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1. Observation of chiral surface excitons in a topological insulator Bi ₂ Se ₃

   https://doi.org/10.1073/pnas.1813514116  

   Kung, H. -H.; Goyal, A. P.; Maslov, D. L.; Wang, X.; Lee, A.; Kemper, A. F.; Cheong, S. -W.; Blumberg, G. (February 2019, Proceedings of the National Academy of Sciences)

   The protected electron states at the boundaries or on the surfaces of topological insulators (TIs) have been the subject of intense theoretical and experimental investigations. Such states are enforced by very strong spin–orbit interaction in solids composed of heavy elements. Here, we study the composite particles—chiral excitons—formed by the Coulomb attraction between electrons and holes residing on the surface of an archetypical 3D TI, ${\mathrm{B}\mathrm{i}}_2{\mathrm{S}\mathrm{e}}_3$. Photoluminescence (PL) emission arising due to recombination of excitons in conventional semiconductors is usually unpolarized because of scattering by phonons and other degrees of freedom during exciton thermalization. On the contrary, we observe almost perfectly polarization-preserving PL emission from chiral excitons. We demonstrate that the chiral excitons can be optically oriented with circularly polarized light in a broad range of excitation energies, even when the latter deviate from the (apparent) optical band gap by hundreds of millielectronvolts, and that the orientation remains preserved even at room temperature. Based on the dependences of the PL spectra on the energy and polarization of incident photons, we propose that chiral excitons are made from massive holes and massless (Dirac) electrons, both with chiral spin textures enforced by strong spin–orbit coupling. A theoretical model based on this proposal describes quantitatively the experimental observations. The optical orientation of composite particles, the chiral excitons, emerges as a general result of strong spin–orbit coupling in a 2D electron system. Our findings can potentially expand applications of TIs in photonics and optoelectronics. 

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2. Phonon screening and dissociation of excitons at finite temperatures from first principles

   https://doi.org/10.1073/pnas.2403434121  

   Alvertis, Antonios M; Haber, Jonah B; Li, Zhenglu; Coveney, Christopher_J N; Louie, Steven G; Filip, Marina R; Neaton, Jeffrey B (July 2024, Proceedings of the National Academy of Sciences)

   The properties of excitons, or correlated electron–hole pairs, are of paramount importance to optoelectronic applications of materials. A central component of exciton physics is the electron–hole interaction, which is commonly treated as screened solely by electrons within a material. However, nuclear motion can screen this Coulomb interaction as well, with several recent studies developing model approaches for approximating the phonon screening of excitonic properties. While these model approaches tend to improve agreement with experiment, they rely on several approximations that restrict their applicability to a wide range of materials, and thus far they have neglected the effect of finite temperatures. Here, we develop a fully first-principles, parameter-free approach to compute the temperature-dependent effects of phonon screening within the ab initio $\mathit{GW}$-Bethe–Salpeter equation framework. We recover previously proposed models of phonon screening as well-defined limits of our general framework, and discuss their validity by comparing them against our first-principles results. We develop an efficient computational workflow and apply it to a diverse set of semiconductors, specifically AlN, CdS, GaN, MgO, and ${\text{SrTiO}}_3$. We demonstrate under different physical scenarios how excitons may be screened by multiple polar optical or acoustic phonons, how their binding energies can exhibit strong temperature dependence, and the ultrafast timescales on which they dissociate into free electron–hole pairs. 

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3. T-linear resistivity from magneto-elastic scattering: Application to PdCrO ₂

   https://doi.org/10.1073/pnas.2305609120  

   Mendez-Valderrama, J. F.; Tulipman, Evyatar; Zhakina, Elina; Mackenzie, Andrew P.; Berg, Erez; Chowdhury, Debanjan (September 2023, Proceedings of the National Academy of Sciences)

