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1. High-speed tunable optical absorber based on a coupled photonic crystal slab and monolayer graphene structure

   https://doi.org/10.1364/OE.476763  

   Pan, Mingsen; Liu, Aaron; Liu, Zhonghe; Zhou, Weidong (January 2022, Optics Express)

   Reconfigurable metasurfaces have been pursued intensively in recent years for the ability to modulate the light after fabrication. However, the optical performances of these devices are limited by the efficiency, actuation response speed and mechanical control for reconfigurability. In this paper, we propose a fast tunable optical absorber based on the critical coupling of resonance mode to absorptive medium and the plasma dispersion effect of free carriers in semiconductor. The tunable absorber structure includes a single-layer or bi-layer silicon photonic crystal slab (PCS) to induce a high-Q optical resonance, a monolayer graphene as the absorption material, and bottom reflector to remove transmission. By modulating the refractive index of PCS via the plasma dispersion of the free carrier, the critical coupling condition is shifted in spectrum, and the device acquires tuning capability between perfect absorption and total reflection of the incident monochromatic light beam. Simulation results show that, with silicon index change of 0.015, the tunable absorption of light can achieve the reflection/absorption switching, and full range of reflection phase control is feasible in the over coupling region. The proposed reconfigurable structure has potential applications in remote sensing, free-space communications, LiDAR, and imaging. 

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2. Improved Hydrogen Sensitivity and Selectivity in PdO with Metal-Organic Framework Membrane

   https://doi.org/10.1149/1945-7111/abc0ac  

   Gardner, David W.; Xia, Yong; Fahad, Hossain M.; Javey, Ali; Carraro, Carlo; Maboudian, Roya (October 2020, Journal of The Electrochemical Society)

   Metal-organic frameworks (MOFs) are highly designable porous materials and are recognized for their exceptional selectivity as chemical sensors. However, they are not always suitable for incorporation with existing sensing platforms, especially sensing modes that rely on electronic changes in the sensing material (e.g., work-function response or conductometric response). One way that MOFs can be utilized is by growing them as a porous membrane on a sensing layer and using the MOF to affect the electronic structure of the sensing layer. In this paper, a proof-of-concept for electronic modulation with MOFs is demonstrated. A PdO nanoparticle sensing layer on a chemical-sensitive field-effect-transistor is made more sensitive to a reducing gas, hydrogen, and less sensitive to oxidizng molecules, like H₂S and NO₂, by growing a layer of the MOF “ZIF-8” over the nanoparticles. The proposed mechanism is supported by X-ray photoelectron spectroscopy showing that the ZIF-8 membrane partially reduces the PdO sensing layer. 

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3. Self-assembled HfO ₂ -Au nanocomposites with ultra-fine vertically aligned Au nanopillars

   https://doi.org/10.1039/D2NR03104C  

   Zhang, Yizhi; Zhang, Di; Liu, Juncheng; Lu, Ping; Deitz, Julia; Shen, Jianan; He, Zihao; Zhang, Xinghang; Wang, Haiyan (August 2022, Nanoscale)

   Oxide-metal-based hybrid materials have gained great research interest in recent years owing to their potential for multifunctionality, property coupling, and tunability. Specifically, oxide-metal hybrid materials in a vertically aligned nanocomposite (VAN) form could produce pronounced anisotropic physical properties, e.g. , hyperbolic optical properties. Herein, self-assembled HfO 2 -Au nanocomposites with ultra-fine vertically aligned Au nanopillars (as fine as 3 nm in diameter) embedded in a HfO 2 matrix were fabricated using a one-step self-assembly process. The film crystallinity and pillar uniformity can be obviously improved by adding an ultra-thin TiN-Au buffer layer during the growth. The HfO 2 -Au hybrid VAN films show an obvious plasmonic resonance at 480 nm, which is much lower than the typical plasmonic resonance wavelength of Au nanostructures, and is attributed to the well-aligned ultra-fine Au nanopillars. Coupled with the broad hyperbolic dispersion ranging from 1050 nm to 1800 nm in wavelength, and unique dielectric HfO 2 , this nanoscale hybrid plasmonic metamaterial presents strong potential for the design of future integrated optical and electronic switching devices. 

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4. TiN‐Au/HfO ₂ ‐Au Multilayer Thin Films with Tunable Hyperbolic Optical Response

   https://doi.org/10.1002/smtd.202400087  

   Zhang, Yizhi; Shen, Jianan; Tsai, Benson Kunhung; Sheng, Xuanyu; Hu, Zedong; Zhang, Xinghang; Wang, Haiyan (March 2024, Small Methods)

   Abstract Hyperbolic metamaterials (HMM) possess significant anisotropic physical properties and tunability and thus find many applications in integrated photonic devices. HMMs consisting of metal and dielectric phases in either multilayer or vertically aligned nanocomposites (VAN) form are demonstrated with different hyperbolic properties. Herein, self‐assembled HfO₂‐Au/TiN‐Au multilayer thin films, combining both the multilayer and VAN designs, are demonstrated. Specifically, Au nanopillars embedded in HfO₂and TiN layers forming the alternative layers of HfO₂‐Au VAN and TiN‐Au VAN. The HfO₂and TiN layer thickness is carefully controlled by varying laser pulses during pulsed laser deposition (PLD). Interestingly, tunable anisotropic physical properties can be achieved by adjusting the bi‐layer thickness and the number of the bi‐layers. Type II optical hyperbolic dispersion can be obtained from high layer thickness structure (e.g., 20 nm), while it can be transformed into Type I optical hyperbolic dispersion by reducing the thickness to a proper value (e.g., 4 nm). This new nanoscale hybrid metamaterial structure with the three‐phase VAN design shows great potential for tailorable optical components in future integrated devices. 

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5. Modeling and Analysis of Terahertz Graphene Switches for On-Wafer Coplanar Transmission Lines

   Trichopoulos, G; Theofanopoulos, P (June 2020, Journal of infrared millimeter and terahertz waves)

   null (Ed.)

   We present an analysis of graphene-loaded transmission line switches for sub-millimeter wave and terahertz applications. As such, we propose equivalent circuit models for graphene-loaded coplanar waveguides and striplines and examine the switching performance under certain parameters. Specifically, we identify the optimum design of graphene switches based on transmission line characteristic impedance, scaling factor, graphene shape, and topology (series or shunt). These parameters are varied to obtain the insertion loss and ON/OFF ratio of each switch configuration. The extracted results act as the design roadmap toward an optimum switch topology and emphasize the limitations with respect to fabrication challenges, parasitic effects, and radiation losses that are especially pronounced in the millimeter wave/terahertz bands. This is the first time that such an in-depth analysis is carried out on graphene-loaded transmission line switches, enabling the development of efficient millimeter wave/terahertz tunable topologies in terms of insertion loss and ON/OFF ratio. Specifically, the optimized switches can be integrated with antennas or employed for the development of tunable phase shifters, leading to the implementation of efficient reconfigurable reflective surfaces (e.g., reflectarrays) or coded phased arrays either for imaging or wireless communication applications. In our models, we use measured graphene values (sheet impedance) instead of theoretical equations, to obtain the actual switching performance. Moreover, the proposed study can be easily expanded to other thin film materials that can be characterized by a sheet impedance including vanadium dioxide and molybdenum disulfide. Finally, the proposed equivalent models are crucial for this in-depth study; since we simulated more than 2,000,000 configurations, a computationally challenging task with the use of full-wave solvers. 

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