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1. Pronounced and rapid exhumation of the Connecticut Valley Trough revealed through quartz in garnet Raman barometry and diffusion modelling of garnet dissolution–reprecipitation reactions

   https://doi.org/10.1111/jmg.12601  

   Wolfe, Oliver M.; Spear, Frank S.; Harrison, T. Mark (April 2021, Journal of Metamorphic Geology)

   Abstract Metamorphic rocks from the Connecticut Valley Trough (CVT), Vermont, and Massachusetts, have been examined using quartz‐in‐garnet (QuiG) and conventional thermobarometry, thermodynamic reaction modelling, diffusion modelling, and⁴⁰Ar/³⁹Ar thermochronology to constrain theirP–T–tpaths during Acadian metamorphism and subsequent exhumation. Numerous samples, collected in the vicinity of the Acadian domes, contain garnet porphyroblasts that display cloudy zones characterized by numerous fluid inclusions and modified garnet compositions associated with the replacement of the original garnet by biotite±muscovite±plagioclase±quartz±lowX_grs/enrichedX_sps. QuiG and conventional thermobarometry constrain both the conditions of garnet nucleation and peakP–Tconditions to have occurred at ~0.85–1.05 GPa, ~550–600°C. Most notably, QuiG barometry was performed on inclusions adjacent to these reaction zones in conjunction with Gibbs method reaction modelling to reveal that these dissolution–reprecipitation reactions occurred during nearly isothermal decompression from the peakP–Tconditions to around ~0.3 GPa, 550°C. Diffusion modelling reveals that the Mn zoning profiles created during garnet resorption that accompanied decompression formed in less thanc. 3 Ma, which constrains the tectonic exhumation to have occurred at 8–10 mm/year. Subsequent cooling to 500°C occurred rapidly at a rate of 100°C/Ma, followed by slower cooling reaching 1.7°C /Ma by the mid Carboniferous. This is the first reported example of QuiG barometry revealing a multi‐stage metamorphic history and highlights the utility of this method for unravelling complex metamorphic terranes. 

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2. Regional Quartz Inclusion Barometry and Comparison with Conventional Thermobarometry and Intersecting Isopleths from the Connecticut Valley Trough, Vermont and Massachusetts, USA

   https://doi.org/10.1093/petrology/egaa076  

   Wolfe, Oliver M; Spear, Frank S (August 2020, Journal of Petrology)

   Abstract A comparative analysis of Raman shifts of quartz inclusions in garnet was made along two traverses across the Connecticut Valley Trough (CVT) in western New England, USA, to examine the regional trends of quartz inclusion in garnet (QuiG) Raman barometry pressure results and to compare this method with conventional thermobarometry and the method of intersecting garnet core isopleths. Overall, Raman shifts of quartz inclusions ranged from 1·2 to 3·5 cm–1 over all field areas and displayed a south to north decrease, matching the overall decrease in mapped metamorphic grade. Raman shifts of quartz inclusions typically did not show systematic variation with respect to their radial position within a garnet crystal, and indicate that garnet probably grew at nearly isothermal and isobaric pressure–temperature (P–T) conditions. The P–T conditions inferred from conventional thermobarometry were in the range of ∼500–575 °C and ∼7·4–10·3 kbar over the sample suite and are in good agreement with previous published thermobarometry throughout the CVT. These P–T results are broadly consistent with QuiG barometry and also suggest that garnet grew isothermally and isobarically at near peak P–T conditions. However, P–T conditions and P–T paths inferred using either garnet core thermobarometry or garnet core intersecting isopleths yield results that are internally inconsistent and generally disagree with the pressure results from QuiG barometry. Garnet core isopleth intersections consistently plotted between the nominal garnet-in curve on mineral assemblage diagrams and the P–T conditions constrained by QuiG isomekes for the majority of the sample suite. Additionally, most samples’ P–T results from QuiG barometry and rim thermobarometry show marked disagreement from those derived from garnet core thermobarometry, compared with the minority that showed agreement within uncertainty. Pressures calculated from QuiG barometry ranged from 8·5 to 9·5 kbar along the traverses in western Massachusetts (MA) and central Vermont (VT) and from 6·5 to 7·5 kbar in northern VT indicating an increase in peak burial of 3–6 km from north to south. Along the western end of the central VT traverse, there are differences in measured Raman shifts and inferred peak pressures of up to 1 kbar across the Richardson Memorial Contact (RMC), indicating a possible fault contact with minor post-peak metamorphic shortening of up to ∼3 km. In contrast, along an east–west traverse in the vicinity of the Goshen Dome, MA, there was little observed variation in Raman shifts across the contact. By contrast, QuiG barometry clearly indicates significant discontinuities in peak pressure east of the Strafford Dome in central VT. This supports the interpretation that post-peak metamorphic shortening was necessary to juxtapose upper staurolite–kyanite zone rocks next to lower garnet zone pelites. Overall, it is concluded that garnet core thermobarometry and garnet core isopleths may provide unreliable results for the P–T conditions of garnet nucleation and inferred P–T paths during garnet growth unless independently verified. The consistency of QuiG results with rim thermobarometry indicates that peak metamorphic conditions previously reported for the CVT using garnet rim thermobarometry are robust and that variation in QuiG barometry results is a valuable tool to analyze structural features within a metamorphic terrane. 

