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Abstract Nanocomposites containing nanoscale materials offer exciting opportunities to encode nanoscale features into macroscale dimensions, which produces unprecedented impact in material design and application. However, conventional methods cannot process nanocomposites with a high particle loading, as well as nanocomposites with the ability to be tailored at multiple scales. A composite architected mesoscale process strategy that brings particle loading nanoscale materials combined with multiscale features including nanoscale manipulation, mesoscale architecture, and macroscale formation to create spatially programmed nanocomposites with high particle loading and multiscale tailorability is reported. The process features a low‐shrinking (<10%) “green‐to‐brown” transformation, making a near‐geometric replica of the 3D design to produce a “brown” part with full nanomaterials to allow further matrix infill. This demonstration includes additively manufactured carbon nanocomposites containing carbon nanotubes (CNTs) and thermoset epoxy, leading to multiscale CNTs tailorability, performance improvement, and 3D complex geometry feasibility. The process can produce nanomaterial‐assembled architectures with 3D geometry and multiscale features and can incorporate a wide range of matrix materials, such as polymers, metals, and ceramics, to fabricate nanocomposites for new device structures and applications.
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Multiscale nature of electric-field-induced structural formations in non-colloidal suspensions
Non-colloidal suspensions undergoing dipolar interactions in an electric field have been extensively studied and are also known as smart materials as they share similarities with electrorheological (ER) fluids. Although the macroscopic responses are well-documented, the multiscale nature of such suspensions is still lacking. In this study, a large-scale Stokesian dynamics simulation is used to investigate the structural formation of such suspensions in an electric field up to highly concentrated regimes across different length scales: from particle-level (microscale) to particle cluster-level (mesoscale) and stress response-level (macroscale). It is observed that at a volume fraction of ϕ ≈ 30%, the steady-state structures are the most isotropic at the microscale, but at the macroscale, their normal stress fields are the most anisotropic. Interestingly, these structures are also the most heterogeneous at both the microscale and mesoscale. Furthermore, the effects of confinement on the multiscale responses are explored, revealing that there could be a strong link between the mesoscale and macroscale. This multiscale nature can offer the potential for precisely controlling or designing ER fluids in practical applications.
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- Award ID(s):
- 1936065
- PAR ID:
- 10432844
- Date Published:
- Journal Name:
- Soft Matter
- Volume:
- 18
- Issue:
- 36
- ISSN:
- 1744-683X
- Page Range / eLocation ID:
- 6916 to 6926
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/d2sm00617k
