The use of high pressure to realize superconductivity in the vicinity of room temperature has a long history, much of it focused on achieving this in hydrogen-rich materials. This paper provides a brief overview of the work presented at this May 2018 conference, together with background on motivation and techniques, the theoretical predictions of superconductivity in lanthanum hydride, and the subsequent experimental confirmation. Theoretical calculations using density-functional based structure-search methods combined with BCS-type models predicted a new class of dense, hydrogen-rich materials – superhydrides (MHx, with x > 6 and M selected rare earth elements) – with superconducting critical temperatures (Tc) in the vicinity of room-temperature at and above 200 GPa pressures. The existence of a series of these phases in the La-H system was subsequently confirmed experimentally, and techniques were developed for their syntheses and characterization, including measurements of structural and transport properties, at megabar pressures. Four-probe electrical transport measurements of a cubic phase identified as LaH10 display signatures of superconductivity at temperatures above 260 K near 200 GPa. The results are supported by pseudo-four probe conductivity measurements, critical current determinations, low-temperature x-ray diffraction, and magnetic susceptibility measurements. The measured high Tc is in excellent agreement with the original calculations. The experiments also reveal additional superconducting phases with Tc between 150 K and above 260 K. This effort highlights the novel physics in hydrogen-rich materials at high densities, the success of ‘materials by design’ in the discovery and creation of new materials, and the possibility of new classes of superconductors Tc‘s at and above room temperature.
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This content will become publicly available on March 19, 2025
Thermodynamic properties and enhancement of diamagnetism in nitrogen doped lutetium hydride synthesized at high pressure
Nitrogen doped lutetium hydride has drawn global attention in the pursuit of room-temperature superconductivity near ambient pressure and temperature. However, variable synthesis techniques and uncertainty surrounding nitrogen concentration have contributed to extensive debate within the scientific community about this material and its properties. We used a solid-state approach to synthesize nitrogen doped lutetium hydride at high pressure and temperature (HPT) and analyzed the residual starting materials to determine its nitrogen content. High temperature oxide melt solution calorimetry determined the formation enthalpy of LuH1.96N0.02(LHN) from LuH2and LuN to be −28.4 ± 11.4 kJ/mol. Magnetic measurements indicated diamagnetism which increased with nitrogen content. Ambient pressure conductivity measurements observed metallic behavior from 5 to 350 K, and the constant and parabolic magnetoresistance changed with increasing temperature. High pressure conductivity measurements revealed that LHN does not exhibit superconductivity up to 26.6 GPa. We compressed LHN in a diamond anvil cell to 13.7 GPa and measured the Raman signal at each step, with no evidence of any phase transition. Despite the absence of superconductivity, a color change from blue to purple to red was observed with increasing pressure. Thus, our findings confirm the thermodynamic stability of LHN, do not support superconductivity, and provide insights into the origins of its diamagnetism.
more » « less- Award ID(s):
- 2052527
- NSF-PAR ID:
- 10496461
- Publisher / Repository:
- Proceedings of the National Academy of Sciences of the United States of America
- Date Published:
- Journal Name:
- Proceedings of the National Academy of Sciences
- Volume:
- 121
- Issue:
- 12
- ISSN:
- 0027-8424
- Page Range / eLocation ID:
- e2321540121
- Subject(s) / Keyword(s):
- ["Material synthesis and characterization. Superconductivity"]
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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