skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Measuring gas discharge in contact electrification
Abstract Contact electrification in a gas medium is usually followed by partial surface charge dissipation caused by dielectric breakdown of the gas triggered during separation of the surfaces. It is widely assumed that such discharge obeys the classical Paschen’s law, which describes the general dependence of the breakdown voltage on the product of gas pressure and gap distance. However, quantification of this relationship in contact electrification involving insulators is impeded by challenges in nondestructive in situ measurement of the gap voltage. The present work implements an electrode-free strategy for capturing discrete discharge events by monitoring the gap voltage via Coulomb force, providing experimental evidence of Paschen curves governing nitrogen breakdown in silicone-acrylic and copper-nylon contact electrification. It offers an alternative approach for characterizing either the ionization energies of gases or the secondary-electron-emission properties of surfaces without the requirement of a power supply, which can potentially benefit applications ranging from the design of insulative materials to the development of triboelectric sensors and generators.  more » « less
Award ID(s):
1662925 2145803
PAR ID:
10478399
Author(s) / Creator(s):
;
Publisher / Repository:
Nature Publishing Group
Date Published:
Journal Name:
Nature Communications
Volume:
14
Issue:
1
ISSN:
2041-1723
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract This study delves into the dynamics of cold atmospheric plasma and their interaction within conductive solutions under the unique conditions of nanosecond pulsed discharges (22 kV peak voltage, 10 ns FWHM, 4.5 kV ns−1rate-of-rise). The research focuses on the electrical response, breakdown, and discharge propagation in an argon bubble, submerged in a NaCl solution of varying conductivity. Full or partial discharges were observed at conductivities of 1.5µS cm−1(deionized water) to 1.6 mS cm−1, but no breakdown was observed at 11.0 mS cm−1when reducing the electrode gap. It is demonstrated that at higher conductivity electric breakdown is observed only when the gas bubble comes into direct contact with the electrode and multiple emission nodes were observed at different timescales. These nodes expanded in the central region of the bubble over timescales longer than the initial high-voltage pulse. This work offers a temporal resolution of 2 ns exposure times over the first 30 ns of the initial voltage pulse, and insight into plasma formation over decaying reflected voltage oscillations over 200 ns. 
    more » « less
  2. Abstract In experiment and 2D3V PIC MCC simulations, the breakdown development in a pulsed discharge in helium is studied forU= 3.2 kV and 10 kV andP= 100 Torr. The breakdown process is found to have a stochastic nature, and the electron avalanche develops in different experimental and simulation runs with time delays ranging from 0.3 to 8μs. Nevertheless our experiments demonstrate that the breakdown delay time distribution can be controlled with a change of the pulse discharge frequency. The simulation results show that the breakdown process can be distinguished in three stages with (a) the ionization by seed electrons, (b) the ions drift to the cathode and (c) the enhanced ionization within the cathode sheath by the electrons emitted from the cathode. The effects of variation of seed electron concentrations, voltage rise times, voltage amplitudes and ion–electron emission coefficients on the breakdown development in the pulsed gas discharge are reported. 
    more » « less
  3. In this work, evolution of parameters of nanosecond repetitively pulsed (NRP) discharges in pin-to-pin configuration in air was studied during the transient stage of initial 20 discharge pulses. Gas and plasma parameters in the discharge gap were measured using coherent microwave scattering, optical emission spectroscopy, and laser Rayleigh scattering for NRP discharges at repetition frequencies of 1, 10, and 100 kHz. Memory effects (when perturbations induced by the previous discharge pulse would not decay fully until the subsequent pulse) were detected for the repetition frequencies of 10 and 100 kHz. For 10 kHz NRP discharge, the discharge parameters experienced significant change after the first pulse and continued to substantially fluctuate between subsequent pulses due to rapid evolution of gas density and temperature during the 100  μs inter-pulse time caused by intense redistribution of the flow field in the gap on that time scale. For 100 kHz NRP discharge, the discharge pulse parameters reached a new steady-state at about five pulses after initiation. This new steady-state was associated with well-reproducible parameters between the discharge pulses and substantial reduction in breakdown voltage, discharge pulse energy, and electron number density in comparison to the first discharge pulse. For repetition frequencies 1–100 kHz considered in this work, the memory effects can be likely attributed to the reduction in gas number density and increase in the gas temperature that cannot fully recover to ambient conditions before subsequent discharge pulses. 
