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Title: Liquid–liquid transition kinetics in D-mannitol
The kinetics of the first order liquid–liquid transition (LLT) in a single-component liquid D-mannitol have been examined in detail by the high rate of flash differential scanning calorimetry measurements. By controlling the annealing temperature, the phase X formation from the supercooled liquid is distinguished by either a nucleation-growth or a spinodal-decomposition type of LLT. In the measured time–temperature-transformation curve the portion covering the nucleation-growth type of LLT can be well fitted with a classical nucleation theory analysis.  more » « less
Award ID(s):
1720415
PAR ID:
10407349
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
The Journal of Chemical Physics
Volume:
157
Issue:
7
ISSN:
0021-9606
Page Range / eLocation ID:
071101
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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