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Conical surfaces pose an interesting challenge to crystal growth: A crystal growing on a cone can wrap around and meet itself at different radii. We use a disk-packing algorithm to investigate how this closure constraint can geometrically frustrate the growth of single crystals on cones with small opening angles. By varying the crystal seed orientation and cone angle, we find that—except at special commensurate cone angles—crystals typically form a seam that runs along the axial direction of the cone, while near the tip, a disordered particle packing forms. We show that the onset of disorder results from a finite-size effect that depends strongly on the circumference and not on the seed orientation or cone angle. This finite-size effect occurs also on cylinders, and we present evidence that on both cylinders and cones, the defect density increases exponentially as circumference decreases. We introduce a simple model for particle attachment at the seam that explains the dependence on the circumference. Our findings suggest that the growth of single crystals can become frustrated even very far from the tip when the cone has a small opening angle. These results may provide insights into the observed geometry of conical crystals in biological and materials applications.
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Phonon eigenfunctions of inhomogeneous lattices: Can you hear the shape of a cone?
We study the phonon modes of interacting particles on the surface of a truncated cone resting on a plane subject to gravity, inspired by recent colloidal experiments. We derive the ground-state configuration of the particles under gravitational pressure in the small-cone-angle limit and find an inhomogeneous triangular lattice with spatially varying density but robust local order. The inhomogeneity has striking effects on the normal modes such that an important feature of the cone geometry, namely its apex angle, can be extracted from the lattice excitations. The shape of the cone leads to energy crossings at long wavelengths and frequency-dependent quasilocalization at short wavelengths.We analytically derive the localization domain boundaries of the phonons in the limit of small cone angle and check our results with numerical results for eigenfunctions.
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- Award ID(s):
- 2011754
- PAR ID:
- 10499974
- Publisher / Repository:
- American Physical Society
- Date Published:
- Journal Name:
- Physical Review E
- Volume:
- 104
- Issue:
- 6
- ISSN:
- 2470-0045
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1103/PhysRevE.104.065005
