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1. Formation of talc in the subduction interface: Mg isotopes demonstrate Mg loss over Si gain

   https://doi.org/10.1130/G52538.1  

   Easthouse, Griffin; Hoover, William; Teng, Fang-Zhen; Condit, Cailey; Pike, Courteney; Wang, Ze-Zhou; Berg, Anna; Wynn, Peter; Woods, Lauren; Poulaki, Eirini (February 2025, Geology)

   Abstract Talc-rich metasomatic rocks in subduction interface shear zones profoundly influence seismicity and arc magmatism, but their petrogenesis remains controversial. Magnesium isotope compositions of exhumed subduction interface rocks from the Catalina Schist (California, USA) record Mg exchange from ultramafic to crustal rocks. Preferential loss of isotopically light Mg from serpentinite produces isotopically heavy talc-rich metasomatic rocks. Addition of this isotopically light Mg to adjacent metasedimentary and metamafic rocks from the slab produces actinolite- and chlorite-rich metasomatic rocks, respectively, with convergent δ26Mg values relative to their protoliths. The addition of Ca to ultramafic- and metasedimentary-derived metasomatic rocks reflects a separate contribution from infiltrating metabasalt-derived fluids. Talc-rich rocks are formed by passive enrichment of Si in serpentinite during Mg loss to adjacent Mg sinks. These results and a global compilation of exhumed paleosubduction terranes suggest that talc is a common component of the subduction interface and often forms independent of Si metasomatism. Talc is likely prevalent along the interface from mantle wedge corner to subarc wherever ultramafic material is in contact with a Mg sink and where it could influence slow slip events, subduction interface rheology, and arc magmatism in modern subduction zones. 

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2. Slab-derived devolatilization fluids oxidized by subducted metasedimentary rocks

   https://doi.org/10.1038/s41561-022-00904-7  

   Ague, Jay J.; Tassara, Santiago; Holycross, Megan E.; Li, Ji-Lei; Cottrell, Elizabeth; Schwarzenbach, Esther M.; Fassoulas, Charalampos; John, Timm (March 2022, Nature Geoscience)

   Abstract Metamorphic devolatilization of subducted slabs generates aqueous fluids that ascend into the mantle wedge, driving the partial melting that produces arc magmas. These magmas have oxygen fugacities some 10–1,000 times higher than magmas generated at mid-ocean ridges. Whether this oxidized magmatic character is imparted by slab fluids or is acquired during ascent and interaction with the surrounding mantle or crust is debated. Here we study the petrology of metasedimentary rocks from two Tertiary Aegean subduction complexes in combination with reactive transport modelling to investigate the oxidative potential of the sedimentary rocks that cover slabs. We find that the metasedimentary rocks preserve evidence for fluid-mediated redox reactions and could be highly oxidized. Furthermore, the modelling demonstrates that layers of these oxidized rocks less than about 200 m thick have the capacity to oxidize the ascending slab dehydration flux via redox reactions that remove H₂, CH₄and/or H₂S from the fluids. These fluids can then oxidize the overlying mantle wedge at rates comparable to arc magma generation rates, primarily via reactions involving sulfur species. Oxidized metasedimentary rocks need not generate large amounts of fluid themselves but could instead oxidize slab dehydration fluids ascending through them. Proposed Phanerozoic increases in arc magma oxygen fugacity may reflect the recycling of oxidative weathering products following Neoproterozoic–Palaeozoic marine and atmospheric oxygenation. 

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3. Oxidized sulfur-rich arc magmas formed porphyry Cu deposits by 1.88 Ga

   Meng, X. (January 2021, Nature communications)

   null (Ed.)

   Most known porphyry Cu deposits formed in the Phanerozoic and are exclusively associated with moderately oxidized, sulfur-rich, hydrous arc-related magmas derived from partial melting of the asthenospheric mantle metasomatized by slab-derived fluids. Yet, whether similar metallogenic processes also operated in the Precambrian remains obscure. Here we address the issue by investigating the origin, fO2, and S contents of calc-alkaline plutonic rocks associated with the Haib porphyry Cu deposit in the Paleoproterozoic Richtersveld Magmatic Arc (southern Namibia), an interpreted mature island-arc setting. We show that the ca. 1886–1881 Ma ore-forming magmas, originated from a mantle-dominated source with minor crustal contributions, were relatively oxidized (1‒2 log units above the fayalitemagnetite- quartz redox buffer) and sulfur-rich. These results indicate that moderately oxidized, sulfur-rich arc magma associated with porphyry Cu mineralization already existed in the late Paleoproterozoic, probably as a result of recycling of sulfate-rich seawater or sediments from the subducted oceanic lithosphere at that time. 

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4. Slab-derived sulfate generates oxidized basaltic magmas in the southern Cascade arc (California, USA)

   https://doi.org/10.1130/G48759.1  

   Muth, Michelle J.; Wallace, Paul J. (June 2021, Geology)

   Abstract Whether and how subduction increases the oxidation state of Earth's mantle are two of the most important unresolved questions in solid Earth geochemistry. Using data from the southern Cascade arc (California, USA), we show quantitatively for the first time that increases in arc magma oxidation state are fundamentally linked to mass transfer of isotopically heavy sulfate from the subducted plate into the mantle wedge. We investigate multiple hypotheses related to plate dehydration and melting and the rise and reaction of slab melts with mantle peridotite in the wedge, focusing on electron balance between redox-sensitive iron and sulfur during these processes. These results show that unless slab-derived silicic melts contain much higher dissolved sulfur than is indicated by currently available experimental data, arc magma generation by mantle wedge melting must involve multiple stages of mantle metasomatism by slab-derived oxidized and sulfur-bearing hydrous components. 

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5. Subducted organic matter buffered by marine carbonate rules the carbon isotopic signature of arc emissions

   https://doi.org/10.1038/s41467-022-30421-5  

   Tumiati, S.; Recchia, S.; Remusat, L.; Tiraboschi, C.; Sverjensky, D. A.; Manning, C. E.; Vitale Brovarone, A.; Boutier, A.; Spanu, D.; Poli, S. (December 2022, Nature Communications)

   Abstract Ocean sediments consist mainly of calcium carbonate and organic matter (phytoplankton debris). Once subducted, some carbon is removed from the slab and returns to the atmosphere as CO 2 in arc magmas. Its isotopic signature is thought to reflect the bulk fraction of inorganic (carbonate) and organic (graphitic) carbon in the sedimentary source. Here we challenge this assumption by experimentally investigating model sediments composed of 13 C-CaCO 3  +  12 C-graphite interacting with water at pressure, temperature and redox conditions of an average slab–mantle interface beneath arcs. We show that oxidative dissolution of graphite is the main process controlling the production of CO 2 , and its isotopic composition reflects the CO 2 /CaCO 3 rather than the bulk graphite/CaCO 3 (i.e., organic/inorganic carbon) fraction. We provide a mathematical model to relate the arc CO 2 isotopic signature with the fluid–rock ratios and the redox state in force in its subarc source. 

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