Colloidal nanocrystals consist of an inorganic crystalline core with organic ligands bound to the surface and naturally self-assemble into periodic arrays known as superlattices. This periodic structure makes superlattices promising for phononic crystal applications. To explore this potential, we use plane wave expansion methods to model the phonon band structure. We find that the nanoscale periodicity of these superlattices yield phononic band gaps with very high center frequencies on the order of 10 2 GHz. We also find that the large acoustic contrast between the hard nanocrystal cores and the soft ligand matrix lead to very large phononic band gap widths on the order of 10 1 GHz. We systematically vary nanocrystal core diameter, d , nanocrystal core elastic modulus, E NC core , interparticle distance ( i.e. ligand length), L , and ligand elastic modulus, E ligand , and report on the corresponding effects on the phonon band structure. Our modeling shows that the band gap center frequency increases as d and L are decreased, or as E NC core and E ligand are increased. The band gap width behaves non-monotonically with d , L , E NC core , and E ligand , and intercoupling of these variables can eliminate the band gap. Lastly, we observe multiple phononic band gaps in many superlattices and find a correlation between an increase in the number of band gaps and increases in d and E NC core . We find that increases in the property mismatch between phononic crystal components ( i.e. d / L and E NC core / E ligand ) flattens the phonon branches and are a key driver in increasing the number of phononic band gaps. Our predicted phononic band gap center frequencies and widths far exceed those in current experimental demonstrations of 3-dimensional phononic crystals. This suggests that colloidal nanocrystal superlattices are promising candidates for use in high frequency phononic crystal applications.
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Dual Atomic Coherence in the Self-Assembly of Patchy Heterostructural Nanocrystals
Abstract Image
Advances in the synthesis and self-assembly of nanocrystals have enabled researchers to create a plethora of different nanoparticle superlattices. But while many superlattices with complex types of translational order have been realized, rotational order of nanoparticle building blocks within the lattice is more difficult to achieve. Self-assembled superstructures with atomically coherent nanocrystal lattices, which are desirable due to their exceptional electronic and optical properties, have been fabricated only for a few selected systems. Here, we combine experiments with molecular dynamics (MD) simulations to study the self-assembly of heterostructural nanocrystals (HNCs), consisting of a near-spherical quantum dot (QD) host decorated with a small number of epitaxially grown gold nanocrystal (Au NC) “patches”. Self-assembly of these HNCs results in face-centered-cubic (fcc) superlattices with well-defined orientational relationships between the atomic lattices of both QD hosts and Au patches. MD simulations indicate that the observed dual atomic coherence is linked to the number, size, and relative positions of gold patches. This study provides a strategy for the design and fabrication of NC superlattices with large structural complexity and delicate orientational order.
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- NSF-PAR ID:
- 10355270
- Date Published:
- Journal Name:
- ACS Nano
- ISSN:
- 1936-0851
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1021/acsnano.2c06167