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3. High-pressure granulite facies metamorphism (∼1.8 GPa) revealed in silica-undersaturated garnet-spinel-corundum gneiss, Central Maine Terrane, Connecticut, U.S.A.

   https://doi.org/10.2138/am-2018-6543  

   Keller, D.S.; Ague, J.J. (January 2018, American Mineralogist)

   We quantify the metamorphic pressure-temperature (P-T) conditions for a newly discovered silica-undersaturated high-pressure granulite (HPG) from the Central Maine Terrane (CMT) in northeastern Connecticut, U.S.A. The rocks lie within the Acadian-Neoacadian orogenic belt (Devonian) and form part of the Brimfield Schist. The Brimfield and the adjacent Bigelow Brook Formation contain silica-saturated rocks that have previously been shown to have undergone ~1000 °C metamorphism. The pressure was less well constrained at ≥ ~1 GPa. Silica-undersaturated rocks hold underutilized potential for pinpointing peak metamorphic conditions, particularly pressure, because of their resilience to melting and the variety of refractory minerals they contain. The typical silica-undersaturated mineral assemblage is garnet + spinel + corundum + plagioclase + K-feldspar + biotite + ilmenite. Leucosomes are syenites consisting of two feldspars ± biotite. Plagioclase is commonly antiperthitic, particularly in feldspathic domains surrounding peritectic garnet; such garnet crystals reach ~10 cm in diameter. Alkali feldspars are perthitic. The rocks contain remarkable ellipsoidal spinels as much as 5.5 cm long comprising discrete crystallographic domains hosting crystallographically oriented lamellae of a Fe-Ti phase, most likely ilmenite. Corundum is usually colorless, but can also be found as sapphire in shades of pink, purple, and blue, particularly in antiperthite-rich domains surrounding large garnets. Some sapphires are concentrically color zoned. We carried out a P-T estimation using ternary feldspar reintegration thermometry of metamorphic antiperthites together with pseudosection modeling. Samples texturally and chemically record near-eclogite facies equilibration at minimum conditions of ~1040 °C and ~1.8 GPa, establishing the CMT in northeastern CT as the first known HPG locality in the U.S. These results are consistent with high P2O5 levels found in garnet (0.18 wt%), Ti-in-biotite thermometry, regional sillimanite pseudomorphs after kyanite, and preliminary experimental work on melt inclusions in garnet (Ferrero et al. 2017). The leucosomes provide strong evidence that partial melting of silica-undersaturated rocks at HPG conditions can produce syenitic magmata. Strongly melt-depleted silica-undersaturated rocks may also be protoliths for garnet + spinel + corundum xenoliths reported from kimberlites. The presence of HPG gneisses demonstrates that the large-scale thrusts of the CMT sample the deepest roots of the orogenic belt (60–70 km), and perhaps even deeper subduction zone lithologies as well. 

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4. Re-equilibration of quartz inclusions in garnet

   https://doi.org/10.5194/ejm-36-581-2024  

   Pummell, Benjamin A; Thomas, Jay B (August 2024, European Journal of Mineralogy)

