Abstract Light coupling with patterned subwavelength hole arrays induces enhanced transmission supported by the strong surface plasmon mode. In this work, a nanostructured plasmonic framework with vertically built‐in nanohole arrays at deep‐subwavelength scale (6 nm) is demonstrated using a two‐step fabrication method. The nanohole arrays are formed first by the growth of a high‐quality two‐phase (i.e., Au–TiN) vertically aligned nanocomposite template, followed by selective wet‐etching of the metal (Au). Such a plasmonic nanohole film owns high epitaxial quality with large surface coverage and the structure can be tailored as either fully etched or half‐way etched nanoholes via careful control of the etching process. The chemically inert and plasmonic TiN plays a role in maintaining sharp hole boundary and preventing lattice distortion. Optical properties such as enhanced transmittance and anisotropic dielectric function in the visible regime are demonstrated. Numerical simulation suggests an extended surface plasmon mode and strong field enhancement at the hole edges. Two demonstrations, including the enhanced and modulated photoluminescence by surface coupling with 2D perovskite nanoplates and the refractive index sensing by infiltrating immersion liquids, suggest the great potential of such plasmonic nanohole array for reusable surface plasmon‐enhanced sensing applications.
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Plasmon Hybridizations in Compound Nanorod–Nanohole Arrays
This study shows that a hybridized plasmonic mode, represented by an additional transmission peak, in a compound structure consisting of a nanorod embedded in a nanohole can be effectively described as a quasi-dipole oscillator. When two nanorods are introduced into a nanohole, these two quasi-dipoles can couple and hybridize, giving rise to two additional transmission peaks in the enhanced optical transmission spectrum. The relative intensities of these peaks can be con-trolled by adjusting the incident polarization, while their separations can be tuned by modifying the length of the nanorods. The concept of quasi-dipoles in compound nanohole structures can be further extended to predict the coupling behavior of even more complex compound configura-tions, such as multiple nanorods within nanoholes, resulting in the generation of multiple hy-bridization states. Consequently, the shape and response of the transmission peaks can be pre-cisely engineered. This strategy could be used to design nanohole-based metasurfaces for applica-tions such as ultra-thin optical filters, waveplates, polarizers, etc.
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- Award ID(s):
- 1808271
- PAR ID:
- 10434045
- Date Published:
- Journal Name:
- Nanomaterials
- ISSN:
- 2079-4991
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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