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A<sc>bstract</sc> Positivity bounds represent nontrivial limitations on effective field theories (EFTs) if those EFTs are to be completed into a Lorentz-invariant, causal, local, and unitary framework. While such positivity bounds have been applied in a wide array of physical contexts to obtain useful constraints, their application to inflationary EFTs is subtle since Lorentz invariance is spontaneously broken during cosmic inflation. One path forward is to employ aBreit parameterizationto ensure a crossing-symmetric and analytic S-matrix in theories with broken boosts. We extend this approach to a theory with multiple fields, and uncover a fundamental obstruction that arises unless all fields obey a dispersion relation that is approximately lightlike. We then apply the formalism to various classes of inflationary EFTs, with and without isocurvature perturbations, and employ this parameterization to derive new positivity bounds on such EFTs. For multifield inflation, we also consider bounds originating from the generalized optical theorem and demonstrate how these can give rise to stronger constraints on EFTs compared to constraints from traditional elastic positivity bounds alone. We compute various shapes of non-Gaussianity (NG), involving both adiabatic and isocurvature perturbations, and show how the observational parameter space controlling the strength of NG can be constrained by our bounds.
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Overcoming positivity violations for density matrices in surface hopping
Fewest-switches surface hopping (FSSH) has emerged as one of the leading methods for modeling the quantum dynamics of molecular systems. While its original formulation was limited to adiabatic populations, the growing interest in the application of FSSH to coherent phenomena prompts the question of how one should construct a complete density matrix based on FSSH trajectories. A straightforward solution is to define adiabatic coherences based on wavefunction coefficients. In this paper, we demonstrate that inconsistencies introduced in the density matrix through such treatment may lead to a violation of positivity. We furthermore show that a recently proposed coherent generalization of FSSH results in density matrices that satisfy positivity while yielding improved accuracy throughout much (but not all) of parameter space.
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- Award ID(s):
- 2145433
- PAR ID:
- 10403315
- Date Published:
- Journal Name:
- The Journal of Chemical Physics
- Volume:
- 158
- Issue:
- 5
- ISSN:
- 0021-9606
- Page Range / eLocation ID:
- 054117
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1063/5.0135456