   Abstract. Inclusion–host elastic thermobarometers are widely used to determine the pressure and temperature (P–T) histories of metamorphic rocks. Complex metamorphic P–T paths can affect the pressures that develop in host–inclusion systems. There are limited experimental studies that investigate how changing P–T conditions may re-equilibrate or “reset” residual pressures of inclusions. To evaluate re-equilibration of the quartz-in-garnet (QuiG) elastic thermobarometer, we performed single-, two-, and three-stage isothermal experiments. In the first stage of the experiments, oxide starting materials hydrothermally crystallised to grow garnet crystals with quartz inclusions between 700 and 800 °C and 1.0 and 3.2 GPa with constant P–T conditions for 48 h. In the second and third stage of the experiments, we isothermally changed pressure by 1.0 to 1.2 GPa for durations up to 38 d. We used Raman spectroscopy to measure strain-induced changes to the 128, 207, and 465 cm−1 Raman bands of quartz inclusions to determine the inclusion pressures (Pinc) and entrapment pressures (Ptrap) at the experimental temperature. The multi-stage experiments show that elasticity primarily controlled changes to Pinc values that occur from Ptrap through quenching to room conditions and that Pinc values measured at room conditions along with elastic modelling can be used to accurately calculate Ptrap. Quartz Pinc values in two-stage experiments re-equilibrated to give Pinc values between P1 and P2. The three-stage isothermal experiments show that the observed changes to inclusion pressures are reversible along different P–T paths to restore the re-equilibrated Pinc values back to their original entrapment isomeke at Ptrap. For rocks that underwent protracted metamorphism along complicated P–T paths, the re-equilibration experiments and viscoelastic calculations show that QuiG may underestimate maximum Ptrap conditions. 

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5. Geochemical and textural investigations of the Eoarchean Ukaliq supracrustals, Northern Québec (Canada)

   https://doi.org/10.1016/j.lithos.2020.105673  

   Wriju Chowdhury, Dustin Trail (January 2020, Lithos)

   null (Ed.)

   Structural, geochronological and geochemical studies of pre-3.75 Ga rocks of volcano-sedimentary protoliths in the Inukjuak domain in the Superior Province in Québec have been mostly focused on the Nuvvuagittuq Supracrustal Belt (NSB). The Porpoise Cove outcrops – at the southwestern limit of the NSB – are the de-facto “type locality” for the supracrustals of the Inukjuak Complex. Yet, it remains unclear whether the NSB rocks are geochemically distinct from, or are in fact common to, a host of other supracrustal enclaves locked in the dominantly gneissic Inukjuak domain. Here, we report detailed textural and geochemical studies for a suite of rocks from the Ukaliq Supracrustal Belt (USB), located approximately 3 km northeast of the NSB. We find that the USB and NSB have a similar protracted metamorphic history; both experienced amphibolite grade metamorphism and contain granitoid gneiss sheets, quartz-magnetite rocks (banded iron-formation s.l.) and quartz-biotite schists within amphibolitized rocks of basaltic affinity with local retrogressions. If the various Inukjuak supracrustal belts were once a part of a larger coherent (now dismembered) terrane, they should show similar emplacement ages and source chemistry. New zircon Usingle bondPb geochronology from five gneissic units and two quartz-biotite (metasedimentary) schists reveal the oldest emplacement ages across all units of each individual rock type to be 3.68 ± 0.07 Ga (granitoid gneisses) and 3.65 ± 0.06 Ga (quartz-biotite schists). These new ages are similar to those documented as likely minimum emplacement ages of the NSB determined by Usingle bondPb geochronology. Zircons from the quartz-biotite schist were also analyzed by ion microprobe for their Usingle bondPb geochronology and were found to yield statistically identical, albeit more precise, ages than those obtained by LA-ICP-MS. Possible detrital zircons from the USB quartz-biotite schists were analyzed by ion microprobe for their coupled δ30SiNBS28 and δ18OVSMOW values with respective values between −0.75 and − 0.07‰ (δ30SiNBS28), and + 5.61 and + 6.59‰ (δ18OVSMOW). The δ18OVSMOW values, which are on average above mantle-derived zircon, indicate contribution of altered, non-mantle, derived material into the source of the rocks that weathered to form the quartz-biotite schists. Zircon mineral inclusions (quartz, feldspar, apatite, biotite, muscovite and other unrecognized Fe/Al/Si rich phases), along with the major- and trace element contents for the rocks were analyzed to substantiate this interpretation. Together with δ30SiNBS28, δ18OVSMOW, our results suggest that lithologies like authigenic silica and serpentinized rocks re-melted to form the parent melts that gave rise to zircons found in the USB quartz-biotite schists. Additional Lusingle bondHf studies reported here on the same zircons also show similarities with NSB zircons. The εHf values showed a positive correlation with the measured Usingle bondPb age from −22.7 ± 0.8 to +1.9 ± 1.1. The Lusingle bondHf system also reveals that the USB, extracted at ca. 3.8 Ga, carries isotopic signatures of an older Hadean reservoir, having been formed from an Eoarchean mafic melt that incorporated them. Taken together, this supports a co-genetic origin for the NSB and the USB. 

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