   An electronic solid with itinerant carriers and localized magnetic moments represents a paradigmatic strongly correlated system. The electrical transport properties associated with the itinerant carriers, as they scatter off these local moments, have been scrutinized across a number of materials. Here, we analyze the transport characteristics associated with ultraclean PdCrO ${}_2$—a quasi-two-dimensional material consisting of alternating layers of itinerant Pd-electrons and Mott-insulating CrO ${}_2$layers—which shows a pronounced regime ofT-linear resistivity over a wide range of intermediate temperatures. By contrasting these observations to the transport properties in a closely related material PdCoO ${}_2$, where the CoO ${}_2$layers are band-insulators, we can rule out the traditional electron–phonon interactions as being responsible for this interesting regime. We propose a previously ignored electron-magneto-elastic interaction between the Pd-electrons, the Cr local moments and an out-of-plane phonon as the main scattering mechanism that leads to the significant enhancement of resistivity and aT-linear regime in PdCrO ${}_2$at temperatures far in excess of the magnetic ordering temperature. We suggest a number of future experiments to confirm this picture in PdCrO ${}_2$as well as other layered metallic/Mott-insulating materials. 

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4. Thermally generated spin current in the topological insulator Bi ₂ Se ₃

   https://doi.org/10.1126/sciadv.adi4540  

   Jain, Rakshit; Stanley, Max; Bose, Arnab; Richardella, Anthony R.; Zhang, Xiyue S.; Pillsbury, Timothy; Muller, David A.; Samarth, Nitin; Ralph, Daniel C. (December 2023, Science Advances)

   We present measurements of thermally generated transverse spin currents in the topological insulator Bi₂Se₃, thereby completing measurements of interconversions among the full triad of thermal gradients, charge currents, and spin currents. We accomplish this by comparing the spin Nernst magneto-thermopower to the spin Hall magnetoresistance for bilayers of Bi₂Se₃/CoFeB. We find that Bi₂Se₃does generate substantial thermally driven spin currents. A lower bound for the ratio of spin current density to thermal gradient is $\frac{J_s}{{\mathbf{\nabla }}_{\mathit{x}}\mathit{T}}$= (4.9 ± 0.9) × 10⁶ $\left(\frac{\hslash }{2e}\right)\frac{\mathbf{A}{\mathbf{m}}^{-2}}{\mathbf{K}\text{μ}{\mathbf{m}}^{-1}}$, and a lower bound for the magnitude of the spin Nernst ratio is −0.61 ± 0.11. The spin Nernst ratio for Bi₂Se₃is the largest among all materials measured to date, two to three times larger compared to previous measurements for the heavy metals Pt and W. Strong thermally generated spin currents in Bi₂Se₃can be understood via Mott relations to be due to an overall large spin Hall conductivity and its dependence on electron energy. 

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5. On-chip spin-orbit locking of quantum emitters in 2D materials for chiral emission

   https://doi.org/10.1364/OPTICA.463481  

   Ma, Yichen; Zhao, Haoqi; Liu, Na; Gao, Zihe; Mohajerani, Seyed_Sepehr; Xiao, Licheng; Hone, James; Feng, Liang; Strauf, Stefan (August 2022, Optica)

   Light carries both spin angular momentum (SAM) and orbital angular momentum (OAM), which can be used as potential degrees of freedom for quantum information processing. Quantum emitters are ideal candidates towards on-chip control and manipulation of the full SAM–OAM state space. Here, we show coupling of a spin-polarized quantum emitter in a monolayer ${\mathrm{W}\mathrm{S}\mathrm{e}}_2$with the whispering gallery mode of a ${\mathrm{S}\mathrm{i}}_3{\mathrm{N}}_4$ring resonator. The cavity mode carries a transverse SAM of $\mathrm{\sigma <\#comment/>}=\pm <\#comment/>1$in the evanescent regions, with the sign depending on the orbital power flow direction of the light. By tailoring the cavity–emitter interaction, we couple the intrinsic spin state of the quantum emitter to the SAM and propagation direction of the cavity mode, which leads to spin–orbit locking and subsequent chiral single-photon emission. Furthermore, by engineering how light is scattered from the WGM, we create a high-order Bessel beam which opens up the possibility to generate optical vortex carrying OAM states. 

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