for generating electrical energy and, thus, the synthesized lead‐free piezoelectric (1‐x)BCZT‐(x)BCST samples are suitable for energy harvesting applications. The results and analyses point to the outcome that the (1‐x)BCZT‐(x)BCST ceramics as a potentially strong contender within the family of Pb‐free piezoelectric materials for future electronics and energy harvesting device technologies.

    

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3. Near-ideal electromechanical coupling in textured piezoelectric ceramics

   https://doi.org/10.1038/s41467-022-31165-y  

   Yan, Yongke ; Geng, Liwei D. ; Liu, Hairui ; Leng, Haoyang ; Li, Xiaotian ; Wang, Yu U. ; Priya, Shashank ( June 2022 , Nature Communications)

   Electromechanical coupling factor,k, of piezoelectric materials determines the conversion efficiency of mechanical to electrical energy or electrical to mechanical energy. Here, we provide an fundamental approach to design piezoelectric materials that provide near-ideal magnitude ofk, via exploiting the electrocrystalline anisotropy through fabrication of grain-oriented or textured ceramics. Coupled phase field simulation and experimental investigation on <001> textured Pb(Mg_1/3Nb_2/3)O₃-Pb(Zr,Ti)O₃ceramics illustrate thatkcan reach same magnitude as that for a single crystal, far beyond the average value of traditional ceramics. To provide atomistic-scale understanding of our approach, we employ a theoretical model to determine the physical origin ofkin perovskite ferroelectrics and find that strong covalent bonding between B-site cation and oxygen viad-phybridization contributes most towards the magnitude ofk. This demonstration of near-idealkvalue in textured ceramics will have tremendous impact on design of ultra-wide bandwidth, high efficiency, high power density, and high stability piezoelectric devices.

    

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4. Effects of piezoelectric energy harvesting from a morphing flapping tail on its performance

   https://doi.org/10.1016/j.apenergy.2023.122022  

   Alqaleiby, Hossam ; Ayyad, Mahmoud ; Hajj, Muhammad R. ; Ragab, Saad A. ; Zuo, Lei ( January 2024 , Applied Energy)

   Monitoring fish migration, which can extend over distances of thousands of kilometers, via fish tags is important to maintain healthy fish stocks and pre-serve biodiversity. One constraint of current fish tags is the limited power of their batteries. Attaching a piezoelectric element to an oscillating part of the fish body has been proposed to develop self-powered tags. To determine the functionality and potential of this technology, we present an analysis showing variations of the generated voltage with specific aspects of the tail’s response. We also perform numerical simulations to validate the analysis and determine the effects of attaching a piezoelectric element on performance metrics including thrust generation, propulsive efficiency, and harvested electric power. The tail with the attached piezoelectric element is modeled as a unimorph beam moving at a constant forward speed and excited by sinusoidal pitching at its root. The hydrodynamic loads are calculated using three-dimensional unsteady vor-tex lattice method. These loads are coupled with the equation of motion, which is solved using the finite element method. The implicit finite different scheme is used to discretize the time-dependent generated voltage equation. The analysis shows that the harvested electric power depends on the slope of the trailing edge, a result that is validated with the numerical simulations. The numeri-cal simulations show that, depending on the excitation frequency, attaching a piezoelectric element can increase or decrease the thrust force. The balance of required hydrodynamic power, generated propulsive power and harvested elec-trical power shows that, depending on the excitation frequency, relatively high levels of harvested power can be harvested without a high adverse impact on the hydrodynamic or propulsive power. For a specified frequency of oscillations, the approach and results can be used to identify design parameters where harvested electrical power by a piezoelectric element will have a minimal adverse impact on the hydrodynamic or propulsive power of a swimming fish. 

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5. Physics-Based Device Models and Progress Review for Active Piezoelectric Semiconductor Devices

   https://doi.org/10.3390/s20143872  

   Oh, Hongseok ; Dayeh, Shadi A. ( July 2020 , Sensors)

   Piezoelectric devices transduce mechanical energy to electrical energy by elastic deformation, which distorts local dipoles in crystalline materials. Amongst electromechanical sensors, piezoelectric devices are advantageous because of their scalability, light weight, low power consumption, and readily built-in amplification and ability for multiplexing, which are essential for wearables, medical devices, and robotics. This paper reviews recent progress in active piezoelectric devices. We classify these piezoelectric devices according to the material dimensionality and present physics-based device models to describe and quantify the piezoelectric response for one-dimensional nanowires, emerging two-dimensional materials, and three-dimensional thin films. Different transduction mechanisms and state-of-the-art devices for each type of material are reviewed. Perspectives on the future applications of active piezoelectric devices are discussed. 

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