    more » « less
  4. Abstract In this work, we focus on plasma discharges produced between two electrodes with a high potential difference, resulting in the ionization of the neutral particles supporting a current in a gaseous medium. At low currents and low temperatures, this process can create luminescent emissions: glow and corona discharges. The parallel plate geometry used in Townsend's theory lets us develop a theoretical formalism, with explicit solutions for the critical voltage effectively reproducing experimental Paschen curves. However, most discharge processes occur in non‐parallel plate geometries, such as discharges between particles in multiphase systems and between cylindrical conductors. Here, we propose a generalization of the classic parallel plate configurations to concentric spherical and coaxial cylindrical geometries in Earth, Mars, Titan, and Venus atmospheres. In a spherical case, a small radius effectively represents a sharp tip rod, while larger, centimeter‐scale radii represent blunted tips. In cylindrical geometries, small radii resemble thin wires. We solve continuity equations in the gap and estimate a critical radius and minimum breakdown voltage that allows the formation of a glow discharge. We show that glow coronæ form more easily in Mars's low‐pressure, CO2‐rich atmosphere than in Earth's high‐pressure, N2‐rich atmosphere. Additionally, we present breakdown criteria for Titan and Venus, two planets where discharge processes have been postulated. We further demonstrate that critical voltage minima occur at 0.5 cm⋅Torr for all three investigated geometries, suggesting easier initiation around millimeter‐size particles in dust and water clouds. This approach could be readily extended to examine other multiphase flows with inertial particles. 
    more » « less
  5. Abstract Conventional lubricants face significant challenges in electric vehicle (EV) systems due to their low electrical conductivity and inability to mitigate tribo-electrification effects which can result in increased friction, wear, and electrical discharge damage under external electrification. Consequently, conductive lubricants like ionic liquids (ILs) have emerged as promising alternatives, offering enhanced compatibility with EV applications. This study investigated the tribological behavior of four phosphonium-based room temperature ionic liquids (PRTILs) with trihexyltetradecyl phosphonium [P6,6,6,14] or tributyltetradecyl phosphonium [P4,4,4,14] cations and saccharinate [Sacc] or benzoate [Benz] anions under electrified conditions, targeting potential EV applications. Physicochemical properties, including viscosity and ionic conductivity, were measured using a viscometer and a conductivity meter, while tribological properties were evaluated using an electrified mini-traction machine and an electrified rotary ball-on-disk setup. The results revealed that all the PRTILs exhibited superior tribological (friction and wear) performance than mineral oil with or without electrification. PRTILs with the [Sacc] anion feature a double aromatic ring structure, while those with the [Benz] anion feature a single aromatic ring structure. Under low electrification (10 mA), [P6,6,6,14][Sacc] outperformed [Benz]-based PRTILs, showing a lower coefficient of friction and wear due to their higher viscosity and lower ionic conductivity. Additionally, [P6,6,6,14][Sacc] showed a power loss lower than [P4,4,4,14][Sacc] but higher than [Benz]-based PRTILs under tribo-electrification. The addition of graphene nanoplatelets (GNPs) reduced the power loss of [P6,6,6,14][Sacc] by 24% by reducing the electric contact resistance. Overall, double-ring aromatic [P6,6,6,14][Sacc] demonstrated superior tribological performance, and GNP additives enhanced their power efficiency, offering a promising pathway for IL-based lubricant development for electrified conditions. 
    more » « less